AeroShell Grease S.7108
Safety Data Sheet
AeroShell Grease S.7108
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Product Code 001A0068
Infosafe No. ACITO GB/eng/C
Issued Date 14/05/2003
Product Type/Use Synthetic grease for aircraft. For further details consult the AeroShell Book
on www.shell.com/aviation.
Other Names Name Code
AeroShell Grease S.7108 140001168125
Supplier Telephone Numbers
SHELL UK PRODUCTS LTD Emergency Tel.
Stanlow Manufacturing Complex
0151-350-4595
PO Box 3
Telephone/Fax Number
Ellesmere Port
CH65 4HB Tel: 0151-350-4000
Technical Contact: Product HSE
Department
United Kingdom
2. COMPOSITION/INFORMATION ON INGREDIENTS
Preparation Description
Synthetic oil grease thickened with clay, containing additives.
Dangerous Components / Constituents
Barium content of the blended product is < 0.5%(m/m).
Name CAS EINECS Proportion Hazard R Phrase
R36/38, R43,
Tolutriazole 136-85-6 205-265-8 0.1-0.9 % Xi, Xn R20/21/22,
R52/53
3. HAZARDS IDENTIFICATION
EC Classification Not classified as Dangerous under EC criteria.
Human Health Hazards
Version No. 1.1 14/05/2003 Page 1 of 8
AeroShell Grease S.7108
No specific hazards under normal use conditions. Prolonged or repeated exposure may give rise to dermatitis.
Used grease may contain harmful impurities.
Safety Hazards
Not classified as flammable, but will burn.
Environmental Hazards
Not classified as dangerous for the environment.
4. FIRST AID MEASURES
Symptoms and Effects
Not expected to give rise to an acute hazard under normal conditions of use. May cause an allergic skin
reaction in sensitive individuals.
Inhalation
In the unlikely event of dizziness or nausea, remove casualty to fresh air. If symptoms persist, obtain medical
attention.
Skin
Remove contaminated clothing and wash affected skin with soap and water. If persistent irritation occurs, obtain
medical attention. If high pressure injection injuries occur, obtain medical attention immediately.
Eye
Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention.
Ingestion
Wash out mouth with water and obtain medical attention. Do not induce vomiting.
Advice to Doctor
Treat symptomatically. Aspiration into the lungs may result in chemical pneumonitis. Dermatitis may result from
prolonged or repeated exposure.
High pressure injection injuries may require surgical intervention and possibly steroid therapy to minimise tissue
damage and loss of function. Because entry wounds are small and may not reflect the seriousness of the
underlying damage, surgical exploration to determine the extent of involvement may be necessary. Emesis of
lubricants is not usually necessary, unless a large amount has been ingested, or some other compound has
been dissolved in the product. If this is indicated, for example, when there is rapid onset of central nervous
system depression from large ingested volume - gastric lavage under controlled hospital conditions, with full
protection of the airway is required. Supportive care may include oxygen, arterial blood gas monitoring,
respiratory support, and, if aspiration has occurred, treatment with corticosteriods and antibiotics. Seizures
should be controlled with Diazepam, or appropriate equivalent drug.
5. FIRE FIGHTING MEASURES
Specific Hazards
Combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases,
including carbon monoxide and unidentified organic and inorganic compounds.
Extinguishing Media
Foam and dry chemical powder. Carbon dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing Media
Water in jet. Use of halon extinguishers should be avoided for environmental reasons.
Protective Equipment
Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined
space.
Version No. 1.1 14/05/2003 Page 2 of 8
AeroShell Grease S.7108
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Avoid contact with skin and eyes. Wear PVC, Neoprene or nitrile rubber gloves. Wear rubber knee length safety
boots and PVC Jacket and Trousers. Wear safety glasses or full face shield if splashes are likely to occur.
Environmental Precautions
Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate
barriers. Inform local authorities if this cannot be prevented.
Clean-up Methods - Small Spillages
Dispose into a suitable, clearly marked container for disposal or reclamation in accordance with local
regulations.
Clean-up Methods - Large Spillages
As for small spills.
7. HANDLING AND STORAGE
Handling
Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Avoid prolonged or
repeated contact with skin. When handling product in drums, safety footwear should be worn and proper
handling equipment should be used. Prevent spillages. Cloth, paper and other materials that are used to absorb
spills present a fire hazard. Avoid their accumulation by disposing of them safely and immediately. In addition to
any specific recommendations given for controls of risks to health, safety and the environment, an assessment
of risks must be made to help determine controls appropriate to local circumstances. Exposure to this product
should be reduced as low as reasonably practicable. Reference should be made to the Health and Safety
Executive's publication 'COSHH Essentials'.
Storage
Keep in a cool, dry, well-ventilated place. Use properly labelled and closeable containers. Avoid direct sunlight,
heat sources, and strong oxidizing agents.
Storage Temperatures
0篊 Minimum. 50篊 Maximum.
Recommended Materials
For containers or container linings, use mild steel or high density polyethylene.
Unsuitable Materials
For containers or container linings, avoid PVC.
Other Information
Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Limits
No Exposure Limit Established
Other Exposure Information
Due to the product's semi-solid consistency, generation of mists and dusts is unlikely to occur.
Exposure Controls
The use of personal protective equipment is only one aspect of an integrated approach to the Control Of
Version No. 1.1 14/05/2003 Page 3 of 8
AeroShell Grease S.7108
Substances Hazardous to Health.
The management of Health and Safety at Work Regulations 1992 require employers to identify and evaluate the
risks to health and to implement appropriate measures to eliminate or minimise those risks. The choice of
personal protective equipment is highly dependent upon local conditions, e.g. exposure to other chemical
substances and micro-organisms, thermal hazards (protection from extremes of cold and heat), electrical
hazards, mechanical hazards and appropriate degree of manual dexterity required to undertake an activity.
Whilst the content of this section may inform the choice of personal protective equipment used, the limitations of
any information which can be provided must be fully understood, e.g. personal protective equipment chosen to
protect employees from occasional splashes maybe entirely inadequate for activities involving partial or
complete immersion.If the levels of oil mist or vapour in air are likely to exceed the occupational exposure
standards then consideration should be given to the use of local exhaust ventilation to reduce personal
exposure.
The choice of personal protective equipment should only be undertaken in the light of a full risk assessment by
a suitably qualified competent person ( e.g. a professionally qualified occupational hygienist).
Effective protection is only achieved by correctly fitting and well maintained equipment and employers should
ensure that appropriate training is given. All personal protective equipment should be regularly inspected and
replaced if defective.
Respiratory Protection
Care should be taken to keep exposures below applicable occupational exposure limits. If this cannot be
achieved, use of a respirator fitted with an organic vapour cartridge combined with a particulate pre-filter should
be considered. Half masks (EN 149) or valved half masks (EN 405) in combination with type A2 (EN 141) and
P2/3 (EN 143) pre-filters maybe considered.
If product is subjected to elevated temperatures, half masks (EN 149) or valved half masks (EN 405) in
combination with type AX (EN 371) and P2/3 (EN 143) prefilters maybe considered.
Hand Protection
Chemical protective gloves are made from a wide range of materials, but there is no single glove material ( or
combination of materials) which gives unlimited resistance to any individual or combination of substances or
preparations. The extent of the breakthrough time will be affected by a combination of factors which include
permeation, penetration, degradation, use pattern ( full immersion, occasional contacts) and how the glove is
stored when not in use.
Theoretical maximum levels of protection are seldom achieved in practice and the actual level of protection can
be difficult to assess. Effective breakthrough time should be used with care and a margin of safety should be
applied. HSE guidance on protective gloves recommends a 75% safety factor to be applied to any figures
obtained in a laboratory test. Nitrile gloves may offer relatively long breakthrough times and slow permeation
rates. Test data, e.g breakthrough data obtained through test standard EN374-3:1994 are available from
reputable equipment suppliers.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly. A non perfumed moisturiser should be applied.
Eye Protection
Goggles conforming to a minimum standard of EN 166 345B should be considered if there is a possibility of eye
contact with the product through splashing. Higher rated eye protection must be considered for highly
hazardous operations or work areas. For example, employees involved in metalworking operations such as
chipping, grinding or cutting may require additional protection to avert injury from fast moving particles or broken
tools.
Body Protection
Minimise all forms of skin contact. Overalls and shoes with oil resistant soles should be worn. Launder overalls
and undergarments regularly.
Environmental Exposure Controls
Minimise release to the environment. An environmental assessment must be made to ensure compliance with
local environmental legislation.
9. PHYSICAL AND CHEMICAL PROPERTIES
Version No. 1.1 14/05/2003 Page 4 of 8
AeroShell Grease S.7108
Colour Tan.
Physical State Semi-solid at ambient temperature.
Odour Slight.
pH Value Data not available.
Vapour Pressure Data not available.
Solubility in Water Negligible.
Density 1100 kg/m3 at 15篊.
Flash Point >200篊 (COC) (Based on synthetic oil).
Flammable Limits - Upper Data not available.
Flammable Limits - Lower Data not available.
Auto-Ignition Temperature Data not available.
Vapour Density (Air=1) Data not available.
Partition co-efficient, n-octanol/water Data not available.
Pour Point Not applicable.
Dropping Point 149篊 (ASTM D-566).
Elements Content Barium <0.13%(m/m).
10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to Avoid
Extremes of temperature and direct sunlight.
Materials to Avoid
Strong oxidizing agents.
Hazardous Decomposition Products
Hazardous decomposition products are not expected to form during normal storage.
11. TOXICOLOGICAL INFORMATION
Basis for Assessment
Toxicological data have not been determined specifically for this product. Information given is based on a
knowledge of the components and the toxicology of similar products.
Acute Toxicity - Oral
LD50 expected to be > 2000 mg/kg.
Acute Toxicity - Dermal
LD50 expected to be > 2000 mg/kg.
Acute Toxicity - Inhalation
Not considered to be an inhalation hazard under normal conditions of use.
Eye Irritation
Expected to be slightly irritating.
Skin Irritation
Expected to be slightly irritating.
Version No. 1.1 14/05/2003 Page 5 of 8
AeroShell Grease S.7108
Respiratory Irritation
If vapours are inhaled, slight irritation of the respiratory tract may occur.
Skin Sensitisation
Not expected to be a skin sensitizer.
Carcinogenicity
Components are not known to be associated with carcinogenic effects.
Mutagenicity
Not considered to be a mutagenic hazard.
Reproductive Toxicity
Not considered to be toxic to reproduction.
Other Information
Prolonged and/or repeated contact with this product can result in defatting of the skin, particularly at elevated
temperatures. This can lead to irritation and possibly dermatitis, especially under conditions of poor personal
hygiene. Skin contact should be minimised. Used grease may contain harmful impurities that have accumulated
during use.The concentration of such harmful impurities will depend on use and they may present risks to health
and the environment on disposal. ALL used grease should be handled with caution and skin contact avoided as
far as possible.
12. ECOLOGICAL INFORMATION
Basis for Assessment
Ecotoxicological data have not been determined specifically for this product. Information given is based on a
knowledge of the components and the ecotoxicology of similar products.
Mobility
Semi-solid under most environmental conditions. Sinks in water. If it comes into contact with soil, it will strongly
adsorb to soil particles.
Persistence / Degradability
Not expected to be readily biodegradable. Major constituents are expected to be inherently biodegradable, but
the product contains components that may persist in the environment.
Bioaccumulation
Contains components with the potential to bioaccumulate.
Ecotoxicity
Poorly soluble mixture. May cause physical fouling of aquatic organisms. Product is expected to be practically
non-toxic to aquatic organisms, LL/EL50 >100 mg/l. (LL/EL50 expressed as the nominal amount of product
required to prepare aqueous test extract).
Other Adverse Effects
Not expected to have ozone depletion potential, photochemical ozone creation potential or global warming
potential.
13. DISPOSAL CONSIDERATIONS
Waste Disposal
Dispose into a suitable, clearly marked container for disposal or reclamation in accordance with local
regulations. The competence of the contractor to deal satisfactorily with this type of product should be
established beforehand. Do not pollute the soil, water or environment with the waste product. Note that this
product contains barium compounds.
Product Disposal
Version No. 1.1 14/05/2003 Page 6 of 8
AeroShell Grease S.7108
As for waste disposal.
Container Disposal
Recycle or dispose of in accordance with the legislation in force with a recognised collector or contractor.
14. TRANSPORT INFORMATION
Transport Information
Not dangerous for transport under ADR/RID, IMO and IATA/ICAO regulations.
15. REGULATORY INFORMATION
EC Symbols None.
EC Risk Phrase Not classified.
EC Safety Phrase Not classified.
EINECS All components listed or polymer exempt.
TSCA (USA) All components listed.
National Legislation
Environmental Protection Act 1990 (as amended).
Health and Safety at Work Act 1974
Consumers Protection Act 1987
Control of Pollution Act 1974
Environmental Act 1995
Factories Act 1961
Carriage of Dangerous Goods by Road and Rail (Classification, Packaging and Labelling) Regulations
Chemicals (Hazard Information and Packaging for Supply) Regulations 2002.
Control of Substances Hazardous to Health Regulations 1994 (as amended).
Road Traffic (Carriage of Dangerous Substances in Packages) Regulations
Merchant Shipping (Dangerous Goods and Marine Pollutants) Regulations
Road Traffic (Carriage of Dangerous Substances in Road Tankers in Tank Containers) Regulations
Road Traffic (Training of Drivers of Vehicles Carrying Dangerous Goods) Regulations
Reporting of Injuries, Diseases and Dangerous Occurences Regulations
Health and Safety (First Aid) Regulations 1981
Personal Protective Equipment (EC Directive) Regulations 1992
Personal Protective Equipment at Work Regulations 1992
Packaging & Labelling
Contains triazole derivatives. May produce an allergic reaction. Safety data sheet available for professional user
on request.
16. OTHER INFORMATION
Revisions Highlighted
No amendments made to information. To assist harmonisation of sds authoring practices, a version number has
been introduced.
References
European Model Code of Safe Practice in the Storage and Handling of Petroleum Products. EN 374-2:1994
Protective gloves against chemicals and micro-organisms
Version No. 1.1 14/05/2003 Page 7 of 8
AeroShell Grease S.7108
EN 149:2001 Respiratory protective devices - filtering half masks to protect against particles - requirements,
testing, marking
EN 405:1992 Respiratory protective devices - valved filtering half masks to protect against gases or gases and
particles - requirements, testing, marking.
EN 141:2000 Respiratory protective devices - gas filters and combined filters - requirements, testing, marking
EN 143:2000 Respiratory protective devices - particle filters - requirements, testing, marking
EN 166:1995 Personal eye-protection - specification.
Restrictions
This product must be used, handled and applied in accordance with the requirements of the equipment
manufacturer's manuals, bulletins and other documentation.
List of R Phrases in Section 2
R43 May cause sensitization by skin contact.
R36/38 Irritating to eyes and skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
Technical Contact Numbers
0151-350-4000.
Further Information
This information is based on our current knowledge and is intended to describe the product for the purposes of
health, safety and environmental requirements only. It does not constitute a guarantee for any specific property
of the product.
... End Of SDS ...
Version No. 1.1 14/05/2003 Page 8 of 8
|