MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
TRADE NAME:
3M EC-3439
ID NUMBER/U.P.C.:
62-3439-6540-6 00-21200-85070-7 62-3439-7501-7 00-21200-64907-3
62-3439-8501-6 00-21200-20822-5
ISSUED: May 29, 2001
SUPERSEDES: November 25, 1997
DOCUMENT: 11-1352-1
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1. INGREDIENT C.A.S. NO. PERCENT
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GLASS BUBBLES........................... None 30.0 - 40.0
MEMTETRAHYDROPHTHALIC ANHYDRIDE......... 25134-21-8 20.0 - 30.0
EPOXY RESIN............................. 25068-38-6 10.0 - 20.0
FLAME RETARDANT......................... 13560-89-9 10.0 - 20.0
EPOXY RESIN............................. 9072-62-2 10.0 - 20.0
ANTIMONY TRIOXIDE....................... 1309-64-4 1.0 - 10.0
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
ANTIMONY TRIOXIDE
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2. PHYSICAL DATA
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BOILING POINT:................. N/A
VAPOR PRESSURE:................ N/A
VAPOR DENSITY:................. N/A
EVAPORATION RATE:.............. N/A
SOLUBILITY IN WATER:........... Not soluble
SPECIFIC GRAVITY:.............. 0.500 Water=1
PERCENT VOLATILE:.............. 0.00 % by wt
pH:............................ N/A
VISCOSITY:..................... N/A
MELTING POINT:................. N/D
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M EC-3439
May 29, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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APPEARANCE AND ODOR:
non-flow paste, off-white, epoxy odor.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... N/A
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Not applicable.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 0 REACTIVITY: 1
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Hydrogen Chloride, Phosgene,
Chlorine.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M EC-3439
May 29, 2001 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Collect spilled material. Place in a
U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate uncured waste in an industrial or commercial incinerator.
Dispose of completely cured (or polymerized) material in a sanitary
landfill.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: N/A.
VOC Less H2O & Exempt Solvents: N/D.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Immediately wash skin with soap and large amounts of water. Remove
contaminated clothing. If signs/symptoms occur, call a physician.
Wash contaminated clothing before reuse and dispose of contaminated
shoes.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M EC-3439
May 29, 2001 PAGE 4
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear vented goggles. Wear safety glasses with
side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: polyethylene/ethylene vinyl alcohol, polyvinyl alcohol.
RECOMMENDED VENTILATION:
Use with appropriate local exhaust ventilation. Provide appropriate
local exhaust for grinding, cutting or sanding cured material.
Curing ovens must be exhausted to outdoors or to a suitable emission
control device. If exhaust ventilation is not adequate, use
appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors created during the cure cycle. Avoid
breathing of dust created by cutting, sanding or grinding. Select
one of the following NIOSH approved respirators based on airborne
concentration of contaminants and in accordance with OSHA
regulations: half-mask dust respirator
Use water as a lubricant on machining tools to eliminate dust and
improve machinability of cured parts.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
RECOMMENDED STORAGE:
Store at temperatures which are below 32 degrees F (0 degrees C).
Allow material to return to room temperature before use. Keep out of
the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Not applicable.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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GLASS BUBBLES........................ NONE NONE NONE NONE
MEMTETRAHYDROPHTHALIC ANHYDRIDE...... NONE NONE NONE NONE
EPOXY RESIN.......................... NONE NONE NONE NONE
FLAME RETARDANT...................... NONE NONE NONE NONE
EPOXY RESIN.......................... NONE NONE NONE NONE
ANTIMONY TRIOXIDE.................... 0.5 MG/M3 TWA ACGIH
as Sb
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M EC-3439
May 29, 2001 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
Vapors from heated material may cause eye irritation.
Dust created by cutting, grinding, sanding, or machining may cause
eye irritation.
SKIN CONTACT:
Allergic Skin Reaction: signs/symptoms can include redness, swelling,
blistering, and itching.
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
INHALATION:
Vapors of heated material may cause respiratory system irritation.
Dust from cutting, grinding, sanding or machining may cause
irritation of the respiratory system.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
CANCER:
WARNING: Contains a chemical which can cause cancer. (1309-64-4)
(ACGIH suspected human carcinogen A2, IARC possible human carcingen
2B, Calif. Proposition 65)
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M EC-3439
May 29, 2001 PAGE 6
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SECTION CHANGE DATES
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HEADING SECTION CHANGED SINCE November 25, 1997 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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