Safety Data Sheet
Dow Chemical Company Ltd
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Print Date: 09 Jan 2008
Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1. Identification of the substance/preparation and of the company/undertaking
Product Name
FROTH-PAK(TM) 600 Polyol QR
Use of the substance/preparation
Cavity sealing foam. Thermal insulation.
COMPANY IDENTIFICATION
Dow Chemical Company Ltd
Diamond House, Lotus Park
Kingsbury Crescent
TW18 3AG Staines, Middlesex
United Kingdom
Customer Information Number: 0203 139 4000
EMERGENCY TELEPHONE NUMBER
+44 (0) 1553 761 251
24-Hour Emergency Contact:
00 44 155 37 61 251
Local Emergency Contact:
2. Composition/information on ingredients
Component Amount Classification: CAS # EC #
Formulated polyol in
pressurized can
Blend of polyether polyols > 20.0 % Not classified. Confidential Polymers
("B" +"E")
Propylene glycol- 5.0 - 15.0 % Not classified. 25322-69-4 500-039-8
propylene oxide polymer
Polyester polyol 5.0 - 15.0 % Not classified. confidential Polymer
Diethylene glycol 2.0 - 5.0 % Xn: R22 111-46-6 203-872-2
1,1,1,2-Tetrafluoroethane 15.0 - 30.0 % Not classified. 811-97-2 212-377-0
2-ethylhexanoic acid 1.0 - 3.0 % Xi: R36 3164-85-0 221-625-7
potassium salt
Triethyl phosphate 1.0 - 3.0 % Xn: R22 78-40-0 201-114-5
Tris(1-chloro-2-propyl) 15.0 - 24.0 % Xn: R22 13674-84-5 237-158-7
phosphate
* Indicates a Trademark
Page 1 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
See Section 16 for full text of R-phrases.
Hazards Identification
3.
Harmful if swallowed.
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness
may be observed.
4. First-aid measures
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Wash skin with plenty of water.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Notes to Physician: Due to structural analogy and clinical data, this material may have a mechanism
of intoxication similar to ethylene glycol. On that basis, treatment similar to ethylene glycol intoxication
may be of benefit. In cases where several ounces (60 - 100 ml) have been ingested, consider the use
of ethanol and hemodialysis in the treatment. Consult standard literature for details of treatment. If
ethanol is used, a therapeutically effective blood concentration in the range of 100 - 150 mg/dl may be
achieved by a rapid loading dose followed by a continuous intravenous infusion. Consult standard
literature for details of treatment. 4-Methyl pyrazole (Antizol? is an effective blocker of alcohol
dehydrogenase and should be used in the treatment of ethylene glycol (EG), di- or triethylene glycol
(DEG, TEG), ethylene glycol butyl ether (EGBE), or methanol intoxication if available. Fomepizole
protocol (Brent, J. et al., New England Journal of Medicine, Feb. 8, 2001, 344:6, p. 424-9): loading
dose 15 mg/kg intravenously, follow by bolus dose of 10 mg/kg every 12 hours; after 48 hours,
increase bolus dose to 15 mg/kg every 12 hours. Continue fomepizole until serum methanol, EG,
DEG, TEG or EGBE are undetectable. The signs and symptoms of poisoning include anion gap
metabolic acidosis, CNS depression, renal tubular injury, and possible late stage cranial nerve
involvement. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving
significant exposure should be observed 24-48 hours for signs of respiratory distress. Maintain
adequate ventilation and oxygenation of the patient. In severe poisoning, respiratory support with
mechanical ventilation and positive end expiratory pressure may be required. Exposure may increase
"myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless
absolutely necessary. This material is a cholinesterase inhibitor. Treat symptomatically. Atropine,
only by injection, is the preferable antidote. Oximes, such as 2-PAM/protopam, may be therapeutic if
used early; however, use only in conjunction with atropine. If exposed, plasma and red blood cell
cholinesterase tests may indicate significance of exposure (baseline data are useful). In case of
severe acute poisoning, use antidote immediately after establishing an open airway and respiration.
Attempt seizure control with diazepam 5-10 mg (adults) intravenous over 2-3 minutes. Repeat every
5-10 minutes as needed. Monitor for hypotension, respiratory depression, and need for intubation.
Consider second agent if seizures persist after 30 mg. If seizures persist or recur administer
phenobarbital 600-1200 mg (adults) intravenous diluted in 60 ml 0.9% saline given at 25-50
mg/minute. Evaluate for hypoxia, dysrhythmia, electrolyte disturbance, hypoglycemia (treat adults with
dextrose 100 mg intravenous). If lavage is performed, suggest endotracheal and/or esophageal
control. Danger from lung aspiration must be weighed against toxicity when considering emptying the
stomach. Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.
Page 2 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
5. Fire Fighting Measures
Extinguishing Media: In case of fire, use water fog, foam, dry powder, carbon dioxide.
Fire Fighting Procedures: Down-wind personnel must be evacuated. Fire debris must be disposed
of in accordance with local regulations. Do not discharge extinguishing waters into streams, rivers and
lakes.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves).
Unusual Fire and Explosion Hazards: During a fire, smoke may contain the original material in
addition to combustion products of varying composition which may be toxic and/or irritating. Will
support combustion. Violent eruption of containers may occur under fire conditions.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon dioxide. Carbon monoxide. Hydrogen chloride.
Hydrogen fluoride. Phosphorous compounds. Phosphorus oxides.
6. Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Spills should be contained by, and covered
with large quantities of sand, earth or any other readily available absorbent material which is then
brushed in vigorously to assist absorption. The mixture can then be collected into drums and removed
for disposal. Wash area from residues with soap and water and rinse down.
Personal Precautions: Use appropriate safety equipment. For additional information, refer to Section
8, Exposure Controls and Personal Protection. Spilled material may cause a slipping hazard.
Environmental Precautions: Dike to prevent contamination of ground and surface water, then
transfer into closed containers. Recover if possible, or dispose of according to applicable regulations.
7. Handling and Storage
Handling
General Handling: Keep equipment clean.
Storage
Keep in a cool place, heat causes an increase in pressure and risk of bursting.
Storage Period: Storage temperature:
15 Months 15 - 25 癈
8. Exposure Controls / Personal Protection
Exposure Limits
Component List Type Value
|
Ireland OELV TWA 100 mg/m3 23 ppm
Diethylene glycol
WEEL TWA 10 mg/m3
UK WEL TWA 101 mg/m3 23 ppm
|
WEEL TWA 4,240 mg/m3 1,000 ppm
1,1,1,2-Tetrafluoroethane
UK WEL TWA 4,240 mg/m3 1,000 ppm
|
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or
equivalent.
Page 3 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective
gloves against chemicals and micro-organisms. Examples of acceptable glove barrier
materials include: Viton. Polyethylene. Chlorinated polyethylene. Polyvinyl alcohol ("PVA").
Ethyl vinyl alcohol laminate ("EVAL"). Examples of preferred glove barrier materials include:
Natural rubber ("latex"). Nitrile/butadiene rubber ("nitrile" or "NBR"). Avoid gloves made of:
Butyl rubber. When prolonged or frequently repeated contact may occur, a glove with a
protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN
374) is recommended. When only brief contact is expected, a glove with a protection class of
1 or higher (breakthrough time greater than 10 minutes according to EN 374) is
recommended. NOTICE: The selection of a specific glove for a particular application and
duration of use in a workplace should also take into account all relevant workplace factors
such as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to glove
materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: If tetrafluoroethane levels are above the guideline or unknown, wear
supplied air. If tetrafluoroethane levels are below the guideline, but an air purifying cartridge is required
for other components of this product, wear the following: Use the following CE approved air-purifying
respirator: Organic vapor cartridge with a particulate pre-filter, type AP2.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Provide general and/or local exhaust ventilation to control airborne levels below the
exposure guidelines. Lethal concentrations may exist in areas with poor ventilation.
9. Physical and Chemical Properties
Foam
Physical State
Brown
Color
Characteristic
Odor
No test data available
Flash Point - Closed Cup
Lower: No test data available
Flammable Limits In Air
Upper: No test data available
No test data available
Autoignition Temperature
No test data available
Vapor Pressure
No test data available.
Boiling Point (760 mmHg)
3.5 (1,1,1,2-tetrafluoroethane)
Vapor Density (air = 1)
No test data available
Specific Gravity (H2O = 1)
No test data available
Freezing Point
No test data available
Melting Point
Moderate
Solubility in Water (by
weight)
No test data available
pH
Not applicable
Dynamic Viscosity
10. Stability and Reactivity
Stability/Instability
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Because
of high vapour pressure, containers are liable to burst if temperature rises.
Hazardous Decomposition Products: Unlikely to be formed under normal industrial use.
Hazardous Polymerization
Will not occur by itself.
Page 4 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
11. Toxicological Information
Acute Toxicity
Ingestion
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling
operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
Single dose oral LD50 has not been determined. Estimated LD50, Rat > 2,000 mg/kg
Eye Contact
May cause moderate eye irritation. May cause slight corneal injury.
Skin Contact
Brief contact may cause slight skin irritation with local redness.
Skin Absorption
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
The dermal LD50 has not been determined. Estimated LD50, Rabbit > 2,000 mg/kg
Inhalation
Prolonged excessive exposure may cause adverse effects. In confined or poorly ventilated areas,
vapor can easily accumulate and can cause unconsciousness and death due to displacement of
oxygen. May cause respiratory irritation and central nervous system depression. Excessive exposure
may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats).
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness
may be observed.
Repeated Dose Toxicity
Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition. Signs and
symptoms of excessive exposure may be headache, dizziness, incoordination, muscle twitching,
tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation,
tearing, tightness in chest, excessive urination, convulsions. For the component(s) tested: In animals,
effects have been reported on the following organs: Liver. Bone marrow. Kidney. Central nervous
system. Bladder. Gastrointestinal tract. Adrenal gland.
Chronic Toxicity and Carcinogenicity
For the component(s) tested: Did not cause cancer in laboratory animals.
Developmental Toxicity
For the component(s) tested: Has been toxic to the fetus in lab animals at doses toxic to the mother.
For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the mother. Did
not cause birth defects in laboratory animals. Diethylene glycol has caused toxicity to the fetus and
some birth defects at maternally toxic, high doses in animals. Other animal studies have not
reproduced birth defects even at much higher doses that caused severe maternal toxicity.
Reproductive Toxicity
For the minor component(s): In laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals.
Genetic Toxicology
In vitro genetic toxicity studies were negative for component(s) tested. For the minor component(s):
(triethyl phosphate) In vitro genetic toxicity studies were negative in some cases and positive in other
cases. Genetic toxicity studies in animals were negative for component(s) tested. For the minor
component(s): (triethyl phosphate) Animal genetic toxicity studies were negative in some cases and
positive in other cases.
12. Ecological Information
CHEMICAL FATE
Data for Component: Propylene glycol-propylene oxide polymer
Movement & Partitioning
No bioconcentration is expected because of the relatively high molecular weight (MW greater
than 1000).
Page 5 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Persistence and Degradability
For this family of materials: Based on stringent OECD test guidelines, this material cannot be
considered as readily biodegradable; however, these results do not necessarily mean that the
material is not biodegradable under environmental conditions.
Data for Component: Polyester polyol
Movement & Partitioning
Based largely or completely on data for major component(s): Bioconcentration potential is low
(BCF < 100 or Log Pow < 3). Potential for mobility in soil is low (Koc between 500 and 2000).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Persistence and Degradability
Based largely or completely on data for major component(s): Biodegradation may occur under
aerobic conditions (in the presence of oxygen).
Data for Component: Diethylene glycol
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50). Given its very low Henry's constant,
volatilization from natural bodies of water or moist soil is not expected to be an important fate
process.
Henry's Law Constant (H): 7.96E-10 atm*m3/mole; 25 癈 Estimated
Partition coefficient, n-octanol/water (log Pow): -1.47 Estimated
Partition coefficient, soil organic carbon/water (Koc): < 1 Estimated
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is
ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent
biodegradability).
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
92 % 28 d OECD 301C Test
82 - 98 % 28 d OECD 302C Test
Data for Component: 1,1,1,2-Tetrafluoroethane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is high (Koc between 50 and 150).
Henry's Law Constant (H): 5.00E-2 atm*m3/mole; 25 癈 Measured
Partition coefficient, n-octanol/water (log Pow): 1.68 Estimated
Partition coefficient, soil organic carbon/water (Koc): 97 Estimated
Persistence and Degradability
1,1,1,2-Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential (ODP) of
zero, relative to CFC 12 (ODP=1). Material is expected to biodegrade only very slowly (in the
environment). Fails to pass OECD/EEC tests for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
4% 28 d OECD 301D Test
Data for Component: 2-ethylhexanoic acid potassium salt
Movement & Partitioning
Based largely or completely on information for similar material(s). Bioconcentration potential is
low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is very high (Koc between 0 and
50).
Page 6 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Persistence and Degradability
Based largely or completely on information for similar material(s). Material is expected to be
readily biodegradable. Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
Data for Component: Triethyl phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from
natural bodies of water or moist soil is not expected to be an important fate process.
Henry's Law Constant (H): 3.60E-08 atm*m3/mole Measured
Partition coefficient, n-octanol/water (log Pow): 0.80 Measured
Partition coefficient, soil organic carbon/water (Koc): 48 Estimated
Data for Component: Tris(1-chloro-2-propyl) phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is
low (Koc between 500 and 2000).
Henry's Law Constant (H): < 1.35E-5 atm*m3/mole; 25 癈 Estimated
Partition coefficient, n-octanol/water (log Pow): 2.59 Measured
Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated
Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured
Persistence and Degradability
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
14 % 28 d OECD 301E Test
Data for Component: Polyether polyol "B"
Movement & Partitioning
No bioconcentration is expected because of the relatively high molecular weight (MW greater
than 1000).
Persistence and Degradability
For this family of materials: Based on stringent OECD test guidelines, this material cannot be
considered as readily biodegradable; however, these results do not necessarily mean that the
material is not biodegradable under environmental conditions.
Data for Component: Polyether polyol "E"
Movement & Partitioning
No bioconcentration is expected because of the relatively high water solubility.
Persistence and Degradability
Based largely or completely on information for similar material(s). Material is inherently
biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegradability).
ECOTOXICITY
Data for Component: Propylene glycol-propylene oxide polymer
For this family of materials: Material is not classified as dangerous to aquatic organisms
(LC50/EC50/IC50 greater than 100 mg/L in most sensitive species).
Data for Component: Polyester polyol
Not expected to be acutely toxic to aquatic organisms.
Data for Component: Diethylene glycol
Page 7 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), 96 h: > 1,000 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 48,900 mg/l
Aquatic Plant Toxicity
EC50, diatom Skeletonema costatum, biomass growth inhibition, 72 h: > 1,000 mg/l
Toxicity to Micro-organisms
IC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: > 1,000 mg/l
Data for Component: 1,1,1,2-Tetrafluoroethane
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 450 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, immobilization: 980 mg/l
Data for Component: 2-ethylhexanoic acid potassium salt
Based largely or completely on information for similar material(s). Material is harmful to
aquatic organisms (LC50/EC50/IC50 between 10 and 100 mg/L in most sensitive species).
Data for Component: Triethyl phosphate
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, Japanese medaka (Oryzias latipes), static, 48 h: > 500 mg/l
Data for Component: Tris(1-chloro-2-propyl) phosphate
Material is harmful to aquatic organisms (LC50/EC50/IC50 between 10 and 100 mg/L in most
sensitive species).
Fish Acute & Prolonged Toxicity
LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l
Aquatic Plant Toxicity
EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96 h: 47 mg/l
EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l
Toxicity to Micro-organisms
EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l
Aquatic Invertebrates Chronic Toxicity Value:
ChV Value mg/l Species Test Type Endpoint Exposure Time
> 32 mg/l water flea static renewal number of 21 d
Daphnia magna offspring
Data for Component: Polyether polyol "B"
For this family of materials: Material is not classified as dangerous to aquatic organisms
(LC50/EC50/IC50 greater than 100 mg/L in most sensitive species).
Data for Component: Polyether polyol "E"
Based largely or completely on information for similar material(s). Material is not classified as
dangerous to aquatic organisms (LC50/EC50/IC50 greater than 100 mg/L in most sensitive
species).
13. Disposal Considerations
Page 8 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Contents under pressure. Do not puncture or incinerate container. Relieve all pressure prior to
disposal. Do not dump into any sewers, on the ground, or into any body of water. The generation of
waste should be avoided or minimized wherever possible. Refer to manufacturer/supplier for
information on recovery/recycling. Any disposal practice must be in compliance with all local and
national laws and regulations.
14. Transport Information
ROAD & RAIL
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2 ID Number: UN1956
Classification: 1A
Kemler Code: 20
Tremcard Number: 20G1A
OCEAN
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2 ID Number: UN1956
EMS Number: F-C,S-V
Marine pollutant.: No
AIR
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2 ID Number: UN1956Cargo Packing Instruction: 200
Passenger Packing Instruction: 200
INLAND WATERWAYS
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: 1,1,1,2-Tetrafluoroethane
Hazard Class: 2.2 ID Number: UN1956
Classification: 1A
Kemler Code: 20
Tremcard Number: 20G1A
15. Regulatory Information
European Inventory of Existing Commercial Chemical Substances (EINECS)
The components of this product are on the EINECS inventory or are exempt from inventory
requirements.
EC Classification and User Label Information
Hazard Symbol :
Xn - Harmful.
Risk Phrases :
R22 - Harmful if swallowed.
Safety Phrases :
S23 - Do not breathe vapour/gas/fumes/spray.
S51 - Use only in well-ventilated areas.
S2 - Keep out of the reach of children.
Page 9 of 10
Product Name: FROTH-PAK(TM) 600 Polyol QR Revision Date: 2006/10/07
Container is under pressure.
Keep out of reach of children.
Protect from sun and temperatures above 50癈.
During shipment and storage the product container must be kept closed and protected against direct
sunlight.
Do not open with force or incinerate even after use.
To avoid risk for man and the environment, follow the use instructions.
16. Other Information
Risk-phrases in Section 2
R22 Harmful if swallowed.
R36 Irritating to eyes.
R52 Harmful to aquatic organisms.
Revision
Identification Number: 82583 / 3005 / Issue Date 2006/10/07 / Version: 4.3
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
Page 10 of 10
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