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MSDS Material Safety Data Sheet
CAS

6840-01-0 134-62-3 113-48-4 136-45-8

File Name: 6840-01-0_134-62-3_113-48-4_136-45.asp

DEET PLUS                                                                                                                 NSN 6840-01-003-9589

MATERIAL SAFETY DATA SHEET

Insect Guard II


1. Company Identification
Manufacturer
Associated Registrations, Inc. Sawyer Products
Safety Harbor FL 34695 Safety Harbor FL 34695


Telephone Number: 800-356-7811 Product Description: Personal Insect Repellent
Fax Number: 727-725-1954 EPA Registration No.: 54287-8
Emergency Telephone Number: 800-356-7811 Product Code: None Assigned

Issue Date 5-Sep-06
Replaces Issue Date: 2 17-Aug-06

2. Composition/Information on Ingredients
Chemical Name CAS Number Percent
Deet 134-62-3 17.50
N-octyl bicycloheptene dicarboximide 113-48-4 5.00
Di-n-propyl isocinchomeronate 136-45-8 2.50
Inert Ingredients Not Established 75.00
Ingredients not identified are proprietary or nonhazardous. Values are not product specifications.


3. Hazards Identification
Primary Route(s) of Entry
None Known
Eye Hazards: Not a primary eye irritant, but contact with eyes may cause mild, transient irritation.
Skin Hazards:: None Known
Ingestion Hazards: None Known
Inhalation Hazards: None Known

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.

Remove contact lenses, if worn.

Call a medical officer, poison control center or doctor for further treatment advice.

Ingestion
If swallowed, consult a physician immediately.

Signs And Symptions Of Overexposure: Eye Contact: Redness, Swelling, Pain, Tearing, and Hazy Vision.
In rare occasions, children have had reactions characterized by diarrhea and vomiting from gross overexposure
to deet, the active ingredient in this product.

5. Fire Fighting Measures
Flash Point: >200癋 Flash Point Method: TCC
Lower Explosive Limit: NE Upper Explosive Limit: NE

Fire and Explosion Hazards
None Known

Extinguishing Media
In case of fire, use water spray, CO2, Dry Chemical, or Foam

Fire Fighting Instructions
None Known




Page 1 of 3
DEET PLUS NSN 6840-01-003-9589
6. Accidental Release Measures
Soak up with absorbent, shovel into waste container, flush area with water.



7. Handling and Storage
Handling and Storage Precautions
Do not store over 160癋. Material may separate.

Handling Precautions
Avoid contact with eyes and lips.

Storage Precautions
Keep away from heat.

Work/Hygienic Practices
Follow Label Directions.

8. Exposure Controls/Personal Protection
Engineering Controls: None Known
Eye/Face Protection: None Known
Skin Protection: Non Known
Respiratory Protection: None normally required

9. Physical and Chemical Properties
Appearance: Peach Cream Melting Point: Not applicable
Odor: Slighly sweet fragrance Boiling Point: Not applicable
Specific Gravity: .99 % Low VOC: Not applicable
% Medium VOC: Not applicable Solubility: Oil: NA Water: NA
Evaporation Rate: Not applicable Shelf Life: 4 years

10. Stability and Reactivity
Stable

Stability:
Will not occur

Hazardous Polymerization:

Condition to Avoid (Stability)
Do not store when temperatures exceed 160?F. Exposure to temperatures above 160?F may cause material
to separate.

Incompatible Materials
None Known

Hazardous Decomposition Products
None Known

Conditions to Avoid
None Known

11. Toxicological Information
No Data Available

12. Ecological Information
No Data Available

13. Disposal Considerations
Dispose of in accordance with all applicable Federal, State and Local regulations. Material collected with absorbent may
be disposed of in a permitted landfill in accordance with Federal, State, and Local reulations.




Page 2 of 3
DEET PLUS NSN 6840-01-003-9589
14. Transport Information
U.S. Department of Transportation (DOT) information: Not considered hazardous by DOT Title 49
regulations. Proper Shippng Name: N/A. Hazard Class: N/A. Identification Number (UN or NA): NA
Packing Group: N/A. International Transportion Reulations: ICAO/IATA Description: Not considered
hazardous by IATA regulations for tranportation via air. IMO Description (IMDG Code): Not considered
harardous by IMO Regulations for Transportation via vessel.

15. Regulatory Information
US Regulatory Information
This product is a pesticide and is exempt from the US Toxic Substances Control Act (TSCA) Chemical Substance Inventory


EPA Reg. No.: 54287-8


SARA Section 313 Notification
This product does not contain any ingredients regulated under Section 313 of the Emergency Planning and Community Right-To-Know
Act of 1986 or 40 CFR 372


16. Other Information
Precautionary Label
WARNING: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE IRRITATION
Wash thoroughly after handling and before eating or smoking.

Disclaimer
The information contained herein is believed to be accurate whether originating with Associated Registrations or not.
Associated Registrations provides no warranty either express or implied, and assumes no responsibility for the
accuracy or completeness of the data. Recipients are advised to confirm any data, in advance of need, that it is current,
applicable, and suitable to their circumstances.




Page 3 of 3
MATERIAL SAFETY DATA SHEET
Page 1 of 4
Coulston Products Inc. Date-Issued: 08/31/1997
P.O. Box 30 MSDS Ref. No: 01
Easton, PA 18044 Date-Revised: 05 sep 2006
Revision No: 03
DURANON INSECT REPELLENT

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: DURANON INSECT REPELLENT
PRODUCT DESCRIPTION: Personal Insect Repellent.
PRODUCT CODE: None Assigned EPA REGISTRATION NO.: 50404-8
MANUFACTURER: Coulston Products Incorporated
Product Stewardship: 1-800-940-4464
Customer Service: 1-800-940-4464
24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC U.S. and CANADA: (800) 424-9300
CHEMTREC All Other Areas: (703) 527-3887
Emergency Phone (888) 740-8712
COMMENTS:
For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call the
INTERNATIONALPOISON CENTER at 1-888-740-8712 24 hrs a day.

2. COMPOSITION / INFORMATION ON INGREDIENTS

Wt.% CAS# ACGIH TLV
N,N-diethyl-m-Toluamide (DEET) 20 134-62-3 N/A

COMMENTS:
Ingredients not identified are proprietary or nonhazardous. Values are not product specifications.

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:

CAUTION: Avoid contact with eyes. Use of this product may cause skin reactions in rare cases. Prolonged or

frequently repeated skin contact may cause allergic reaction in some individuals. Wash treated clothing before

wearing it again. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet..

POTENTIAL HEALTH EFFECTS
EYES: May cause eye injury.

SKIN: Avoid contact with eyes and lips. May cause skin reaction in rare cases.

INGESTION: Harmful if swallowed.

INHALATION: Avoid breathing spray mist or using in an enclosed area.

CHRONIC: Not established


4. FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,

after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

INGESTION: If swallowed, call poison control center or doctor immediately for treatment advice. Have person sip a

glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor.

Do not give anything by mouth to an unconscious person.

INHALATION: Remove affected person to fresh air. If breathing has stopped, administer artificial respiration and

seek medical attention immediately.

If you suspect a reaction to this product:
Discontinue use; Take off contaminated clothing; Rinse skin immediately with plenty of water for 15-20 minutes;
Call a poison control center or doctor for treatment advice.
MATERIAL SAFETY DATA SHEET
Page 2 of 4
Coulston Products Inc. Date-Issued: 08/31/1997
P.O. Box 30 MSDS Ref. No: 01
Easton, PA 18044 Date-Revised: 05 sep 2006
Revision No: 03
DURANON INSECT REPELLENT

5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: 170癋 TCC
FLAMMABLE LIMITS: Lower: NE Upper: NE
AUTOIGNITION TEMPERATURE: NA
FIRE EXTINGUISHING MEDIA: CO2, Foam or Dry Chemical

FIRE FIGHTING PROCEDURES:

Use a full-faced self-contained breathing apparatus along with full protective gear. Keep nearby containers and

equipment cool with a water stream.


6. ACCIDENTAL RELEASE MEASURES
Wipe up with absorbent material. Wash small quantities away with soapy water. Prevent bulk quantities from
entering open sewers and waterways.
Waste Disposal:
Dispose of all wastes in accordance with Federal, state and local regulations.

7. HANDLING AND STORAGE PRECAUTIONS
Do not store where temperature exceeds 130癋

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Mechanical ventilation should be used when handling this product in enclosed spaces. Local exhaust ventilation may
be necessary.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear OSHA-approved safety glasses, goggles or face shield.

SKIN: Wear chemically impervious gloves such as Neoprene or Nitrile and protective clothing.

RESPIRATORY: In absence of proper mechanical ventilation, wear a NIOSH approved organic vapor respirator.

PROTECTIVE CLOTHING: Wear chemically impervious gloves, such as neoprene or nitrile. Wear leather shoes

and long pants and long sleeve shirt.

WORK HYGIENIC PRACTICES:

DO NOT SMOKE, EAT OR DRINK OR APPLY COSMETICS IN WORK AREA! Wash promptly if skin

becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet.


9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Lotion
ODOR: Slight (deet)
APPEARANCE: Milky white
pH: 7.1 ?7.25
PERCENT VOLATILE: Not Available
VAPOR DENSITY: Not Available
BOILING POINT: Not Available
FREEZING POINT: Not Available
MELTING POINT: Not Applicable
SOLUBILITY IN WATER: Miscible
SPECIFIC GRAVITY: 0.98 (water=1) at 20癈
EVAPORATION RATE: Not Available
MATERIAL SAFETY DATA SHEET
Page 3 of 4
Coulston Products Inc. Date-Issued: 08/31/1997
P.O. Box 30 MSDS Ref. No: 01
Easton, PA 18044 Date-Revised: 05 sep 2006
Revision No: 03
DURANON INSECT REPELLENT

10. STABILITY AND REACTIVITY
STABLE: YES HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: Temperatures above 130癋

11. TOXICOLOGICAL INFORMATION
GENERAL COMMENTS: No data available.

COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are

listed by IARC, NTP, OSHA or ACGIH as being carcinogens.


12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: None Available

13. DISPOSAL CONSIDERATIONS
Pesticide Storage: Store in a cool and dry place. Keep out of reach of children.

If empty: Do not reuse container. Place in trash or offer for recycling if available.

If partly filled: Call your local solid waste agency or 1-800-CLEANUP for disposal instructions.


14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Consumer Commodity
PRIMARY HAZARD CLASS/DIVISION: ORM-D

15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)

311/312 HAZARD CATEGORIES:

FIRE: NO PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: NO

313 REPORTABLE INGREDIENTS: None

302/304 EMERGENCY PLANNING

EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this

formulation. (40 CFR 355). There are no components that are subject to emergency requirements under CERCLA

Section 103(a)(40 CFR 302.4) in this formulation.


TSCA (TOXIC SUBSTANCE CONTROL ACT)

TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control ACT

inventory reporting requirements.

MATERIAL SAFETY DATA SHEET
Page 4 of 4
Coulston Products Inc. Date-Issued: 08/31/1997
P.O. Box 30 MSDS Ref. No: 01
Easton, PA 18044 Date-Revised: 05 sep 2006
Revision No: 03
DURANON INSECT REPELLENT

16. OTHER INFORMATION
REVISION SUMMARY: Updated MSDS
HMIS CODES
FIRE: 0 HEALTH: 2 REACTIVITY: 0

HMIS RATINGS NOTES:
We assign HMIS ratings to this product based on the hazards of its ingredients(s). Since the customer is most aware
of the applications and conditions of use, he must ensure that the proper personal protective equipment is provided
consistent with the information contained in sections 7 and 8 of this MSDS.

COMMENTS:
The data contained herein is based on information currently available to Coulston Products Inc. and believed to be

factual and the opinions expressed to be those of qualified experts; however, this data is not to be taken as a

warranty or representation for which Coulston Products Inc. assumes legal responsibility.

MSDS Prepared by Scientific Coordination, Inc.

Page 1 of 1
PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

DermAegis LipoDEET Insect
CAUTION


Repellent 302
Avoid contact with eyes. Use of this product may cause skin reactions in rare cases. Prolonged or frequently repeated skin contact
may cause allergic reaction in some individuals. Wash treated clothing before wearing it again. Wash hands before eating,
drinking, chewing gum, using tobacco or using the toilet.
Provides Protection Against Mosquitoes for Up to 4 Hours
FIRST AID

30% DEET

?Call a poison control center or doctor immediately for treatment advice.
If Swallowed
Insect Repellent z Lotion z Repels Mosquitoes
?Have person sip a glass of water if able to swallow.
?Do not induce vomiting unless told to do so by the poison control center or doctor.
Odorless After Application

?Do not give anything by mouth to an unconscious person.
Repels biting insects for up to 4 hours

?Hold eye open and rinse slowly and gently with water for 15-20 minutes.
If In Eyes
Effective Unscented Protection From Mosquitoes, Gnats,
?Remove contact lenses, if present, after the first 5 minutes, continue rinsing the eye.
No-See-Ums, Sand Flies, Biting Flies, Deer Flies, Stable

?Call a poison control center or doctor for treatment advice.
Flies, Black, Flies, Ticks, Chiggers, Red Bugs and Fleas


?Discontinue use.
If you suspect
Just the right protection around the home and backyard

?Take off contaminated clothing.
a reaction to
Non-greasy zNon Staining zResists Perspiration
?Rinse skin immediately with plenty of water for 15-20 minutes.
this product
?Call a poison control center or doctor for treatment advice.
Have the product container or label with you when calling a poison control center or doctor or going for treatment.
ACTIVE INGREDIENTS:
Questions ???: 858-259-5659
DEET (CAS No. 134-62-3) ..................... 30.00%
OTHER INGREDIENTS ....................
70.00%
TOTAL: 100.00% NOTE: The First Aid statement's grid format will be used if market label space permits; otherwise a paragraph format will be
used.
DIRECTIONS FOR USE
KEEP OUT OF REACH OF CHILDREN


It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read and follow all directions and
WARNING

precautions on this product label. SHAKE WELL BEFORE USING.
Skin application: Squeeze into one hand, rub hands together and apply thoroughly in a thin layer to the forearms. Use additional
SEE BACK PANEL FOR ADDITIONAL

lotion for upper arms. Repeat for other exposed areas. To apply to face, squeeze lotion into palm of hand and spread on face and
PRECAUTIONARY STATEMENTS

neck. Do not apply near eyes and mouth. Apply sparingly around ears. Do not apply to children's hands. Do not apply over cuts,
wounds or irritated skin. When using on children, apply to your own hands and then put it on the child. Do not allow children to
handle this product. Use just enough repellent to cover exposed skin and/or clothing. Wipe excess from hands after applying. Do
not use under clothing. Avoid over-application of this product. Frequent reapplication and saturation is unnecessary for
effectiveness. After returning indoors wash treated skin with soap and water. May damage certain synthetic fabrics, acetate,
spandex and nylon. If you suspect a reaction to this product, discontinue use, wash treated skin, and call your local poison control
Net Contents oz..

center. If you go to a doctor, take this product with you.

STORAGE AND DISPOSAL

Pesticide Storage: Store in a cool and dry place. Keep out of reach of children.

If empty: Do not reuse this container. Place in trash or offer for recycling if available. If partly filled: Call your local solid waste

agency or 1-800-CLEANUP for disposal instructions. Never place unused product down any indoor or outdoor drain.


EPA Reg. No. 82810-1 EPA Est. No. 54287-FL-01

DermAegis, Inc.

4747 Plummer Ct.

San Diego, CA 92130


102506LipoDEETCorrectedLABEL
MATERIAL SAFETY DATA SHEET
Page 1 of 4
DermAegis, Inc. Date-Issued: 02/02/2005
5730 Clarendon Drive MSDS Ref. No: 01
Rockford, IL 61114 Date-Revised: 05 SEP 2006
Revision No: 02
LIPODEET INSECT REPELLENT FORMULA 302

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: LIPODEET INSECT REPELLENT FORMULA 302
PRODUCT DESCRIPTION: Personal Insect Repellent Lotion.
PRODUCT CODE: 302 EPA REGISTRATION NUMBER: 82810-1
MANUFACTURER: DermAegis, Incorporated
Product Stewardship: 815-877-2313
Customer Service: 815-877-2313
24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC U.S. and CANADA: 815-877-2313
CHEMTREC All Other Areas: (703) 527-3887
Emergency Phone 815-877-2313
COMMENTS:
For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call the
INTERNATIONALPOISON CENTER at 1-888-740-8712 24 hrs a day.

2. COMPOSITION / INFORMATION ON INGREDIENTS

Wt.% CAS# ACGIH TLV
N,N-diethyl-m-Toluamide (DEET) 30 134-62-3 N/A
Phospholipid-containing membrane plus
Other inert ingredients ~70 N/E N/E
COMMENTS:
Ingredients not identified are proprietary or nonhazardous. Values are not product specifications.

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:

WARNING: Harmful if swallowed. May cause eye injury. Avoid contact with eyes and lips. May cause skin

reaction in rare cases. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet.

POTENTIAL HEALTH EFFECTS
EYES: May cause eye injury.

SKIN: Avoid contact with eyes and lips. May cause skin reaction in rare cases.

INGESTION: Harmful if swallowed.

INHALATION: Avoid breathing spray mist or using in an enclosed area.

CHRONIC: Not established


4. FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,

after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

INGESTION: If swallowed, call poison control center or doctor immediately for treatment advice. Have person sip a

glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor.

Do not give anything by mouth to an unconscious person.

INHALATION: Remove affected person to fresh air. If breathing has stopped, administer artificial respiration and

seek medical attention immediately.

If you suspect a reaction to this product:
Discontinue use; Take off contaminated clothing; Rinse skin immediately with plenty of water for 15-20 minutes;
Call a poison control center or doctor for treatment advice.
MATERIAL SAFETY DATA SHEET
Page 2 of 4
DermAegis, Inc. Date-Issued: 02/02/2005
5730 Clarendon Drive MSDS Ref. No: 01
Rockford, IL 61114 Date-Revised: 05 SEP 2006
Revision No: 02
LIPODEET INSECT REPELLENT FORMULA 302

5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: N/E
FLAME EXTENSION: N/A
FLAMMABLE LIMITS: Lower: N/E Upper: N/E
AUTOIGNITION TEMPERATURE: N/E
FIRE EXTINGUISHING MEDIA: CO2, Foam or Dry Chemical

FIRE FIGHTING PROCEDURES:

Use a full-faced self-contained breathing apparatus along with full protective gear. Keep nearby containers and

equipment cool with a water stream.


6. ACCIDENTAL RELEASE MEASURES
Wipe up with absorbent material. Wash small quantities away with soapy water. Prevent bulk quantities from
entering open sewers and waterways.
Waste Disposal:
Dispose of in accordance with local, state and Federal regulations. Do not incinerate empty container, dispose of
properly.

7. HANDLING AND STORAGE PRECAUTIONS
Store in a cool and dry place. Keep out of reach of children.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Mechanical ventilation should be used when handling this product in enclosed spaces. Local exhaust ventilation may
be necessary.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear OSHA-approved safety glasses, goggles or face shield.

SKIN: Wear chemically impervious gloves such as Neoprene or Nitrile and protective clothing.

RESPIRATORY: In absence of proper mechanical ventilation, wear a NIOSH approved organic vapor respirator.

PROTECTIVE CLOTHING: Wear chemically impervious gloves, such as neoprene or nitrile. Wear leather shoes

and long pants and long sleeve shirt.

WORK HYGIENIC PRACTICES:

DO NOT SMOKE, EAT OR DRINK OR APPLY COSMETICS IN WORK AREA! Wash promptly if skin

becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet.


9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Lotion
ODOR: Faint DEET
APPEARANCE: Off white lotion
pH: 6.4
PERCENT VOLATILE: N/A
VAPOR DENSITY: N/A
BOILING POINT: N/E
FREEZING POINT: N/E
MELTING POINT: N/E
SOLUBILITY IN WATER: Fine suspension
SPECIFIC GRAVITY: N/E
EVAPORATION RATE: N/E
MATERIAL SAFETY DATA SHEET
Page 3 of 4
DermAegis, Inc. Date-Issued: 02/02/2005
5730 Clarendon Drive MSDS Ref. No: 01
Rockford, IL 61114 Date-Revised: 05 SEP 2006
Revision No: 02
LIPODEET INSECT REPELLENT FORMULA 302

10. STABILITY AND REACTIVITY
STABLE: YES HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: Temperatures above 120癋

11. TOXICOLOGICAL INFORMATION

DERMAL SENSITIZATION: Not a sensitizer.
PRIMARY SKIN IRRITATION: Not a skin irritant.
DERMAL TOXICITY: Not a dermal toxicant.
ORAL TOXICITY: Not an oral toxicant.
EYE IRRITATION: Moderately irritating. Irritation cleared by day 14.
COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are
listed by IARC, NTP, OSHA or ACGIH as being carcinogens.

12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: None Available

13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD:

If empty: Do not reuse container. Place in trash or offer for recycling if available.

If partly filled: Call your local solid waste agency or 1-800-CLEANUP for disposal instructions.


14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Consumer Commodity
PRIMARY HAZARD CLASS/DIVISION: ORM-D
OTHER SHIPPING INFORMATION: N/A

15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)

311/312 HAZARD CATEGORIES:

FIRE: NO PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: NO

313 REPORTABLE INGREDIENTS: None

302/304 EMERGENCY PLANNING

EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this

formulation. (40 CFR 355). There are no components that are subject to emergency requirements under CERCLA

Section 103(a)(40 CFR 302.4) in this formulation.


TSCA (TOXIC SUBSTANCE CONTROL ACT)

TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control ACT

inventory reporting requirements.

MATERIAL SAFETY DATA SHEET
Page 4 of 4
DermAegis, Inc. Date-Issued: 02/02/2005
5730 Clarendon Drive MSDS Ref. No: 01
Rockford, IL 61114 Date-Revised: 05 SEP 2006
Revision No: 02
LIPODEET INSECT REPELLENT FORMULA 302

16. OTHER INFORMATION
REVISION SUMMARY: Updated MSDS
HMIS CODES
FIRE: 1 HEALTH: 2 REACTIVITY: 0

HMIS RATINGS NOTES:
We assign HMIS ratings to this product based on the hazards of its ingredients(s). Since the customer is most aware
of the applications and conditions of use, he must ensure that the proper personal protective equipment is provided
consistent with the information contained in sections 7 and 8 of this MSDS.

COMMENTS:
The data contained herein is based on information currently available to DermAegis, Inc. and believed to be factual

and the opinions expressed to be those of qualified experts; however, this data is not to be taken as a warranty or

representation for which DermAegis, Inc. assumes legal responsibility.

MSDS Prepared by Scientific Coordination, Inc.


N/A: Not Applicable

N/E: Not Established

3M MATERIAL SAFETY DATA SHEET ULTRATHON (tm) INSECT REPELLENT (lotion) 12/14/2005




Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ULTRATHON (tm) INSECT REPELLENT (lotion)
MANUFACTURER: 3M
DIVISION: Protective Materials & Consumer Specialties Division

ADDRESS: 3M Center
St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 12/14/2005
Supercedes Date: 12/14/2004

Document Group: 16-0613-6

Product Use:
Specific Use: INSECT REPELLANT


SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 40 - 44
N,N-DIETHYL M-TOLUAMIDE 134-62-3 34 - 36
INERT INGREDIENTS Mixture 24 - 26



SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous Lotion

Odor, Color, Grade: White with DEET odor.

General Physical Form: Liquid

Immediate health, physical, and environmental hazards: May cause severe eye irritation.


3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.


_________________________________________________________________________________________________
Page 1 of 7
3M MATERIAL SAFETY DATA SHEET ULTRATHON (tm) INSECT REPELLENT (lotion) 12/14/2005




Skin Contact:
Prolonged or repeated exposure may cause:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.




Inhalation:
No health effects are expected.

Ingestion:
Ingestion may cause:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.




SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are

followed.


Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.


Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.


Inhalation: No need for first aid is anticipated.


If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious

person. Get medical attention.


4.2 NOTE TO PHYSICIANS
Probable mucosal damage may contraindicate the use of gastric lavage.



SECTION 5: FIRE FIGHTING MEASURES


5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL




_________________________________________________________________________________________________
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5.2 EXTINGUISHING MEDIA
Non-combustible. Choose material suitable for surrounding fire.

5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus

(SCBA).


Unusual Fire and Explosion Hazards: Not applicable.


Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.


SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to
prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite,
vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much
of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person.
Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container
approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.



SECTION 7: HANDLING AND STORAGE


7.1 HANDLING
Avoid eye contact. Keep out of the reach of children. Wash hands thoroughly with soap and water after applying product.

7.2 STORAGE
Store under normal warehouse conditions.


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 ENGINEERING CONTROLS
Not applicable.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.


8.2.2 Skin Protection
Gloves are not required. Do not use on synthetic fabrics, plastics, watch crystals, leather, painted, or varnished surfaces. After
returning indoors, wash treated skin with soap and water. Wash treated clothing.



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3M MATERIAL SAFETY DATA SHEET ULTRATHON (tm) INSECT REPELLENT (lotion) 12/14/2005



If irritation occurs, discontinue use.

8.2.3 Respiratory Protection
Not applicable.


8.2.4 Prevention of Swallowing
Wash hands thoroughly with soap and water after applying product.

8.3 EXPOSURE GUIDELINES
None Established


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Viscous Lotion
Specific Physical Form:
White with DEET odor.
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
>=95 篎
Boiling point
0.995 - 1.035 g/ml
Density
Not Applicable
Vapor Density

<=16 psia [@ 68 篎]
Vapor Pressure

0.995 - 1.035 [Ref Std: WATER=1]
Specific Gravity

No Data Available
Melting point
Not Applicable
Solubility In Water
Negligible
Solubility in Water
No Data Available
Evaporation rate
Approximately 0.19 g/l
Volatile Organic Compounds
>=44.00 % weight
Percent volatile
Approximately 38.16 g/l
VOC Less H2O & Exempt Solvents
150000 - 300,000 centipoise [Test Method: ASTM METHOD]
Viscosity


SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.


Materials and Conditions to Avoid: None known



Hazardous Polymerization: Hazardous polymerization will not occur.


Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion

_________________________________________________________________________________________________
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Carbon dioxide During Combustion

Oxides of Nitrogen During Combustion




SECTION 11: TOXICOLOGICAL INFORMATION

Product-Based Toxicology Information:

Use of this product may cause skin reactions in rare cases.

Component-Based Toxicology Information:




SECTION 12: ECOLOGICAL INFORMATION


ECOTOXICOLOGICAL INFORMATION
Not determined.

CHEMICAL FATE INFORMATION
Not determined.


SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility.
Dispose of empty product containers in a sanitary landfill.


EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.


SECTION 14:TRANSPORT INFORMATION

ID Number(s):
70-0711-7347-3, 70-0711-7696-3, 70-1000-7054-2, 70-1000-7097-1, 70-1000-7404-9, 70-1000-8095-4, 70-1000-8287-7, 70
1000-9881-6, 70-1000-9888-1, 70-1000-9889-9, 70-2007-2649-8




Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.


SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS
Contact 3M for more information.


_________________________________________________________________________________________________
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311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No



FIFRA

Status Registration Number
Registered 58007-1



STATE REGULATIONS
Contact 3M for more information.




CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.




INTERNATIONAL REGULATIONS
Contact 3M for more information.




This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.


SECTION 16: OTHER INFORMATION

NFPA Hazard Classification
Health: 2 Flammability: 0 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.


Revision Changes:

Copyright was modified.

Section 10: Hazardous decomposition or by-products table was modified.

Section 2: Ingredient table was modified.

Sections 3 and 9: Specific physical form information was modified.



_________________________________________________________________________________________________
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Section 5: Flammable limits (UE) information was modified.

Section 5: Flammable limits (LEL) information was modified.

Section 9: Property description for optional properties was modified.

Section 9: Flammable limits (LEL) information was modified.

Section 9: Flammable limits (UEL) information was modified.

Section 4: Note to physicians heading was added.

Section 15: FIFRA heading was added.

Section 15: FIFRA information was added.

Section 4: Note to physicians was added.

Section 15: Inventories information was added.

Section 9: Solubility in water text was added.



DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M

MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF

TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of

use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely

within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a

particular purpose and suitable for user's method of use or application.


3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may

have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.



3M MSDSs are available at www.3M.com




_________________________________________________________________________________________________
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