152 Kennedy Road South
Brampton, Ontario
Canada
L6W 3G4
General Inquiry Number: (905) 459-1232
Material Safety Data Sheet
Attached
This product is distributed by Canada Colors and Chemicals Limited
General Inquiry Phone Number: (905) 459-1232
24 Hour Emergency Phone Number (416) 444-2112
457084
CCC Product Code:______________________
FYROL PCF
CCC Product Name:_______________________________________
MATERIAL SAFETY DATA SHEET
________________________________________________________________________________________
Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
________________________________________________________________________________________
1. Identification of the substance & the company
Chemical name Tris(B-chloroisopropyl) phosphate
Synonym(s) Tris(1-methyl-2-chloroethyl) phoshate
2-Propanol,1-chloro-, phosphate (3:1)
Chemical formula C9H18Cl3O4P
Chemical family Alkyl phosphate
Type of product and use Flame retardant
Supplier ICL Supresta, Inc.
622 Emerson Road - Suite 500
St Louis, Missouri 63141, USA
Tel:(314)983-7884 Fax:(314)983-7607
Emergency Telephone Chemtrec (800)424-9300
2. Hazards identification
Emergency overview May cause mild irritation to the eyes. May cause skin and respiratory tract irritation.
NFPA Ratings (Scale 0-4) Health = 1, Fire = 1, Reactivity = 0
HMIS Ratings (Scale 0-4) Health = 1, Fire =1, Reactivity = 0.
3. Composition / information on ingredients
Components CAS No. Weight %
Tris(2-chloro-1-methylethyl) 13674-84-5 99.5
phosphate
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MATERIAL SAFETY DATA SHEET
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Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
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4. First-aid measures
Eye contact Holding the eyelids apart, flush eyes promptly with copious flowing water for at least
20 minutes.Get medical attention immediately.
Skin contact Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of
water for at least 15 minutes. Wash clothing before re-use.
Get medical attention if irritation occurs.
Inhalation Keep him quiet and warm. Apply artificial respiration if necessary and get medical
attention immediately.
In case of inhalation, remove person to fresh air.
Ingestion If swallowed, wash mouth thoroughly with plenty of water. Get medical attention
immediately.
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NOTE: Never give an unconscious person anything to drink.
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Notes to the physician Treat symptomatically and supportively.
5. Fire - fighting measures
Suitable extinguishing media Material is not combustible. Use extinguishing media appropriate to surrounding fire
conditions.
Fire fighting procedure Fire fighters should wear full protective clothing and self-contained breathing
apparatus (SCBA). Contain runoff to prevent entry into water or drainage systems.
Unusual fire and explosion When heated to decomposition, may release poisonous and corrosive fumes of
hazards Carbon Dioxide, Carbon Monoxide, Hydrogen Chloride and Phosphorus Oxides.
6. Accidental release measures
Personal precautions Wear appropriate safety clothing and eye/face protection (see Section 8)
Methods for cleaning up Soak up with sand or other suitable absorbant and dispose of as solid waste.
Collect in suitable and properly labeled containers.
Ventilate area and wash spill site after material pickup is complete.
Environmental precautions Prevent product from entering drains, ditches and rivers.
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MATERIAL SAFETY DATA SHEET
________________________________________________________________________________________
Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
________________________________________________________________________________________
7. Handling and storage
Handling Keep containers tightly closed.
Avoid bodily contact.
Storage Store in a dry, cool, well-ventilated area away from incompatible materials (see
"materials to avoid").
Maximum recommended storage temperature of 50癈 (122癋)
8. Exposure controls / personal protection
Exposure Limits :
Components ACGIH-TLV Data OSHA (PEL) Data
Tris(2-chloro-1-methylethyl) Not determined Not determined
phosphate
13674-84-5
Ventilation requirements Provide adequate ventilation.
Personal protective equipment:
- Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.
- Hand protection Rubber gloves
- Eye protection Chemical safety goggles
- Skin and body protection Use protective clothing impervious to this material.
Hygiene measures Safety shower and eye bath should be provided. Do not eat, smoke or drink where
material is handled, processed or stored. Wash hands carefully before eating or
smoking.
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MATERIAL SAFETY DATA SHEET
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Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
________________________________________________________________________________________
9. Physical and chemical properties
Appearance Clear colorless liquid
Odor Slightly sweetish
Melting point/range -20癈
Boiling point/range 308癈 (decomposes)
Flash point 218癈 (424癋) (open cup)
Flammable/Explosion limits Not explosive/Not flammable
Auto-ignition temperature Not self-ignitable
Vapour pressure 1.4x10(-3)Pa (25癈)
Viscosity 71mPas (25癈)
Solubility:
- Solubility in water 1.08g/l at 20癈
Density 1.290 (20癈)
Decomposition temperature 172癈
Partition coefficient Log Pow = 2.68
(n-octanol/water)
10. Stability and reactivity
Stability Stable under normal conditions
Materials to avoid Strong oxidizers, strong acids and strong alkalis.
It hydrolyzes slowly at normal temperatures in acidic or alkaline aqueous solutions.
Conditions to avoid Exposure to air and moisture Heating above decomposition temperature
Hazardous decomposition Hydrogen Chloride
products Halogenated hydrocarbons
Hazardous polymerization Not expected to occur
11. Toxicological information
Acute toxicity:
- Rat oral LD50 2800 - 4200 mg/kg
- Rabbit dermal LD50 > 5000 mg/kg
- Rat inhalation LC50 > 4.6 mg/l (4-hr)
- Eye irritation (rabbit) Not irritant
- Dermal irritation (rabbit) Mild irritant
Dermal sensitization Not a sensitizer
Sub-chronic toxicity:
- NOEL > 20,000 ppm (13 weeks oral rat)
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MATERIAL SAFETY DATA SHEET
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Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
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Chronic toxicity No data available
Mutagenicity Not mutagenic by the Ames Test
Not mutagenic in the mouse lymphoma forward mutation assay.
In vivo mouse bone marrow cytogenicity: not mutagenic
Unscheduled DNA (synthesis) - Human (WI-38 cell) data was uninterpretable
Carcinogenicity Not included in NTP 11th Report on Carcinogens
Not classified by IARC
Not classified as a carcinogen by USA OSHA
Neurotoxicity Not neurotoxic
12. Ecological information
Aquatic toxicity :
- EC50, Freshwater algae 47 mg/l (96-hr)
Chronic toxicity The No Observed Effect Concentration (NOEC) in Daphnia magna is 32 mg/l.
Biodegradation Not readily biodegradable
Germany, water endangering 1
classes (WGK)
13. Disposal considerations
Waste disposal Observe all federal, state and local environmental regulations when disposing of this
material
14. Transportation information
UN No. Not regulated
DOT Not regulated
IMO Not regulated
ICAO/IATA Not regulated
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MATERIAL SAFETY DATA SHEET
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Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
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15. Regulatory information
USA Reported in the EPA TSCA Inventory.
- SARA 313 This product does not contain a chemical listed at or above de minimis
concentrations.
- California-Prop 65 WARNING: This product contains a chemical(s) known to the State of California to
cause cancer, or birth defects or other reproductive harm (concentration < 0.1%)
- Waste Classifications This material does not meet RCRA`s characteristic definition of ignitability,
corrosivity, or reactivity, and is not listed in 40CFR 261.33.
- Workplace Classification This product is considered hazardous under the OSHA Hazard Communication
Standard (29CFR 1910.1200).
Canada Listed in DSL
-WHMIS hazard class Non-controlled
EU Reported in EINECS
Japan Listed in ENCS
Australia Listed in AICS
New Zealand Inventory Listed in NZIoC
China inventory Listed
Korea Listed in ECL
Philippines Listed in PICCS
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MATERIAL SAFETY DATA SHEET
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Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
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16. Other information
Health, Safety & Environment Policy
We will strive to ensure that our operations and products meet the needs of the present global community without
compromising the ability of future generations to meet their needs
We accept that the success of our business is dependent on the supply of products and services that will benefit society
whilst ensuring human safety and protection of the environment and natural resources
Within the framework of our commitment to the Responsible Care program, we will provide a healthy and safe work
environment for employees and will responsibly manage our products at all stages of their life cycle in order to protect
human health and the environment whilst maintaining high production standards of operation
TO MEET THIS COMMITMENT WE WILL:
Comply with or exceed applicable national and international regulatory requirements and other requirements to which we
subscribe
Communicate openly and actively encourage dialogue with employees, customers and community concerning our
products and operations
Implement documented management systems consistent with and for promotion of the Responsible Care ethics
Develop and supply products that can be manufactured, transported, used and disposed of safely whilst best meeting the
needs of our customers
Regularly assess, continually improve and responsibly manage health, safety and environmental risks associated with
products and processes throughout their life-cycles
Share knowledge and expertise with others and seek to learn from and incorporate improved practices into our own
operations
Educate and train employees, contractors and customers to improve their HSE performance
Communicate up-to-date information to enable our workers, customers and other interested parties to handle our
products in a safe and environmentally responsible manner
Endeavor to work with customers, suppliers, distributors and contractors to foster the safe use, transport and disposal of
our chemicals
Support Product Stewardship programs in cooperation with customers, distributors and transporters
Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and
believed to be correct as of the date hereof, Bromine Compounds Ltd. makes no representations as to the completeness
or accuracy thereof.
Information is supplied upon the condition that the persons receiving same will make their own determination as to its
safety and suitability for their purposes prior to use.
In no event will Bromine Compounds Ltd. be responsible for damages of any nature whatsoever resulting from the use of
or reliance upon information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS
FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO
INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
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MATERIAL SAFETY DATA SHEET
________________________________________________________________________________________
Product Name FYROL PCF
Product id 7002
Revision date 08/12/2008 Revision: 1
________________________________________________________________________________________
Prepared By HSE Division in ISRAEL
telephone: +/972-8-6297830
telefax: +/972-8-6297832
www.icl-ip.com
e-mail:msdsinfo@icl-ip.com
End of safety data sheet
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