Material Safety Data Sheet
Zep Inc. Section 1. Chemical Product and Company Identification
1310 Seaboard Industrial Blvd.
Product name
Atlanta, GA 30318 ZEP INSECT REPELLENT WITH
1-877-793-7776
DEET
Aerosol Insect Repellent
Product use
R058
Product code
Date of issue Supersedes
08/14/08
This product is a registered pesticide. EPA ID No. 1021-1600-1270
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-793-7776
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
WARNING ! 1 4 0
CAUSES EYE IRRITATION. HARMFUL IF SWALLOWED.
CONTENTS UNDER PRESSURE.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Eye contact. Inhalation.
Acute Effects Routes of Entry
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching.
Eyes
No known significant effects or critical hazards. May cause allergic reactions in certain
Skin
individuals.
Inhalation Avoid direct inhalation of spray. Over-exposure by inhalation may cause respiratory irritation.
Ingestion Harmful if swallowed. Can cause gastrointestinal disturbances.
Contains material which may cause damage to the following organs: kidneys, liver, ears.
Chronic effects
Additional Information: See Toxicological Information (Section 11)
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
This product is formulated for use on skin but should be rinsed off when possible. Get medical attention if
Skin Contact
irritation develops.
Move exposed person to fresh air. If irritation persists, get medical attention.
Inhalation
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do
Ingestion
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
If affected person is conscious, give plenty of water to drink. Never give anything by mouth to an unconscious
person. Get medical attention immediately.
Page: 1/4
Product Name ZEP INSECT REPELLENT WITH
Material Safety Data Sheet
Product code R058
DEET
National Fire Protection Association (U.S.A.)
Section 5. Fire Fighting Measures
4
Not applicable
Flash Point 1 0
Flammable Limits Not available.
Extremely flammable. (CSMA Method)
Flammability
CONTENTS UNDER PRESSURE. Flammable liquid and vapor. Vapors may accumulate in
Fire hazard
low or confined areas or travel a considerable distance to a source of ignition and flash back. In
a fire or if heated, a pressure increase will occur and the container may burst. Bursting aerosol
containers may be propelled from a fire at high speed.
Use an extinguishing agent suitable for the surrounding fire. Cool containers with water jet in
Fire-Fighting
order to prevent pressure build-up, auto-ignition or explosion.
Procedures
Section 6. Accidental Release Measures
Large spills are unlikely due to packaging.
Spill Clean up
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame
Handling
or any other ignition source. Avoid contact with eyes. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wash thoroughly after handling. Apply this product only as specified on the label.
CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Store away from direct sunlight in a dry, cool and
Storage
well-ventilated area, away from incompatible materials (see section 10) and food and drink. Store below 120癋 (49癈).
Avoid all possible sources of ignition (spark or flame). Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
ISOPROPYL ALCOHOL; ipa; dimethylcarbinol; 2-propanol ACGIH TLV (United States).
TWA: 200 ppm 8 hour(s).
OSHA PEL (United States).
TWA: 400 ppm 8 hour(s).
ACGIH/OSHA (United States).
STEL: 400 ppm 15 minute(s).
HYDROCARBON PROPELLANT; blend of propane & isobutane ACGIH TLV / OSHA PEL (United States). Notes: Propane
TWA: 1000 ppm 8 hour(s).
ACETONE; dimethyl ketone ACGIH TLV / OSHA PEL (United States).
TWA: 750 ppm 8 hour(s).
ACGIH / OSHA (United States).
STEL: 1000 ppm 15 minute(s).
Personal Protective Equipment (PPE)
No special protection is required.
Eyes
No special protective clothing is required.
Body
Respiratory Avoid direct inhalation of spray. Use with adequate ventilation.
Section 9. Physical and Chemical Properties
Liquid. [Aerosol.] Color Clear.
Physical State
Not applicable Odor Mild. Characteristic.
pH
Not determined. Vapor Pressure Not determined.
Boiling Point
0.89 Vapor Density >1 [Air = 1]
Specific Gravity
Very slightly soluble in the following materials: cold Evaporation Rate <1 (Ether (anhydrous). = 1)
Solubility
water and hot water.
VOC (Consumer) 555.29 (g/l). 4.63 lbs/gal 62.50%
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Keep away from heat, sparks and flame. Slightly reactive or incompatible with the following
Incompatibility
materials: oxidizing materials, acids and alkalis.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products carbon oxides (CO, CO2), nitrogen oxides (NO, NO2 etc.)
Page: 2/4
Product Name ZEP INSECT REPELLENT WITH
Material Safety Data Sheet
Product code R058
DEET
Section 11. Toxicological Information
Acute Toxicity
Exposure
Product/ingredient name Result Species Dose
Isopropyl Alcohol LD50 Dermal Rabbit 13000 mg/kg -
LD50 Oral Rat 4700 mg/kg -
LC50 Inhalation Vapor Rat 22500 ppm 8 hours
LC50 Inhalation Vapor Rat 19000 ppm 8 hours
DIETHYLTOLUAMIDE LD50 Oral Rabbit 3180 mg/kg -
LD50 Oral Rat 1950 mg/kg -
LC50 Inhalation Vapor Rat 5950 mg/m? 8 hours
Acetone LD50 Dermal Rabbit 20000 mg/kg -
LD50 Oral Mouse 9750 mg/kg -
LC50 Inhalation Vapor Rat 16000 ppm 4 hours
Section 12. Ecological Information
No known significant effects or critical hazards.
Environmental Effects
Aquatic Ecotoxicity
Product/ingredient name Test Result Species Exposure
DIETHYLTOLUAMIDE - Acute EC50 75 mg/L Daphnia 48 hours
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or
regional authorities for additional information.
Waste Stream Code: D001
Classification: - [Hazardous waste]
Origin: - [RCRA waste.]
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label
DOT Classification Not available. Consumer commodity ORM-D
Not determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
Product name
Dipropyl isocinchomeronate
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
WARNING: This product contains a chemical or chemicals known to the state
California Prop 65
of California to cause cancer, birth defects or other reproductive harm.:
Dipropyl isocinchomeronate
Page: 3/4
Product Name ZEP INSECT REPELLENT WITH
Material Safety Data Sheet
Product code R058
DEET
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to
relay the meanings of this scale.