Material Safety Data Sheet
The Dow Chemical Company
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
Print Date: 29 Jul 2008
The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1. Product and Company Identification
Product Name
FROTH-PAK(TM) 1.75 HFC 60gal Refill Polyurethane Spray Foam
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
Customer Information Number: 800-258-2436
EMERGENCY TELEPHONE NUMBER
989-636-4400
24-Hour Emergency Contact:
989-636-4400
Local Emergency Contact:
2. Hazards Identification
Emergency Overview
Color: Yellow
Physical State: Liquid
Odor: Characteristic
Hazards of product:
CAUTION! May cause eye irritation. May be harmful if inhaled. Vapor reduces
oxygen available for breathing. May cause anesthetic effects. May cause central
nervous system effects; may cause respiratory tract irritation. Keep upwind of spill.
Toxic fumes may be released in fire situations. Contents under pressure. Avoid
temperatures above 50?(122?br>
C F)
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Potential Health Effects
Eye Contact: May cause moderate eye irritation. May cause slight corneal injury.
?TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow
Page 1 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
Skin Contact: Brief contact may cause slight skin irritation with local redness.
Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Inhalation: Prolonged excessive exposure may cause adverse effects. In confined or poorly
ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to
displacement of oxygen. May cause respiratory irritation and central nervous system depression.
Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability
(irregular heartbeats). Symptoms of excessive exposure may be anesthetic or narcotic effects;
dizziness and drowsiness may be observed.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may cause
injury.
Effects of Repeated Exposure: Contains a component which is reported to be a weak
organophosphate-type cholinesterase inhibitor. Excessive exposure may produce organophosphate
type cholinesterase inhibition. Signs and symptoms of excessive exposure may be headache,
dizziness, incoordination, muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating,
pinpoint pupils, blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Contains component(s) which have been reported to cause effects on the following organs in animals:
Liver. Bone marrow. Kidney. Adrenal gland.
Birth Defects/Developmental Effects: For the component(s) tested: Has been toxic to the fetus in
laboratory animals at doses toxic to the mother. For similar material(s): Has been toxic to the fetus in
lab animals at doses nontoxic to the mother. Did not cause birth defects in laboratory animals. Based
on animal studies, ingestion of very large amounts of ethylene glycol appears to be the major and
possibly only route of exposure to produce birth defects. Exposures by inhalation or skin contact, the
primary routes of occupational exposure, had minimal effect on the fetus, in animal studies.
Reproductive Effects: For the minor component(s): In laboratory animal studies, effects on
reproduction have been seen only at doses that produced significant toxicity to the parent animals.
Ingestion of large amounts of ethylene glycol has been shown to interfere with reproduction in animals.
Composition Information
3.
Component CAS # Amount
1,1,1,2-Tetrafluoroethane 811-97-2 >= 10.0 - <= 30.0 %
Polyester polyol, aromatic Not available >= 10.0 - <= 30.0 %
Ethylene glycol 107-21-1 > 0.1 - < 1.0 %
Sucrose , propylene oxide polymer 9049-71-2 >= 10.0 - <= 30.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 10.0 - <= 30.0 %
Triethyl phosphate 78-40-0 >= 1.0 - <= 5.0 %
Glycerol propylene oxide polymer 25791-96-2 >= 10.0 - <= 30.0 %
4. First-aid measures
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Wash skin with plenty of water.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Notes to Physician: This material is a cholinesterase inhibitor. Treat symptomatically. Atropine, only
by injection, is the preferable antidote. Oximes, such as 2-PAM/protopam, may be therapeutic if used
early; however, use only in conjunction with atropine. In case of severe acute poisoning, use antidote
immediately after establishing an open airway and respiration. If exposed, plasma and red blood cell
cholinesterase tests may indicate significance of exposure (baseline data are useful). Attempt seizure
control with diazepam 5-10 mg (adults) intravenous over 2-3 minutes. Repeat every 5-10 minutes as
needed. Monitor for hypotension, respiratory depression, and need for intubation. Consider second
Page 2 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
agent if seizures persist after 30 mg. If seizures persist or recur administer phenobarbital 600-1200
mg (adults) intravenous diluted in 60 ml 0.9% saline given at 25-50 mg/minute. Evaluate for hypoxia,
dysrhythmia, electrolyte disturbance, hypoglycemia (treat adults with dextrose 100 mg intravenous).
Maintain adequate ventilation and oxygenation of the patient. Exposure may increase "myocardial
irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely
necessary. Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.
5. Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC
type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,
but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Blowing agent vaporizes quickly at room temperature.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Hydrogen fluoride. Hydrogen chloride. Carbon
monoxide. Carbon dioxide.
6. Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb
with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled containers.
Wash the spill site with water. See Section 13, Disposal Considerations, for additional information.
Personal Precautions: Isolate area. Keep unnecessary and unprotected personnel from entering the
area. Spilled material may cause a slipping hazard. Use appropriate safety equipment. For additional
information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7,
Handling, for additional precautionary measures.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
7. Handling and Storage
Handling
General Handling: Avoid contact with eyes. Avoid breathing vapor. Wash thoroughly after handling.
Keep container closed. Use only with adequate ventilation. This material is hygroscopic in nature.
Contents under pressure. Do not puncture or incinerate container. Do not enter confined spaces
unless adequately ventilated. See Section 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
Page 3 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to lowering of
the autoignition temperatures possibly resulting in spontaneous combustion.
Storage
Store under cover in a dry, clean, cool, well ventilated place away from sunlight.
Storage Period: 6 Months
Storage temperature: 24 ? C
8. Exposure Controls / Personal Protection
Exposure Limits
Component List Type Value
|
WEEL TWA 4,240 mg/m3 1,000 ppm
1,1,1,2-Tetrafluoroethane
||
ACGIH Ceiling 100 mg/m3
Ethylene glycol
Aerosol.
Personal Protection
Eye/Face Protection: Use chemical goggles.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Hand protection: Use gloves chemically resistant to this material. Examples of preferred
glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol
laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of
acceptable glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl
chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular
application and duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be handled, physical
requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions
to glove materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or
guidelines. If there are no applicable exposure limit requirements or guidelines, use only in enclosed
systems or with local exhaust ventilation. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. Lethal concentrations
may exist in areas with poor ventilation.
9. Physical and Chemical Properties
Liquid
Physical State
Yellow
Color
Characteristic
Odor
> 100 癈 (> 212 ?Estimated
F)
Flash Point - Closed Cup
Lower: No test data available
Flammable Limits In Air
Upper: No test data available
No test data available
Autoignition Temperature
Page 4 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
Not applicable
Vapor Pressure
No test data available.
Boiling Point (760 mmHg)
No test data available
Vapor Density (air = 1)
1.18 Calculated
Specific Gravity (H2O = 1)
No test data available
Freezing Point
No test data available
Melting Point
No test data available
Solubility in Water (by
weight)
Not applicable
pH
2,240 cSt @ 25 ?ASTM D4878
C
Kinematic Viscosity
10. Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Avoid temperatures above 50?(122?Product can oxidize at elevated
C F)
temperatures. Elevated temperatures can cause pressure buildup in closed containers due to the
release of blowing agents. Generation of gas during decomposition can cause pressure in closed
systems.
Incompatible Materials: Avoid contact with: Strong acids. Avoid unintended contact with: Amines.
Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates generates heat.
Hazardous Polymerization
Will not occur by itself.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Decomposition products can include and are not limited to: Carbon dioxide. Alcohols. Ethers.
Hydrocarbons. Ketones. Polymer fragments. Halogenated hydrocarbons.
11. Toxicological Information
Acute Toxicity
Ingestion
Single dose oral LD50 has not been determined. Estimated LD50, Rat > 2,000 mg/kg
Skin Absorption
The dermal LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg
Repeated Dose Toxicity
Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and
symptoms of excessive exposure may be headache, dizziness, incoordination, muscle twitching,
tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation,
tearing, tightness in chest, excessive urination, convulsions. Contains component(s) which have been
reported to cause effects on the following organs in animals: Liver. Bone marrow. Kidney. Adrenal
gland.
Chronic Toxicity and Carcinogenicity
Contains component(s) which did not cause cancer in laboratory animals.
Developmental Toxicity
For the component(s) tested: Has been toxic to the fetus in laboratory animals at doses toxic to the
mother. For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the
mother. Did not cause birth defects in laboratory animals. Based on animal studies, ingestion of very
large amounts of ethylene glycol appears to be the major and possibly only route of exposure to
produce birth defects. Exposures by inhalation or skin contact, the primary routes of occupational
exposure, had minimal effect on the fetus, in animal studies.
Reproductive Toxicity
Page 5 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
For the minor component(s): In laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals. Ingestion of large amounts of
ethylene glycol has been shown to interfere with reproduction in animals.
Genetic Toxicology
In vitro genetic toxicity studies were negative for component(s) tested. For the minor component(s):
Triethyl phosphate. In vitro genetic toxicity studies were negative in some cases and positive in other
cases. Genetic toxicity studies in animals were negative for component(s) tested. For the minor
component(s): Triethyl phosphate. Animal genetic toxicity studies were negative in some cases and
positive in other cases.
12. Ecological Information
ENVIRONMENTAL FATE
Data for Component: 1,1,1,2-Tetrafluoroethane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is high (Koc between 50 and 150).
Henry's Law Constant (H): 5.00E-2 atm*m3/mole; 25 ?Measured
C
Partition coefficient, n-octanol/water (log Pow): 1.68 Estimated
Partition coefficient, soil organic carbon/water (Koc): 97 Estimated
Persistence and Degradability
1,1,1,2-Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential (ODP) of
zero, relative to CFC 12 (ODP=1). Material is expected to biodegrade only very slowly (in the
environment). Fails to pass OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
6.20E-15 cm3/s 1,700 d Estimated
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
4% 28 d OECD 301D Test
Theoretical Oxygen Demand: 0.47 mg/mg
Data for Component: Ethylene glycol
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from
natural bodies of water or moist soil is not expected to be an important fate process.
Henry's Law Constant (H): 8.05E-09 atm*m3/mole; 25 ?Estimated
C
Partition coefficient, n-octanol/water (log Pow): -1.36 Measured
Partition coefficient, soil organic carbon/water (Koc): 1 Estimated
Distribution in Environment: Mackay Level 1 Fugacity Model:
Air Water. Biota Sediment
Soil
2.1 % 98 % < 0.01 % < 0.01 % < 0.01 %
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is
ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent
biodegradability).
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
8.32E-12 cm3/s 15 h Estimated
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
> 94 % 28 d OECD 301F Test
90 % 1d OECD 302B Test
Theoretical Oxygen Demand: 1.29 mg/mg
Page 6 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
Data for Component: Sucrose , propylene oxide polymer
Movement & Partitioning
No bioconcentration is expected because of the relatively high water solubility.
Persistence and Degradability
Based on information for a similar material: Material is inherently biodegradable (reaches >
20% biodegradation in OECD test(s) for inherent biodegradability).
Data for Component: Tris(1-chloro-2-propyl) phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
low (Koc between 500 and 2000).
Henry's Law Constant (H): < 1.35E-5 atm*m3/mole; 25 ?Estimated
C
Partition coefficient, n-octanol/water (log Pow): 2.59 Measured
Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated
Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured
Persistence and Degradability
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
4.47E-11 cm3/s 0.24 d Estimated
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
14 % 28 d OECD 301E Test
Theoretical Oxygen Demand: 1.17 mg/mg
Data for Component: Triethyl phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from
natural bodies of water or moist soil is not expected to be an important fate process.
Henry's Law Constant (H): 3.60E-08 atm*m3/mole; 25 ?Measured
C
Partition coefficient, n-octanol/water (log Pow): 0.80 Measured
Partition coefficient, soil organic carbon/water (Koc): 48 Estimated
Persistence and Degradability
Biodegradation under aerobic laboratory conditions is below detectable limits (BOD20 or
BOD28/ThOD < 2.5%).
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
57.94E-12 cm3/s 0.18 d Estimated
Biological oxygen demand (BOD):
BOD 5 BOD 10 BOD 20 BOD 28
0%
Theoretical Oxygen Demand: 1.58 mg/mg
Data for Component: Glycerol propylene oxide polymer
Movement & Partitioning
Based on information for a similar material: Bioconcentration potential is low (BCF less than
100 or log Pow less than 3).
Persistence and Degradability
For this family of materials: Based on stringent OECD test guidelines, this material cannot be
considered as readily biodegradable; however, these results do not necessarily mean that the
material is not biodegradable under environmental conditions.
Page 7 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
ECOTOXICITY
Data for Component: 1,1,1,2-Tetrafluoroethane
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 450 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 980 mg/l
Data for Component: Ethylene glycol
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 18,000 - 46,000 mg/l
Aquatic Invertebrate Acute Toxicity
LC50, water flea Daphnia magna, static, 48 h: 46,300 - 51,100 mg/l
Aquatic Plant Toxicity
EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 9,500 - 13,000
mg/l
Toxicity to Micro-organisms
EC50, OECD 209 Test; activated sludge, respiration inhibition, 30 min: 225 mg/l
Data for Component: Sucrose , propylene oxide polymer
Based on information for a similar material: Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species
tested).
Data for Component: Tris(1-chloro-2-propyl) phosphate
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50
between 10 and 100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l
Aquatic Plant Toxicity
EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l
EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l
Toxicity to Micro-organisms
EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l
Data for Component: Triethyl phosphate
Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L).
Fish Acute & Prolonged Toxicity
LC50, Japanese medaka (Oryzias latipes), static, 48 h: > 500 mg/l
Data for Component: Glycerol propylene oxide polymer
For this family of materials: Material is practically non-toxic to aquatic organisms on an acute
basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
13. Disposal Considerations
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF
PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS
Page 8 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED
PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer.
Incinerator or other thermal destruction device. For additional information, refer to: Handling &
Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section 10 Regulatory
Information, MSDS Section 15
14. Transport Information
DOT Non-Bulk
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
DOT Bulk
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
IMDG
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
ID Number: 2.2
EMS Number: F-C,S-V
ICAO/IATA
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956Cargo Packing Instruction: 200
Passenger Packing Instruction: 200
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information can be
obtained through an authorized sales or customer service representative. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material.
15. Regulatory Information
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning
and Community Right-to-Know Act of 1986) Sections 311 and 312
Yes
Immediate (Acute) Health Hazard
No
Delayed (Chronic) Health Hazard
No
Fire Hazard
No
Reactive Hazard
Yes
Sudden Release of Pressure Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous
Substances List and/or Pennsylvania Environmental Hazardous Substance List:
Page 9 of 11
Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous
Substances List:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
WARNING: This product contains a chemical(s) known to the State of California to cause cancer.
Component CAS # Amount
1,4-Dioxane 123-91-1 <= 0.016 %
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or
are not required to be listed.
16. Other Information
Recommended Uses and Restrictions
Component(s) for the manufacture of urethane polymers.
Revision
Identification Number: 1015125 / 1001 / Issue Date 05/22/2008 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A Not available
W/W Weight/Weight
OEL Occupational Exposure Limit
STEL Short Term Exposure Limit
TWA Time Weighted Average
ACGIH American Conference of Governmental Industrial Hygienists, Inc.
DOW IHG Dow Industrial Hygiene Guideline
WEEL Workplace Environmental Exposure Level
HAZ_DES Hazard Designation
Action Level A value set by OSHA that is lower than the PEL which will trigger the need for
activities such as exposure monitoring and medical surveillance if exceeded.
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
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Product Name: FROTH-PAK(TM) 1.75 HFC 60gal Refill Issue Date: 05/22/2008
Polyurethane Spray Foam
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