MATERIAL SAFETY DATA SHEET
Bayer MaterialScience LLC TRANSPORTATION EMERGENCY
Product Safety & Regulatory Affairs CALL CHEMTREC: (800) 424-9300
100 Bayer Road INTERNATIONAL: (703) 527-3887
Pittsburgh, PA 15205-9741
USA NON-TRANSPORTATION
Bayer Emergency Phone: Call Chemtrec
Bayer Information Phone: (800) 662-2927
1. Product and Company Identification
BAYSEAL 2.0 W
Product Name:
80873353
Material Number:
Polyol System
Chemical Family:
2. Hazards Identification
Emergency Overview
WARNING! Color: Amber, Brown Form: liquid Odor: slight, Ether, Amine.
Use cold water spray to cool fire-exposed containers to minimize the risk of rupture.
Vapor reduces oxygen available for breathing. Causes respiratory tract irritation. Causes
skin irritation. May be harmful if absorbed through skin. May cause allergic skin
reaction. May cause a temporary fogging of the eyes. Causes eye irritation. May affect
nervous system. May cause irregular heartbeat. May cause kidney damage. May cause
liver damage.
Potential Health Effects
Skin Contact, Eye Contact, Inhalation
Primary Routes of Entry:
Eye disorders, Respiratory disorders, Skin disorders
Medical Conditions Aggravated by
Exposure:
HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE
Inhalation
Acute Inhalation
For Component: Hydrofluorocarbon
May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose. May induce
cardiac arrhythmia (irregular heartbeat) in some individuals. Vapor can reduce oxygen available for
breathing.
For Component: Tris-(2-chloroisopropyl)-phosphate
May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 1 of 12 Report Version: 1.1
For Component: Tertiary Amine
May cause pulmonary edema with symptoms of breathing difficulty and tightness of chest.
For Component: Ethylene Glycol
Causes respiratory tract irritation with symptoms of coughing, sore throat and runny nose. Inhalation of the
glycol component is unlikely due to the low vapor pressure. If misted or handled at elevated temperatures,
high concentrations can produce irritation and/or difficulty breathing. May cause nervous system effects
which can include symptoms of dizziness, incoordination, headache, numbness, and/or confusion. May
induce cardiac arrhythmia (irregular heartbeat) in some individuals.
Skin
Acute Skin
For Component: Hydrofluorocarbon
Slightly toxic by skin absorption. May cause slight irritation.
For Component: Tris-(2-chloroisopropyl)-phosphate
May cause slight irritation.
For Component: Tertiary Amine
Toxic by skin absorption.
For Component: Ethylene Glycol
If sufficient amounts are absorbed, systemic toxicity may occur with symptoms similar to those described
in acute inhalation. May cause slight irritation.
Chronic Skin
For Component: Tertiary Amine
Repeated and prolonged contact may cause an allergic skin reaction in sensitive individuals.
Eye
Acute Eye
For Component: Hydrofluorocarbon
May cause slight irritation.
For Component: Tris-(2-chloroisopropyl)-phosphate
Not expected to be irritating.
For Component: Tertiary Amine
Corrosive with symptoms of reddening, tearing, swelling, burning and possible permanent damage.
For Component: Ethylene Glycol
May cause slight irritation.
Chronic Eye
For Component: Tertiary Amine
Prolonged vapor contact may cause conjunctivitis.
Ingestion
Acute Ingestion
For Component: Tris-(2-chloroisopropyl)-phosphate
May be harmful if swallowed. Symptoms of ingestion may include abdominal pain, nausea, vomiting, and
diarrhea. Moderately toxic by ingestion.
For Component: Tertiary Amine
Corrosive to the digestive tract with symptoms of burning and ulceration.
For Component: Ethylene Glycol
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 2 of 12 Report Version: 1.1
May be fatal if swallowed. Symptoms of ingestion may include abdominal pain, nausea, vomiting, and
diarrhea. May cause nervous system effects which can include symptoms of dizziness, incoordination,
headache, numbness, and/or confusion.
Chronic Ingestion
For Component: Tris-(2-chloroisopropyl)-phosphate
May cause liver damage. May cause kidney damage.
For Component: Ethylene Glycol
May cause blood disorders. May cause brain damage. May cause kidney damage. May cause liver damage.
May cause lung damage.
Carcinogenicity:
No Carcinogenic substances as defined by IARC, NTP and/or OSHA
3. Composition/Information on Ingredients
Hazardous Components
Weight % Components CAS-No.
7 - 13% Hydrofluorocarbon 460-73-1
5 - 10% Tris-(2-chloroisopropyl)-phosphate 13674-84-5
5 - 10% Brominated Flame Retardant CAS# is a trade secret
1 - 5% Tertiary Amine CAS# is a trade secret
1 - 5% Ethylene Glycol 107-21-1
4. First Aid Measures
Eye Contact
In case of contact, flush eyes with plenty of lukewarm water. Get medical attention if irritation develops.
Skin Contact
In case of skin contact, wash affected areas with soap and water. Immediately remove contaminated
clothing and shoes. Get medical attention if irritation develops.
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
respiration using a pocket mask type resuscitator. Get medical attention.
Ingestion
If ingested, do not induce vomiting unless directed to do so by medical personnel. Get medical attention.
5. Fire-Fighting Measures
carbon dioxide (CO2), dry chemical, foam, water spray for large
Suitable Extinguishing Media:
fires.
Special Fire Fighting Procedures
Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic
and irritating fumes. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture.
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 3 of 12 Report Version: 1.1
6. Accidental release measures
Spill and Leak Procedures
Cover spill with inert material (e. g., dry sand or earth) and collect for proper disposal. Use appropriate
personal protective equipment during clean up. Evacuate and keep unnecessary people out of spill area.
7. Handling and Storage
Storage Temperature:
7 癈 (44.6 癋)
minimum:
29 癈 (84.2 癋)
maximum:
Storage Period
6 Months
Handling/Storage Precautions
Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling.
Keep container closed when not in use. Material is hygroscopic and may absorb small amounts of
atmospheric moisture. If contamination with isocyanates is suspected, do not reseal containers. Avoid
contact with eyes. Avoid contact with skin or clothing. Do not breathe vapours/dust.
8. Exposure Controls / Personal Protection
Ethylene Glycol (107-21-1)
US. ACGIH Threshold Limit Values
Ceiling Limit Value: 100 mg/m3 (Aerosol.)
US. ACGIH Threshold Limit Values
Hazard Designation: Group A4 Not classifiable as a human carcinogen.
Industrial Hygiene/Ventilation Measures
Use local and general exhaust ventilation to control levels of exposure.
Respiratory Protection
In case of insufficient ventilation wear suitable respiratory equipment.
Hand Protection
Permeation resistant gloves.
Eye Protection
Chemical safety goggles or safety glasses with side-shields.
Skin and body protection
Wear cloth work clothing including long pants and long-sleeved shirts.
Additional Protective Measures
Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate
and train employees in the safe use and handling of this product.
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 4 of 12 Report Version: 1.1
9. Physical and chemical properties
liquid
Form:
Amber, Brown
Color:
slight, Ether, Amine
Odor:
8.5 - 10.5
pH:
Not Established
Freezing Point:
Not Established
Boiling Point/Range:
Not Established
Vapor Pressure:
Not Established
Specific Gravity:
Partially soluble
Solubility in Water:
10. Stability and Reactivity
Hazardous Reactions
Hazardous polymerization does not occur.
Stability
Stable
Materials to avoid
oxidizing agents, Isocyanates
Hazardous decomposition products
By Fire: Carbon Dioxide; Carbon Monoxide; other aliphatic fragments which have not been determined
11. Toxicological Information
Toxicity Data for Hydrofluorocarbon
Acute Inhalation Toxicity
LC50: >200,000 ppm, 4 h (Rat)
Acute dermal toxicity
LD50: > 2,000 mg/kg (Rat)
Skin Irritation
rabbit, Non-irritating
Eye Irritation
rabbit, Mild eye irritation
Sensitization
non-sensitizer (Dog)
Repeated Dose Toxicity
28 d, inhalation: NOAEL: 50,000 ppm, (Rat)
90 d, Inhalation: NOAEL: 2000 ppm, (Rat)
Mutagenicity
Genetic Toxicity in Vitro:
Cytogenetic assay: ambiguous (human lymphocytes, Metabolic Activation: with/without)
Ames: negative (Metabolic Activation: with/without)
Genetic Toxicity in Vivo:
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 5 of 12 Report Version: 1.1
Micronucleus Assay: negative (mouse)
Developmental Toxicity/Teratogenicity
No Teratogenic effects observed at doses tested.
Toxicity Data for Polyether Polyol
Acute Oral Toxicity
LD50: > 5,000 mg/kg (Rat)
Acute Inhalation Toxicity
LC0: 2516 mg/m3, 6 hrs (Rat)
Acute dermal toxicity
LD50: > 5,000 mg/kg (rabbit)
Eye Irritation
rabbit, No eye irritation
Mutagenicity
Genetic Toxicity in Vitro:
Ames: negative
Genetic Toxicity in Vivo:
negative (Drosophila melanogaster, )
Developmental Toxicity/Teratogenicity
rat, female, oral, gestation, NOAEL (teratogenicity): 10,000 mg/kg,
No Teratogenic effects observed at doses tested.
Toxicity Data for Tris-(2-chloroisopropyl)-phosphate
Acute Oral Toxicity
LD50: 632 mg/kg (Rat)
Acute Inhalation Toxicity
LC50: > 17,800 mg/l, aerosol, 1 hrs (rat, Male/Female)
Acute dermal toxicity
LD50: > 5,000 mg/kg (rabbit, Male/Female)
Skin Irritation
Human, Patch Test, No skin irritation
rabbit, No skin irritation
Eye Irritation
rabbit, Draize, Exposure Time: 24 hrs, Mild eye irritation
rabbit, No eye irritation
Sensitization
dermal: non-sensitizer (guinea pig, Maximisation Test (GPMT))
dermal: non-sensitizer (Human, Patch Test)
Repeated Dose Toxicity
90 Days, oral: NOAEL: 36 mg/kg, (Rat, male)
Mutagenicity
Genetic Toxicity in Vitro:
Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without)
Positive and negative results were reported.
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 6 of 12 Report Version: 1.1
Mammalian cell - gene mutation assay: positive (Mouse lymphoma cells (L5178Y/TK), Metabolic
Activation: with)
Positive and negative results were reported.
Toxicity to Reproduction/Fertility
Other method, inhalation, daily, (rat, male)
Reproductive effects have been observed in animal studies.
Developmental Toxicity/Teratogenicity
rat, female, oral, gestation, daily, NOAEL (teratogenicity): > 1%, NOAEL (maternal): > 1%
No Teratogenic effects observed at doses tested. No fetotoxicity observed at doses tested.
Toxicity Data for Tertiary Amine
Acute Oral Toxicity
LD50: 3,250 uL/kg (Rat)
LD50: 2,800 mg/kg (Rat)
Acute dermal toxicity
LD50: > 1,000 mg/kg (rabbit)
Skin Irritation
rabbit, Corrosive
Toxicity Data for Ethylene Glycol
Acute Oral Toxicity
LD50: 4,700 mg/kg (Rat)
Acute Inhalation Toxicity
LC50: > 200 mg/m3, 2 hrs (rat)
Acute dermal toxicity
LD50: 10,600 mg/kg (rabbit)
Skin Irritation
rabbit, Draize Test, Slightly irritating
Eye Irritation
rabbit, Draize Test, Slightly irritating
Repeated Dose Toxicity
16 Weeks, Inhalation: NOAEL: 3.49 mg/l, (Rat, Male/Female, daily)
Mutagenicity
Genetic Toxicity in Vitro:
Ames: Negative results were reported in various in vitro studies. (Salmonella typhimurium, Metabolic
Activation: with/without)
Genetic Toxicity in Vivo:
Dominant Lethal Assay: negative (rat, male, oral)
Drosophila SLRL test: positive (Drosophila melanogaster, )
Micronucleus Assay: negative (mouse, )
Carcinogenicity
rat, oral, 2 years, daily
Did not show carcinogenic effects in animal experiments.
mouse, dermal, lifetime, daily
negative
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 7 of 12 Report Version: 1.1
Toxicity to Reproduction/Fertility
Fertility Screening, oral, (mouse, Male/Female) NOAEL (parental): 2,500 mg/kg, NOAEL (F1): > 750
mg/kg,
No effects on Reproductive parameters observed at doses tested.
Three generation study, oral, daily, (rat) NOAEL (parental): > 1,000 mg/kg, NOAEL (F1): > 1,000 mg/kg,
NOAEL (F2): > 1,000 mg/kg,
Developmental Toxicity/Teratogenicity
rabbit, female, dermal, NOAEL (teratogenicity): approximately 2,000 mg/kg, NOAEL (maternal): > 1,000
mg/kg,
Fetotoxicity has been observed in animal studies. Teratogenic effects have been observed in animal studies.
Rat, female, oral, NOAEL (teratogenicity): < 500 mg/kg, NOAEL (maternal): 1,000 mg/kg,
Fetotoxicity has been observed in animal studies. Teratogenic effects have been observed in animal studies.
12. Ecological Information
Ecological Data for Hydrofluorocarbon
Acute and Prolonged Toxicity to Fish
LC50: > 97.9 mg/l (Rainbow trout (Salmo gairdneri), 48 h)
Acute Toxicity to Aquatic Invertebrates
EC50: 81.8 mg/l (Water flea (Daphnia magna), 96 h)
Ecological Data for Polyether Polyol
Biological Oxygen Demand (BOD)
5 Days, 6 %
20 Days, 77 %
Chemical Oxygen Demand (COD)
1.84 mg/g
Acute and Prolonged Toxicity to Fish
LC50: > 10,000 mg/l (Fathead minnow (Pimephales promelas), 96 hrs)
Acute Toxicity to Aquatic Invertebrates
EC50: > 10,000 mg/l (Water flea (Daphnia magna), 48 hrs)
Toxicity to Microorganisms
> 5,000 mg/l, (16 hrs)
Ecological Data for Tris-(2-chloroisopropyl)-phosphate
Biodegradation
Aerobic, 0 %, Exposure time: 28 Days, Not readily biodegradable.
Bioaccumulation
Carp, Exposure time: 42 Days, approximately 0.8 - 2.8 BCF
Acute and Prolonged Toxicity to Fish
LC50: approximately 84 mg/l (Bluegill (Lepomis macrochirus), 96 hrs)
LC50: 51 mg/l (Fathead minnow (Pimephales promelas), 96 hrs)
LC50: 30 mg/l (Guppy (Poecilia reticulata), 96 hrs)
Acute Toxicity to Aquatic Invertebrates
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 8 of 12 Report Version: 1.1
EC50: approximately 131 mg/l (Water flea (Daphnia magna), 48 hrs)
Toxicity to Aquatic Plants
EC50: 45 mg/l, End Point: biomass (Green algae (Scenedesmus subspicatus), 72 hrs)
EC50: 41 - 55 mg/l, End Point: biomass (Green algae (Selenastrum capricornutum), 96 h)
Toxicity to Microorganisms
EC50: 295 mg/l, (Photobacterium phosphoreum, 30 min)
EC50: 784 mg/l, (Activated sludge microorganisms, 3 hrs)
Ecological Data for Ethylene Glycol
Biodegradation
Aerobic, > 40 %, Exposure time: 20 Days
Biological Oxygen Demand (BOD)
5 Days, 0.78 - 1.81 g/g
Chemical Oxygen Demand (COD)
1.19 - 1.29 g/g
Theoretical Biological Oxygen Demand (ThBOD)
1.26 - 1.29 g/g
Bioaccumulation
Golden orfe, Exposure time: 3 Days, 10 BCF
Acute and Prolonged Toxicity to Fish
41,000 mg/l (Coho salmon, silver salmon (Oncorhynchus kisutch), 96 hrs)
LC50: 49,000 - 57,000 mg/l (Fathead minnow (Pimephales promelas), 96 hrs)
LC50: 18,500 mg/l (Rainbow trout (Salmo gairdneri), 96 hrs)
Acute Toxicity to Aquatic Invertebrates
EC50: 46,300 - 57,600 mg/l (Water flea (Daphnia magna), 48 hrs)
EC50: 13,900 - 29,700 mg/l (Ceriodaphnia sp, 48 hrs)
Toxicity to Aquatic Plants
EC50: 6,500 - 13,000 mg/l, End Point: growth (Green algae (Selenastrum capricornutum), 96 hrs)
Toxicity to Microorganisms
EC50: 10,000 mg/l, (Pseudomonas putida, 16 hrs)
EC50: 621 mg/l, (Photobacterium phosphoreum, 30 min)
13. Disposal considerations
Waste Disposal Method
Waste disposal should be in accordance with existing federal, state and local environmental control laws.
Empty Container Precautions
Recondition or dispose of empty container in accordance with governmental regulations.
14. Transportation information
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 9 of 12 Report Version: 1.1
Land transport (DOT)
Non-Regulated
Sea transport (IMDG)
Non-Regulated
Air transport (ICAO/IATA)
Aviation regulated liquid, n.o.s. (contains Hydrofluorocarbon)
Proper Shipping Name:
9
Hazard Class or Division:
UN3334
UN-No:
Packaging Group:
Miscellaneous
Hazard Label(s):
15. Regulatory Information
United States Federal Regulations
Hazardous
OSHA Hazcom Standard Rating:
Listed on the TSCA Inventory.
US. Toxic Substances Control Act:
US. EPA CERCLA Hazardous Substances (40 CFR 302):
Components
Ethylene Glycol Reportable quantity: 5,000 lbs
SARA Section 311/312 Hazard Categories:
Acute Health Hazard, Chronic Health Hazard
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A):
Components
None
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required:
Components
Ethylene Glycol
US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes
and Appendix VIII Hazardous Constituents (40 CFR 261):
If discarded in its purchased form, this product would not be a hazardous waste either by listing or by
characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time
of disposal, whether a material containing the product or derived from the product should be classified as a
hazardous waste. (40 CFR 261.20-24)
State Right-To-Know Information
The following chemicals are specifically listed by individual states; other product specific health and safety
data in other sections of the MSDS may also be applicable for state requirements. For details on your
regulatory requirements you should contact the appropriate agency in your state.
Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:
Weight % Components CAS-No.
>=1% Polyester Polyol
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 10 of 12 Report Version: 1.1
7 - 13% Hydrofluorocarbon 460-73-1
>=1% Polyether Polyol 25322-68-3
5 - 10% Tris-(2-chloroisopropyl)-phosphate 13674-84-5
5 - 10% Brominated Flame Retardant CAS# is a trade secret
1 - 5% Ethylene Glycol 107-21-1
New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous
Substances Lists:
Weight % Components CAS-No.
1 - 5% Ethylene Glycol 107-21-1
Pennsylvania Right to Know Special Hazard Substance List:
Weight % Components CAS-No.
<0.075% 1,4-Dioxane 123-91-1
MA Right to Know Extraordinarily Hazardous Substance List:
Weight % Components CAS-No.
<0.075% 1,4-Dioxane 123-91-1
California Prop. 65:
Warning! This product contains chemical(s) known to the State of California to be Carcinogenic.
Weight % Components CAS-No.
<0.075% 1,4-Dioxane 123-91-1
<20 ppb Formaldehyde 50-00-0
16. Other Information
NFPA 704M Rating
2
Health
1
Flammability
0
Reactivity
Other
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
HMIS Rating
2*
Health
1
Flammability
0
Physical Hazard
0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe
* = Chronic Health Hazard
The method of hazard communication for Bayer MaterialScience LLC is comprised of Product Labels and
Material Safety Data Sheets. HMIS and NFPA ratings are provided by Bayer MaterialScience LLC as a
customer service.
Contact Person: Product Safety Department
Telephone: (412) 777-2835
MSDS Number: 000000010016
Version Date: 09/13/2008
Report Version: 1.1
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 11 of 12 Report Version: 1.1
This information is furnished without warranty, express or implied. This information is believed to be
accurate to the best knowledge of Bayer MaterialScience LLC. The information in this MSDS relates only
to the specific material designated herein. Bayer MaterialScience LLC assumes no legal responsibility for
use of or reliance upon the information in this MSDS.
Article Number: 80873353
Material Name: BAYSEAL 2.0 W
Page: 12 of 12 Report Version: 1.1
|