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MSDS Material Safety Data Sheet
CAS

000136-45-8 134-62-3 113-48-4 121-33-5 110-27-0 8006-90-4 8000-29-1

File Name: 000136-45-8_134-62-3_113-48-4_121-33-5_110-27-0_8006-90-4_8000-29-1.asp

                           MATERIAL SAFETY DATA SHEET

PRODUCT NAME: POWERDEET 25 INSECT REPELLENT Page 1 of 4
Tec Laboratories, Inc. Issue Date: 11/1/04

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SECTION I - COMPANY AND PRODUCT INFORMATION
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MANUFACTURER: PRODUCT DESCRIPTION:
Tec Laboratories, Inc. Liquid Personal Insect Repellent
7100 Tec Labs Way SW
Albany, OR 97321 CHEMICAL FAMILY:
Pesticides
EMERGENCY TELEPHONE NUMBERS:
(541) 926-4577
24 Hour Emergency Assistance CAS NUMBER:
1-800-535-5053 Not available for this mixture

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SECTION II - HAZARDOUS INGREDIENTS
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This product contains the following toxic chemical subject to the reporting
requirements of section 313 of the Emergency Planning and Community Right-
To-Know Act of 1986 and of 40 CFR 372:

CAS # CHEMICAL NAME PERCENT BY WEIGHT

000136-45-8 Di-n-propyl isocinchomeronate 3.0%

HAZARD SUMMARY

Rating Definitions

Health 1 0 - least
Fire 1 1 - slight
Reactivity 0 2 - moderate
3 - high
4 - extreme

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SECTION III - COMPOSITION
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CAS NUMBER CHEMICAL NAME PERCENT BY WEIGHT

Active ingredients:

134-62-3 N,N-diethyl-m-toluaminde (DEET) 25%
113-48-4 n-octyl bicycloheptene dicarboximode 5%
136-45-8 Di-n-propyl isocinchomeronate 3%

Other ingredients:

121-33-5 Vanillin NF/FCC
110-27-0 Isopropyl myristate
8006-90-4 Peppermint oil
8000-29-1 Citronella oil
MATERIAL SAFETY DATA SHEET

PRODUCT NAME: POWERDEET 25 INSECT REPELLENT Page 2 of 4
Tec Laboratories, Inc. Issue Date: 11/1/04

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SECTION IV - HEALTH HAZARD AND FIRST AID INFORMATION
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OCCUPATION EXPOSURE LIMIT: Not established

CARCINOGENICITY: Not listed by NTP, IARC or OSHA

PRIMARY ROUTES OF ENTRY: Skin, inhalation

SYMPTOMS AND EFFECTS EMERGENCY AND FIRST AID
OF OVEREXPOSURE ROUTE OF ENTRY PROCEDURES

Can cause temporary minor EYES Immediately flush with large
conjunctivitis. amounts of water for 15
minutes. If irritation
persists, get medical
attention.

SKIN Remove contaminated clothing
Can cause minimal temporary
and wash affected areas with
irritation, especially on
soap and water. If
areas occluded from air
irritation persists, get
(inside gloves, under watch
medical attention.
bands, etc.)

INHALATION Immediately remove to fresh
Harmful if inhaled. Avoid
air. If breathing has
breathing spray mist. Do not
stopped, give mouth-to-mouth
spray indoors.
resuscitation. Get immediate
medical attention.


INGESTION Do NOT induce vomiting. Give
Can cause stomach irritation,
affected person two glasses
resulting in nausea, cramps,
of water. Keep them warm and
and diarrhea.
quiet and get medical
attention immediately.


Acute Dermal Toxicity - no deaths at 5.0 gm/kg (rabbits)
Acute Oral Toxicity - LD50 = 5,600 mg/kg (rats)
Acute Inhalation Toxicity - LC 50 = 1.30 mg/L

NOTE TO PHYSICIAN: There is no specific antidote. Treatment of over-exposure
should be directed at the control of symptoms and the clinical condition.
MATERIAL SAFETY DATA SHEET

PRODUCT NAME: POWERDEET 25 INSECT REPELLENT Page 3 of 4
Tec Laboratories, Inc. Issue Date: 11/1/04

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SECTION V - PERSONAL PROTECTION INFORMATION
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--WHEN HANDLING BULK QUANTITIES--

EYE PROTECTION: OSHA approved safety glasses, goggles or face shield.

PROTECTIVE CLOTHING: Wear rubber gloves. To avoid excessive exposure, wear
impervious boots and clothing.

VENTILATION: Mechanical ventilation should be used when handling this product in
enclosed areas.

RESPIRATORY PROTECTION: In the absense of proper ventilation, use a respirator
approved by NIOSH/OSHA for use with pesticides and organic solvents.

--WHEN USING PRODUCT ACCORDING TO DIRECTIONS FOR USE--

EYE PROTECTION: None required. Avoid applying product in and around eyes.

PROTECTIVE CLOTHING: None required for normal use.

VENTILATION: Apply in well ventilated areas. Do not spray indoors.

RESPIRATORY PROTECTION: None required. Do not spray indoors.

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SECTION VI - STORAGE AND SPECIAL HANDLING INFORMATION
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Store containers upright and closed. Store in cool, dry and well ventilated
areas. Keep away from heat, ignition sources and strong oxidizers. Do not
contaminate water, feed or food by storage, handling, or disposal. Read and
observe all precautions and instructions on the product label.

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SECTION VII - SPILL OR LEAK RESPONSE INFORMATION
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PRECAUTIONS IN CASE OF SPILLS OR LEAKS: Eliminate all ignition sources. Contain
the spill (prevent this product from reaching surface waters or other water
supplies). Soak up the spill with an appropriate absorbent and transfer into
waste containers for disposal. Clean the spill area with detergent and water.

WASTE DISPOSAL METHOD: Contaminated absorbent and wash water should be
disposed of according to local, state, and federal regulations.

RCRA/CERCLA HAZARDOUS WASTE: This product contains no hazardous waste.
MATERIAL SAFETY DATA SHEET

PRODUCT NAME: POWERDEET 25 INSECT REPELLENT Page 4 of 4
Tec Laboratories, Inc. Issue Date: 11/1/04

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SECTION VIII - FIRE AND EXPLOSION HAZARD INFORMATION
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FLASH POINT (open cup): >300EF

FLAMMABLE LIMITS: Not established.

EXTINGUISHING MEDIA: Foam, carbon dioxide or dry chemical.

UNUSUAL FIRE AND EXPLOSION HAZARDS: None.

SPECIAL FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-
contained breathing apparatus along with full protective gear. Keep nearby
containers and equipment cool with a water spray. Contain the run-off, if
possible, for proper disposal.

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SECTION IX - REACTIVITY INFORMATION
*********************************************************************************

STABILITY: Stable.

INCOMPATIBILITY (MATERIALS TO AVOID): Contact with strong oxidizers may produce
an explosive situation. Product acts as a plasticizer; avoid contact with
synthetic materials.

HAZARDOUS DECOMPOSITION PRODUCTS: Unknown.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Water, heat, acidic or alkaline conditions may cause this
product to break down.

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SECTION X - PHYSICAL DATA
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APPEARANCE: Clear, slightly yellow liquid.

ODOR: Vanilla fragrance.

SOLUBILITY IN WATER (% by weight): Insoluble.

SPECIFIC GRAVITY: 0.89 @ 25EC

BOILING POINT: > 300EF

VISCOSITY: 12 centipoise

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