1225 West Market St., Akron OH 44313
Phone: 330-869-0500, Fax: 330-869-0518
www.sovchem.net
Material Safety Data Sheet
Mixland ZDBC or Mixland+ ZDBC
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
MLPC International Emergency Contact :
209 Avenue Charles Despiau Chemtrec: 1-800-424-9300 (continental USA)
40370 Rion Des Landes (1)703-527-3887 (outside continental
France USA)
Trade Name(s): Mixland ZDBC or Mixland+ MSDS Number: 1649
ZDBC
Chemical Name: Zinc, bis Synonyms: Zinc Dibutyldithiocarbamate, ZDBC
(dibutylcarbamodithioato-S-S')
Prepared By: Sovereign Chemical Company Date of Issue: November 14, 2003
Revision Number: 2 (Supercedes September 1,
2000)
Change(s): Update transport information
2. INGREDIENTS
BRMA OSHA ACGIH
Component CAS # Percent (TLV) (PEL) (TLV)
8 mg/M3
Zinc, 136-23-2 60-90 NE NE
dibutyldithiocarbamate (total dust for ZDBC)
Proprietary binder Proprietary* 10-40** NE NE NE
system
*Binder system contains no known hazardous materials as defined by the OSHA Hazard Communication Standard
29 CFR 1910.1200.
**The percent of active ingredient and proprietary binder system is defined by the individual product name, for
example, Mixland ZDBC 75 would indicate 75% ZDBC active ingredient and 25% binder system.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Solid slabs or granules. Use appropriate personal protective equipment. During fire situations, irritating
and toxic gases may be generated. Keep from entering storm or sanitary sewers, ground water, or soil.
Product is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
Avoid contact with skin and eyes.
HMIS Rating: Health ?1, Flammability ?0, Reactivity ?0, Personal Protection Equipment ?E* - safety
glasses, gloves, dust mask
*This is recommended personal protection equipment, final personal protection equipment should be
determined by the plant safety department based on the actual conditions under which the product is used.
Potential Health Effects:
Eye: May cause irritation.
Skin Contact: May cause irritation. May cause sensitization by skin contact. Prolonged or repeated contact with
skin can cause eczema-life dermatitis.
Ingestion: May cause irritation..
Inhalation: May cause irritation. Dust inhalation may cause alcohol intolerance.
Chronic & Carcinogenicity: The product is not known to be carcinogenic. No IARC or NTP materials.
Specific Hazards: An adverse reaction can occur when exposed to this product in combination with alcohol.
NOTE ON DISPERSION FORM: This is a polymer bound dispersion form of an originally powder or pellet
material. Because it is a dispersion form and produces little or no dust, the potential health effects (eye, skin
contact, ingestion and inhalation) that are normally associated with powder or pellet materials are greatly
reduced.
4. FIRST AID MEASURES
Skin: Wash off immediately with plenty of soap and water. Seek medical advice in case of skin rash.
Eye: Rinse immediately with plenty of water for at least 15 minutes. If irritation persists, consult an
ophthalmologist.
Ingestion: Get medical help.
Inhalation: Remove to fresh air. Consult a doctor.
5. FIRE FIGHTING MEASURES
Flash Point: ND LEL: ND UEL: ND Auto Ignition Temperature: ND
Use water, dry powder or regular foam to extinguish fires. Product in or near fires should be cooled with a water
spray or fog. A self contained breathing apparatus (SCBA) operating in the positive pressure mode and full fire
fighting protective clothing should be worn for combating fires. During a fire the product can form sulfur oxides
and nitrogen oxides.
6. ACCIDENTAL RELEASE MEASURES
Take up any spilled product by mechanical means (avoid dust formation) and place into sealed containers for
proper disposal. Individuals involved in the cleanup should wear appropriate personal protective equipment. See
Section 8. Unnecessary personnel should be kept clear of the area. Keep from entering storm or sanitary sewers,
ground water, or soil. Dispose of waste materials including empty product bags or drums in accordance with Local,
State and Federal regulations. Avoid contact with skin and eyes.
7. HANDLING AND STORAGE
Storage Conditions: Do not store at high temperatures or near acids and oxidants. Store in closed containers in a
dry environment. Recommended packaging is cardboard box with polyethylene liner.
Handling: Good housekeeping and engineering practices should be employed to prevent the generation and
accumulation of dusts. Individuals handling this product should wear personal protective equipment specified in
Section 8. Plant environment should include controls and equipment specified in Section 8. Avoid contact with
skin and eyes.
8. EXPOSURE CONTROL - PERSONAL PROTECTION
Engineering Controls: Local exhaust ventilation should be provided. Design details for local exhaust ventilation
systems may be found in the latest edition of "Industrial Ventilation: A Manual of Recommended Practices"
published by the ACGIH Committee on Industrial Ventilation, P.O. Box 16153, Lansing, MI 48910. The need for
local exhaust ventilation should be evaluated by a professional industrial hygienist. Local exhaust ventilation
systems should be designed by a professional engineer.
Respiratory Protection: Dust mask recommended.
Eye Protection: Safety glasses with side shields are recommended. An eye wash device should be available in the
work area where the product is handled.
Sovereign Chemical Company Mixland ZDBC, MSDS # 1649 - Page 2 of 5
Document Number: SCCF 4.2.3-2.B Issue Number: 1
Protection Gloves: Neoprene or nitrile gloves should be worn to prevent irritation and possible absorption. Cloth
gloves are not recommended.
Other Protection Items: Neoprene or nitrile rubber coated apron or other body covering may be required if there is
a possibility of regular work clothing becoming contaminated with the product. All soiled or dirty clothing and
personal protective equipment should be thoroughly cleaned before reuse. A shower is recommended after
handling this product.
Do not consume alcohol, eat or smoke while handling this product. Antabuse effect.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State: Solid slabs or Melt Point: 105-110篊
granules
Vapor Density (Air = 1): Not applicable Octanol/Water Partition Coefficient: Not
established
Vapor Pressure: Not applicable Evaporation Rate BuOAC = 1: Not applicable
Odor: None Specific Gravity: 20篊: 1.05 g/cm3
% Volatile by Volume: Not applicable Boiling Point: Not applicable
% Solubility (H2O) : Insoluble in cold water. pH: Not applicable
Other: Soluble in acetone
10. STABILITY AND REACTIVITY
Stability /Polymerization: Stable
Incompatibility (conditions to avoid): High temperatures, oxidants and strong acids. Store protected from
moisture and heat.
Hazardous Decomposition Products: Thermal decomposition into toxic products.
Special Sensitivity: None that are known.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation: No data available.
Ingestion: LD50 (oral, rat) >5000 mg/kg
Skin-contact: LD50 (dermal, rabbit) > 2000 mg/kg
Local Effects:
Inhalation: Dust inhalation may cause alcohol intolerance.
Skin-contact: In animals (rabbits): after occlusive contact (24 hours), not irritating to skin.
Eye-contact: In animals (rabbits), slightly irritating to eyes.
Sensitization:
Skin-contact: Risk of sensitization by skin contact.
Chronic Toxicity: Experimental effects on animals (rat/oral, 4 months), no major effect until 200 mg/kg/day.
Specific Effects: Negative Ames-test. Absence of carcinogenic effects.
Further Information: Alcohol antabuse effect.
12. ECOLOGICAL INFORMATION
Aquatic Toxicity
Acute Toxicity: Daphnia Magna CE(I)50, 48 h: 0.74 mg/l (very toxic)
13. DISPOSAL CONSIDERATIONS
Sovereign Chemical Company Mixland ZDBC, MSDS # 1649 - Page 3 of 5
Document Number: SCCF 4.2.3-2.B Issue Number: 1
Product should be disposed of in an EPA approved incinerator in accordance with all local, state, and/or federal
regulations.
CERCLA/RCRA: This product does not meet the criteria outline in 40 CFR, Part 261, Supart B as a Hazardous
Waste Material according to the Resource Conservation and Recovery Act of 1976. Because this product is
considered a zinc compound [Zinc, bis (dibutylcarbamodithioato-S-S')] it is subjected to reporting under -
Superfund 40 CFR 302.4.
14. TRANSPORTATION INFORMATION
US DOT: Not regulated.
Canadian TDG: Not regulated
UN Number: None
IMDG: Not regulated when shipped from US
IATA: Not regulated when shipped from US
15. REGULATORY INFORMATION
CERCLA/RCRA: This product does not meet the criteria outline in 40 CFR, Part 261, Supart B as a Hazardous
Waste Material according to the Resource Conservation and Recovery Act of 1976. Because this product is
considered a zinc compound [Zinc, bis (dibutylcarbamodithioato-S-S')] it is subjected to reporting under -
Superfund 40 CFR 302.4.
SARA Section 313 Title III: Zinc, bis (dibutylcarbamodithioato-S-S') because it is considered a zinc compound is
subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 and 40 CFR Part 372.
WHMIS, NTP, IARC, Proposition 65 (CA), Clean Air: Not listed
TSCA: All ingredients are listed on the TSCA inventory.
Canadian DSL: All ingredients listed.
16. OTHER INFORMATION
NE = Not Established
NA = Not Applicable
ND = Not Determined
Information contained in this MSDS sheet have been gathered from the following documents:
Chemical REG-A-DEX, J.J.Keller, March 2000
WHMIS Compliance Manual, Carswell, April 2000
Transportation of Dangerous Good, J.J.Keller, February 2000
Code of Federal Regulations, Transportation, 49 CFR Parts 100 to 185, October 1998
NIOSH Pocket Guide to Chemical Hazards, June 1997
ACGIH Threshold Limit Values, 1999
HMIS Implementation Manual, 2nd Edition
Toxicity and Safe Handling of Rubber Chemicals, BRMA, 3rd Edition
ChemCheck Handbook, Specialty Technical Publishers, March 2000
IARC WEB site
NTP WEB site
IMPORTANT SAFETY NOTICE: The information in the Material Safety Data Sheet relates only to the specific material(s) described
herein and does not relate to use in combination with any other material or substance or in any process. We believe that the information contained
herein is current as of the date of issue of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use
of this product are not within the control of Sovereign Chemical Company, it is the user's obligation to determine the conditions of safe use of the
product.
Users of this product should study this Material Safety Data Sheet and become aware of the product hazards and safety information before using the
product. Users should also notify their employees, agents, and contractors of the information on this Material Safety Data Sheet and any product
hazards and safety information in order to provide safe use of this product.
Sovereign Chemical Company Mixland ZDBC, MSDS # 1649 - Page 4 of 5
Document Number: SCCF 4.2.3-2.B Issue Number: 1
Sovereign Chemical Company
341 White Pond Drive
Akron, OH 44320
Dear Customer:
Section 313 of SARA Title III (also known as the Emergency Planning and Community Right
Know Act, or EPCRA) require certain suppliers of mixtures or tradename products to notify their
customers when such mixtures or tradename products contain chemicals listed in Section 313.
This letter constitutes a supplier notification that the following product you ordered contains one
or more chemicals on the Section 313 list under zinc compounds (*) as noted below:
Product Name: Mixland ZDBC or Mixland+ ZDBC
Chemical Name (*) CAS # % Composition
Zinc, 1314-13-2 60-90
bis (dibutylcarbamodithioato-S-S') *
* Zinc, bis (dibutylcarbamodithioato-S-S') * is under the general category of zinc compounds.
In addition, an MSDS for this product is enclosed for your use.
If you are a distributor and you sell this product to another customer (s), you are required under
Section 313 to furnish the same information and MSDS to that customer (s).
If you have any questions, please do not hesitate to contact our Technical Department, Sovereign
Chemical Company at 330-869-0500.
Sovereign Chemical Company
Sovereign Chemical Company Mixland ZDBC, MSDS # 1649 - Page 5 of 5
Document Number: SCCF 4.2.3-2.B Issue Number: 1
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