Material Safety
Data Sheet *2
1
0
MSDS Number: CT 10097-2
DATE PREPARED: March 7, 2008
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product/Trade Name:
CertaSpray Foam (Open Cell)
Chemical Name: Not Applicable
CAS #: Not Applicable
Common Name: CertaSpray-B (Open Cell)
Product Use: CertaSpray open cell spray foam is a two component water-blown spray foam.
When CertaSpray-A is mixed with CertaSpray-B (Open Cell) under pressure in a 1:1 volumetric
ratio, it expands into a low density open-cell foam.
MANUFACTURER INFORMATION: TELEPHONE AND E-MAIL:
CertainTeed Corporation (610) 341-7000 9 AM ?5 PM
P.O. Box 860 (Eastern Time ?USA)
Valley Forge, PA 19482-0101 CertainTeed-EHS@saint-gobain.com
EMERGENCY TELEPHONE: CHEMTREC (800) 424-9300
2. HAZARD IDENTIFICATION
Emergency Overview
This is a liquid product.
Harmful if absorbed through the skin. Causes respiratory tract and skin irritation. May be harmful
if swallowed.
Summary:
Do not ingest. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor or mist. Keep
container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Routes of Exposure: Inhalation, skin, and eye contact.
Potential Health Effects: Eyes
Avoid contact with eyes. Causes sever irritation.
Potential Health Effects: Skin
Avoid contact with skin. Harmful if absorbed through the skin.
Potential Health Effects: Ingestion
Do not ingest. May be harmful if swallowed.
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MSDS Number: CT 10097-2
Potential Health Effects: Inhalation
Avoid breathing vapor or mist.
Medical Conditions Aggravated by Exposure: None.
HMIS Ratings: Health: *2 Fire: 1 Physical Hazard: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS # Component Percent
Not
Polyether Polyol 10-30
Available
9016-45-9 Nonylphenol, ethoxylated 10-30
13674-84-5 tris(2-chloro-1-methylethyl) phosphate 7-13
3033-62-3 Bis (2-dimethylaminoether) ether 1-5
2212-32-0 N,N,N'-trimethylaminoethyl ethanolamine 1-5
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under the OSHA Hazard Communication Standard (29
CFR 1910.1200).
This product is a controlled product under Canadian WHMIS regulations.
4. FIRST AID MEASURES
First Aid: Eyes
Immediately flush eyes with large amounts of water for at least 15 minutes. Seek medical
attention at once.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water for at least 15
minutes. If irritation develops or persists, seek medical attention. Contaminated leather articles,
including shoes, that cannot be decontaminated should be discarded. Launder contaminated
clothing before reuse. Do not take clothing home to be laundered.
First Aid: Ingestion
If the product is ingested, seek immediate medical attention or advice. Do not induce vomiting.
If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.
First Aid: Inhalation
If the product is inhaled, remove the affected person to fresh air. If breathing is difficult,
administer oxygen and/or artificial respiration if necessary and seek medical attention.
Notes to Physician:
Symptomatic treatment and supportive therapy as indicated. Administer oxygen if necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours
as delayed pulmonary edema may develop.
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MSDS Number: CT 10097-2
5. FIRE FIGHTING MEASURES
General Fire Hazards: See Section 9 for Flammability Properties. Cool containers with water spray.
Hazardous Combustion Products:
Combustion products may include carbon oxides, nitrogen oxides, halogenated compounds,
phosphates and hydrogen chloride.
Extinguishing Media: Use methods for the surrounding fire.
Fire Fighting Equipment/Instructions:
Standard fire fighting protective equipment is recommended, including full-face, self-contained
breathing apparatus and impervious protective clothing.
NFPA Ratings: Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
6. ACCIDENTAL RELEASE MEASURES
Containment Procedures:
Wear appropriate personal protective equipment. Stop the flow of material, if this can be done
without risk.
Clean-Up Procedures:
Ventilate the contaminated area. Absorb spilled material with inert absorbent (sand, earth).
Shovel material into an appropriate container for disposal or recovery. Dispose of in accordance
with Federal, State and local regulations in a permitted waste management facility.
Evacuation Procedures:
Evacuate the area promptly. Keep upwind of the spilled material and isolate exposure.
Special Procedures:
Avoid inhalation of vapors or mists. Surfaces may become slippery after spillage.
7. HANDLING AND STORAGE
Handling Procedures:
Avoid contact with skin and eyes. Keep container closed. Use this product with adequate
ventilation. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. Do
not ingest.
Storage Procedures:
It is recommended that the product drums should be stored between 50?00?Keep containers
F.
tightly closed. Keep container in a dry, well-ventilated area protected from freezing, rain, direct
sunlight and excess heat. Do not store material near food, feed or drinking water. The storage life
of chemicals is 3 months.
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MSDS Number: CT 10097-2
8. EXPOSURE CONTROL / PERSONAL PROTECTION
A: Component Exposure Limits:
Bis (2-dimethylaminoether) ether (3033-62-3)
ACGIH: 0.15 ppm STEL
0.05 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
Engineering Controls:
Provide adequate local exhaust ventilation to maintain worker exposures below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: General
Use appropriate personal protective equipment when handling this product. Eye wash fountain
and emergency showers are recommended in areas where this product may be handled/used.
Personal Protective Equipment: Eyes/Face
Wear chemical goggles; add face shield (if splashing is possible).
Personal Protective Equipment: Skin
Wear impervious gloves, such as neoprene, nitrile rubber, or butyl rubber at all times when
handling this product. Thin latex disposable gloves should be avoided for repeated or long term
use. Work clothing sufficient to prevent all skin contact should be worn.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent build-up of vapors, appropriate NIOSH-
approved (or equivalent) respiratory protection must be provided with NIOSH-approved (or
equivalent) cartridges for protection against organic vapors and a P100 (HEPA) particulate filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Odor:
Liquid. Not Available.
Physical State: pH:
Liquid. Not Available.
Vapor Pressure: Vapor Density:
Not Available. Not Available.
Boiling Point: Melting Point:
Not Available. Not Available.
o
Solubility (H2O): Specific Gravity:
Not Available. 1.10 g/ml at 25 C
Flash Point: Flash Point Method:
>230?(110?br>
F C) Cleveland Closed Cup
Lower Flammability Upper Flammability
Not Available. Not Available.
Limit: Limit:
Auto Ignition Temp.: Burning Rate:
Not Available. Not Available.
Flame Spread Index, 4 Flame Spread Method
<25 ASTM E84
inch
Smoke Index, 4 inch Smoke Index Method
<350 ASTM E84
10. CHEMICAL STABILITY AND REACTIVITY INFORMATION
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: None identified
Incompatibility:
Reactive or incompatible with oxidizing materials, reducing materials, metals, acids and alkalis.
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MSDS Number: CT 10097-2
Hazardous Decomposition:
May include carbon oxides, nitrogen oxides, halogenated compounds, phosphates and hydrogen
chloride.
Possibility of Hazardous Reactions: None identified.
11. TOXICOLOGICAL INFORMATION
Acute Dose Effects
A: General Product Information:
Harmful if absorbed through the skin. Causes eye irritation. Causes slight respiratory
tract and skin irritation.
B: Component Analysis:
Polyether polyol (Not Available)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit >2000mg/kg
Nonylphenol, ethoxylated (9016-45-9)
Oral LD50 Rat: 1310 mg/kg; Dermal LD50 Rabbit: 2 mL/kg
tris(2-chloro-1-methylethyl) phosphate (13674-84-5)
Inhalation LC50 Rat: 5 mg/L/4H; Inhalation LC50 Rat: >17.8 mg/L/1H; Oral LD50 Rat:
500 mg/kg; Dermal LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: 1230 mg/kg;
Inhalation LC50 Rat: >4.6 mg/l (4 hour/hours)
Bis (2-dimethylaminoether) ether (3033-62-3)
Oral LD50 Rat: 1070 mg/kg; Dermal LD50 Rabbit: 280 礚/kg
N,N,N'-trimethylaminoethyl ethanolamine (2212-32-0)
Oral LD50 Rat: 1580 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg;
Inhalation LC50 Rat: >2.7 mg/l (4 hour/hours)
Carcinogenicity
A: General Product Information: No known significant effects or critical hazards.
B: Component Carcinogenicity:
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
Mutagenicity: No known significant effects or critical hazards.
Teratogenicity: No known significant effects or critical hazards.
Developmental Effects: No known significant effects or critical hazards.
12. ECOLOGICAL INFORMATION
Ecotoxicity
A: General Product Information: This product has not been tested.
B: Component Analysis ?Ecotoxicity ?Aquatic Toxicity:
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MSDS Number: CT 10097-2
tris(2-chloro-1-methylethyl) phosphate (13674-84-5)
Test & Species Conditions
96 Hr LC50 Brachydanio rerio 56.2 mg/L static
96 Hr LC50 Leuciscus idus 180 mg/L static
96 Hr LC50 Pimephales promelas 98 mg/L static
96 Hr LC50 Poecilia reticulata 30 mg/L static
72 Hr EC50 Scenedesmus 45 mg/L
subspicatus
96 Hr EC50 Selenastrum 4 mg/L
capricornutum
30 min EC50 Photobacterium 295 mg/L
phosphoreum
48 Hr EC50 Daphnia magna 63 mg/L
13. WASTE DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
A: General Product Information:
Wastes must be tested using methods described in 40 CFR Part 261 to determine if it
meets applicable definitions of hazardous wastes.
B: Component Waste Numbers:
No EPA-listed Waste Numbers are being shown for this product's components.
Disposal Instructions:
The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers. Dispose of waste
material according to Federal, State, local and Provincial environmental regulations. See Section
7 for Handling Procedures; see Section 8 for Personal Protective Equipment recommendations.
14. TRANSPORTATION INFORMATION
International Transportation Regulations:
This product is not regulated as a hazardous material by the United States (DOT) or Canadian
(TDG) transportation regulations.
15. REGULATORY INFORMATION
US Federal
A: General Product Information:
Components of this product have been checked against the non-confidential TSCA
inventory by CAS Registry Number. Components not identified on this non-confidential
inventory are either exempt from listing (i.e. polymers, hydrates) or are listed on the
confidential inventory as declared by the supplier.
B: CERCLA:
None of the components of this product are present at an amount reportable to the
National Response Center under the Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA: 40 CFR 302.4) or to State and local
emergency planning committees under the Superfund Amendments and Reauthorization
Act (SARA), Title III, Section 304.
Acute Health: Yes Chronic Health: No Fire: No Pressure: No Reactive: No
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State Regulations
A: General Product Information:
Other state regulations may apply. Check individual state requirements.
B: Component Analysis ?State:
None of this product's components are listed on the state lists from CA, MA, MN, NJ, PA,
or RI.
C: California Safe Drinking Water and Toxics Enforcement Act (Proposition 65):
The following statement(s) are provided under the California Safe Drinking Water and
Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer
and/or birth defects or other reproductive harm.
Canadian WHMIS Information
A: General Product Information: WHMIS Class D1B, D2B ?Irritating to eyes and skin.
B: Component Analysis - WHMIS IDL: No components are listed in the WHMIS IDL.
WHMIS Classification: WHMIS Class D1B, D2B ?Irritating to eyes and skin.
Additional Regulatory Information
A: General Product Information: No additional information available.
B: Component Analysis - Inventory
Component CAS # TSCA DSL
Nonylphenol, ethoxylated 9016-45-9 Yes Yes
tris(2-chloro-1-methylethyl) phosphate 13674-84-5 Yes Yes
Bis (2-dimethylaminoether) ether 3033-62-3 Yes Yes
N,N,N'-trimethylaminoethyl 2212-32-0 Yes Yes
ethanolamine
16. ADDITIONAL COMMENTS
Other Information
Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose.
Any product purchased is sold on the assumption the purchaser will make his own tests to
determine the quality and suitability of the product. Supplier expressly disclaims any and all
liability for incidental and/or consequential property damage arising out of the use of this product.
No information provided shall be deemed to be a recommendation to use any product in conflict
with any existing patent rights. Read the Material Safety Data Sheet before handling product.
Acronyms/definitions used in this MSDS:
ACGIH American Conference of Governmental Industrial Hygienists;
CAS # Chemical Abstracts Services Number;
CERCLA Comprehensive Environmental Response, Compensation and Liability Act;
CFR Code of Federal Regulations;
EPA Environmental Protection Agency;
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MSDS Number: CT 10097-2
HMIS Hazardous Material Identification System;
IARC International Agency for Research on Cancer;
LFL Lower Flammable Limit;
3
mg/m Milligrams per cubic meter;
NFPA National Fire Protection Association;
NIOSH National Institute for Occupational Safety and Health;
NTP National Toxicology Program;
OSHA Occupational Safety and Health Administration;
ppm Parts per million;
PEL Permissible Exposure Limit;
REL Recommended Exposure Limit;
SARA Superfund Amendments and Reauthorization Act;
RCRA Resource Conservation and Recovery Act;
Title III Emergency Planning and Community Right to Know Act;
Section 302- Extremely Hazardous Substances;
Section 313- Toxic Chemicals;
TLV Threshold Limit Value;
TWA Time Weighted Average;
UFL Upper Flammable Limit.
MSDS History
MSDS Revision Summary:
Date MSDS No. Comments
05/21/2007 CT 10097-1 New MSDS
06/15/2007 CT 10097-1 Formatting changes
06/27/2007 CT 10097-1 Additional Property Information
08/31/2007 CT 10097-1 New component information
09/07/2007 CT 10097-1 Minor grammatical change
10/01/2007 CT 10097-1 Update product use information
03/07/2008 CT 10097-2 Update product name
This is the end of MSDS # CT 10097-2
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