Safety Data Sheet
according to 91/155/EEC and ISO 11014-1
Date of printing: 03.08.2007 Page: 1/6
Revised: 22/05/2007 MSDS Ref No. : 328
HAZARDOUS ACCORDING TO THE CRITERIA OF WORKSAFE AUSTRALIA
1. Identification of the substance/preparation and company
Product
Product name
SikaBoom-F
Manufacturer/supplier information
Manufacturer/supplier: Sika (NZ) Ltd
Street/postbox: 85-91 Patiki Road
Town/City and Post Code: Avondale, Auckland
Country: New Zealand
Phone: (02) 9725 1145
Telefax: (02) 9725 3330
General information: Operations Manager
Emergency information phone: 0800 734 607
2. Composition/information on ingredients
Chemical characterization
Urethaneprepolymer with liquefied propellants, flammable and under
pressure
Hazardous ingredients
Designation
CAS No. Concentration Danger symbols R phrases
?Tris (2-chloroisopropyl)phosphate
13674-84-5 10-25% Xn R 22
?diphenylmethane-4,4'-diisocyanate, isomers and homologous
9016-87-9 2.5?0% Xn R20?6/36/38-42/43
?isobutene
75-28-5 2.5-10% F+ R12
?propane
74-98-6 2.5-10% F+ R12
?dimethyl ether
115-10-6 2.5-15% F+ R12
* 3. Hazards identification
Hazards identification
Xn Harmful
F+ Extremely flammable
Information on hazards to man and to the environment
Increasing inside pressure by heating. Danger of bursting by heating.
R12 Extremely flammable
R42/43 May cause sensitisation by inhalation and skin contact.
R36/37/38 Irritating to eyes, respiratory system and skin
Pressurised container. Protect from sunlight and do not expose to temperature
exceeding 50癈. Do not pierce, burn even after use. Do not spray on a naked
flame or any incandescent body. Keep away from sources of ignition ?No
smoking. Without adequate ventilation formation of flammable/explosives
vapour ?air mixture may be possible.
Classification system
The calssification is in line with current EC lists. If is expanded,
however, by information from technical literature and by information
furnished by supplier companies.
Product name: SikaBoom-F
Date of printing: 03.08.2007 Page: 2/3
Revised: 22/05/2007 MSDS Ref No. : 328
4. 4. First-aid measures
General instructions
Irritant effects by pasting. Danger of sticking eyes and skin caused by
cured foam. Sensitization by inhalation and skin contact possible.
After inhalation
Supply fresh air; consult doctor in case of symptoms.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
After eye contact
Rinse opened eye for several minutes under running water. Then consult
doctor.
After ingestion
Do not induce vomiting. Instantly call for medical help.
5. Fire-fighting measures
Suitable extinguishing media
CO2, extinguishing powder or water jet. Fight larger fires with water
jet or alcohol-resistant foam. DO NOT USE water with a full water jet.
Exposure hazard arising from the product, its combustion products or
resulting gases
In the event of fire the following can be released:
Hydrogen chloride (HCI)
Cyanic acid (HCN)
Carbon Monoxide (CO)
danger of bursting
Additional information
Use a respirator with own air supply. Do not inhale explosion gases or
combustion gases.
Cool endangered container with water spray jet. Please do not reals4e
fire water into the canalisation.
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Remove any source of ignition, no smoking, avoid inhalation, eye and skin
contact.
Environmental precautions
Do not release into the canalization.
Procedures for cleaning up
Allow to solidify. Collect mechanically.
When picked up, treat material as prescribed under heading "Disposal".
Product name: SikaBoom-F
Date of printing: 03.08.2007 Page: 3/6
Revised: 22/05/2007 MSDS Ref No. : 328
7. Handling and storage
Handling
Instructions for safe handling
Ensure good ventilation/exhaustion at workplace.
Keep away from heat and direct sunlight.
Ensure good interior ventilation, especially at floor level (fumes are
heavier than air.)
Instructions for fire and explosion protection
Pressurised container. Protect from sunlight and do not expose to
temperatures exceeding 50癈. Do not pierce, burn, even after use. Do
not spray on a naked flame or any incandescent body. Keep away from
sources of ignition ?No smoking. Without adequate ventilation formation
of flammable/explosives vapour ?air mixture may be possible. Keep away
from children.
Storage
Requirements for storage rooms and containers
Observe official regulations on storing packaging with pressurized
containers. Store at a dry, cool and good ventilated room.
Combined storage instructions
Not necessary.
Additional information regarding storage
Protect from heat and direct sunlight. Best storage temperature 18-22癈.
Storage Class
2B pressurised containers
8. Exposure controls/personal protection
Personal protective equipment
General protective and hygiene measures. Avoid contact with eyes and the
skin. The usual precautionary measures should be adhered to in handling
chemicals.
Respiratory protection
Not necessary if room well ventilated.
Hand protection
Butyl rubber/nitrile rubber gloves.
Eye protection
Safety glasses.
Body protection
Protective work clothing.
Components with critical values that require monitoring at the workplace
CAS-Nr Description TLV
9016-87-9 Diiphenymethanediisocyanate, In form of breathable aerosols
TLV: 0.05mg/m3, 0.005 ppm
Isomers and homologous
TLV: 1910mg/m3, 1000ml/m3
115-10-6 Dimethyl ether
TLV: 2400mg/m3, 1000ml/m3
75-28-5 Isobutane
TLV: 1800mg/m3, 1000ml/m3
74-98-6 Propane
Product name: SikaBoom-F
Date of printing: 03.08.2007 Page: 4/6
Revised: 22/05/2007 MSDS Ref No. : 328
9. Physical and chemical properties
Appearance
Physical state: Aerosol
Colour: light red
Odour: weak, characteristic
Data relevant to safety Method
Decomposition temperature > 100 癈
Flash point not applicable as aerosol
Vapour pressure at 20癈 not determined
Density at 20癈 not applicable
Solubility in water not miscible
pH value at 20癈 -
Viscosity at 20癈 -
Ignition Temperature Propellent >230癈
10. Stability and reactivity
Conditions to avoid
No decomposition if used stored according to specifications.
Materials to avoid/dangerous reactions
By warming up over 50癈 due to increasing inside pressure there is danger
of bursting.
Thermal decomposition and hazardous decomposition products
Hydrogen chloride (HCI), cyanic hydrogen (HCN) (at combustion)
11. Toxicological information
Sensitization
-
Experience on humans
When skin contact:
Irritant for skin when pasting. Sensitisation by skin contact possible.
When eyes contact:
Irritant effect: danger of pasting.
When inhalation:
Sensitisation possible Not applicable for the cured foam.
Additional information
After foaming the prepolymer cures with air moisture out of the
environment to neutral polyurethane.
Product name: SikaBoom-F
Date of printing: 03.08.2007 Page: 5/6
Revised: 22/05/2007 MSDS Ref No. : 328
12. Ecological information
Additional information
Cured foam is not biodegradable.
13. Disposal considerations
Product
Recommendations
Observe your local disposal regulations
Pressurised containers containing dangerous substances and gases
Fully emptied containers: Adhesives and sealant disposals, containing
organic solvents and other dangerous substances.
Packaging
Recommendations
Uncleaned packaging: disposal must be made according to official
regulations
14. Transport information
ADG/ADR/RID
Class: 2 Classifying code: 5F UN: 1950
Description: pressurized container
Notice: transport according to chapter 3.4 ADR
IMO/IMDG
Class: 2 UN: 1950 EMS: F-D; S-U
Marine pollutant: No
Technical name: aerosols, limited quantity
IATA/ICAO
Class: 2.1 UN: 1950 Notice: aerosols, flammable
* 15. Regulatory information
Labelling according to EEC Directive
The product is classified and labelled in accordance with
EC directives/the relevant national laws.
Relevant hazardous ingredients for labelling
Contains: Highly flammable propellants and
Diphenylmethane-4,4'-diisocyanate
Danger symbols
Xn Harmful
F+ Extremely flammable
R phrases
R12 Extremely flammable
R42/43 May cause sensitisation by inhalation and skin contact
R36/37/38 Irritation for eyes, respiratory system and skin
Product name: SikaBoom-F
Date of printing: 03.08.2007 Page: 6/6
Revised: 22/05/2007 MSDS Ref No.: 328
* 15. Regulatory information (continued)
S phrases
S2 Keep out of reach of children.
S23 Do not breathe gas/fumes/vapour/spray
S25 Avoid contact with eyes
S26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of
water and soap.
S37 Wear suitable gloves
S39 Wear protective goggles
S45 In case of accident or you feel unwell, seek medical
advice immediately.
Special designation of certain preparation
Pressurised container. Protect from sunlight and do not expose to
temperatures exceeding 50癈. Do not pierce or burn, even after use. Do
not spray into a naked flame or any incandescent object. Keep away from
sources of ignition ?No smoking. Without adequate ventilation
formation of explosives mixtures may occur. Contains Isocyanates.
Observe manufacture's instructions.
National regulations
Toxicity law (CH): Not determined
Water hazard class: None
* 16. Other information
asterisk (*) on left margin marks modification of previous version
R-phrases of the ingredients listed in chapter 2
R12 Extremely flammable
R20 Harmful by inhalation
R22 Harmful if swallowed
R36/37/38 Irritating for eyes, respiratory system and skin
R42/43 May cause sensitisation by inhalation and skin contact
The information contained in this Safety Data Sheet corresponds to our
level of knowledge at the time of publication. All warranties are ex-
cluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
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