Material Safety Data Sheet
Section 1: Product & Company Identification
Product Name: Insect Repellent
Product Number (s): 14011
Manufactured By:
CRC Industries, Inc. General Information (215) 674-4300
885 Louis Drive Technical Assistance (800) 521-3168
Warminster, PA 18974 Customer Service (800) 272-4620
www.crcindustries.com 24-Hr Emergency (CHEMTREC) (800) 424-9300
Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.
Eye Contact:
Remove contaminated clothing and wash affected area with soap and water. Call a physician
Skin Contact:
if irritation persists. Wash contaminated clothing prior to re-use.
Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
Inhalation:
breathing is difficult give oxygen. Call a physician.
If swallowed, call a poison control center or doctor immediately for treatment advice. Have
Ingestion:
person sip a glass of water if able to swallow. Do not induce vomiting unless directed by a
poison control center or doctor. Never give anything by mouth to an unconscious person.
None
Note to Physicians:
Section 5: Fire-Fighting Measures
Flammable Properties: This product is flammable in accordance with aerosol flammability definitions
(16 CFR 1500.3(c)(6) ).
Flash Point: Upper Explosive Limit: NE
75?F (TCC)
Autoignition Temperature: NE Lower Explosive Limit: NE
Foam, carbon dioxide or dry chemical; class B fire extinguishers
Suitable Extinguishing Media:
carbon dioxide, carbon monoxide, nitrogen oxides
Products of Combustion:
Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
Protection of Fire-Fighters:
protection against suffocation and possible toxic decomposition products. Proper eye
and skin protection should be provided. Use water spray to keep fire-exposed
containers cool and to knock down vapors which may result from product
decomposition.
Page 2 of 6
Product Name: Insect Repellent Product Number (s): 14011
Section 6: Accidental Release Measures
Use personal protection recommended in Section 8.
Personal Precautions:
Take precautions to prevent contamination of ground and surface waters. Do not flush
Environmental Precautions:
into sewers or storm drains.
Eliminate sources of ignition. Dike area to contain spill. Ventilate the area
Methods for Containment & Clean-up:
with fresh air. If in confined space or limited air circulation area, clean-up
workers should wear appropriate respiratory protection. Recover or absorb
spilled material using an absorbent designed for chemical spills. Place used
absorbents into proper waste containers.
Section 7: Handling and Storage
Do not use near sources of ignition. Use only at normal room temperatures. Do not spray
Handling Procedures:
towards face. Do not puncture or incinerate can. Use with proper ventilation.
Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F
Storage Procedures:
to prevent cans from rupturing.
III
Aerosol Storage Level:
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines:
OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURC UNIT
E
DEET (N,N-Diethyl-M-Toluamide) NE NE NE NE NE
MGK?264 (N-Octyl Dicycloheptene
NE NE NE NE NE
Dicarboximide)
MGK?Repellent 326 (Di-N-Propyl
NE NE NE NE NE
Isocinchomeronate)
Isopropyl Alcohol 400 500(v) 200 400 NE ppm
Acetone 1000 NE 500 750 NE ppm
Liquefied Petroleum Gas 1000 NE 1000 NE NE ppm
N.E. ?Not Established (c) ?ceiling (s) ?skin (v) ?vacated
Area should have ventilation to provide fresh air. Use local exhaust to prevent accumulation
Engineering Controls:
of vapors. Use mechanical means if necessary to maintain vapor levels below the exposure
guidelines. If working in a confined space, follow applicable OSHA regulations
None required for normal work where adequate ventilation is provided. Use NIOSH-
Respiratory Protection:
approved self-contained positive pressure respirators in low circulation areas and for
emergencies.
For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
Eye/face Protection:
contact, wear splash-proof goggles.
Page 3 of 6
Product Name: Insect Repellent Product Number (s): 14011
Use protective gloves such as Nitrile or Viton. Also, use full protective clothing if there is
Skin Protection:
prolonged or repeated contact of liquid with skin.
Do not store near open flame or in high temperature areas.
Conditions to Avoid:
Extreme acid or alkaline conditions may cause this product to breakdown. Contact with
Incompatible Materials:
strong oxidizers may cause an explosive situation.
Long-term toxicological studies have not been conducted for this product. The following information is
available for components of this product.
ACUTE EFFECTS
Component Test Result Route Species
N-N-Diethyl-M-Toluamide LD50 10 g/kg dermal rabbit
N-N-Diethyl-M-Toluamide LD50 1.95 g/kg oral rat
All active ingredients LC50 > 4.47 mg/L/4H inhalation rat
The dispensed liquid is a D001 flammable hazardous waste. (See 40 CFR Part 261.20 ?261.33)
Disposal:
Full or partial full containers should be punctured and drained, and the liquid should be managed as
hazardous waste. Empty containers may be recycled.
All disposal activities must comply with federal, state and local regulations. Local regulations may be more
stringent than state or national requirements.
Section 14: Transport Information
Proper shipping description:
Consumer Commodity, ORM-D
US DOT (ground):
None
Special Provisions:
Section 15: Regulatory Information
U.S. Federal
Toxic Substances Control Act (TSCA):
All ingredients are either listed on the TSCA inventory or are exempt.
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):
Acetone (5000 lbs)
Reportable Quantities (RQ's) exist for the following ingredients:
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III:
Yes
Section 311/312 Hazard Categories: Fire Hazard
No
Reactive Hazard
Yes
Release of Pressure
Yes
Acute Health Hazard
No
Chronic Health Hazard
Page 5 of 6
Product Name: Insect Repellent Product Number (s): 14011
Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
Di-N-Propyl Isocinchomeronate (2.5%)
Clean Air Act:
None
Section 112 Hazardous Air Pollutants (HAPs):
State Regulations
California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm: Di-N-Propyl Isocinchomeronate
State Right to Know:
68476-86-8
New Jersey:
67-63-0, 68476-86-8
Pennsylvania:
67-63-0l, 68476-86-8
Massachusetts:
67-63-0, 68476-86-8
Rhode Island :
EPA Registration Number: 1021-1600-55809. In states with Consumer
Additional Regulatory Information:
Products VOC regulations, this product is compliant as an Insect Repellent.
This product is registered in all 50 United States. Insect Repellent is not
registered and cannot be sold outside of the United States.
Section 15: Additional Regulatory Information
Changes since last revision:
The information contained in this document applies to this specific material as supplied. It may not be valid for
this material if it is used in combination with any other materials. This information is accurate to the best of
CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any
product, read all warnings and directions on the label.
CAS: Chemical Abstract Service NA: Not Applicable
ppm: Parts per Million ND: Not Determined
TCC: Tag Closed Cup NE: Not Established
PMCC: Pensky-Martens Closed Cup g/L: grams per Liter
PPE: Personal Protection Equipment lbs./gal: pounds per gallon
TWA: Time Weighted Average STEL: Short Term Exposure Limit
OSHA: Occupational Safety and Health Administration
ACGIH American Association of Governmental Industrial Hygienists
NIOSH National Institute of Occupational Safety & Health