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MSDS Material Safety Data Sheet
CAS

68152-81-8 13674-84-5 7732-18-5 3030-47-5

File Name: 68152-81-8_13674-84-5_7732-18-5_3030-47-5.asp

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Material Safety Data Sheet
Product: SoyTherm?50 B-side
MSDS Date: 2-1-2008
Product Name: SoyTherm?50 B-side
Manufacturer: Urethane Soy Systems Company

I. Product and Company Description

Urethane Soy Systems Company
100 Caspian Avenue
Volga, SD 57071
Emergency Phone Number:
(888) 514-9096
For Product Information:
(888) 514-9096
Product Description:
Polyol Blend
Product Use:
Intended to produce spray foam insulation
Chemical Name or Synonym:
NA
Molecular Formula:
NA

II. Chemical Composition

Component CAS# %Composition
Polyol 68152-81-8 0-50
Halogenated Phosphate Ester 13674-84-5 0-50
Polyether Polyol Trade Secret 0-25
Water 7732-18-5 0-20
Amine Catalyst 3030-47-5 0-5
Silicone Surfactant Trade Secret 0-5

III. Hazards Identification

A. Emergency Overview:
Physical Appearance and Odor:
Opaque liquid with mild amine odor

B. Potential Health Effects:
Acute Eye:
Contact with eyes may cause moderate to severe irritation. Symptoms may include stinging, tearing, redness, swelling,
and blurred vision.




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Acute Skin:
Contact with skin may cause moderate to severe irritation.
Acute Inhalation:
Vapor, mist or dust of product may be moderately to severely irritating to the respiratory tract and mucous membranes.
Acute ingestion:
This product may be harmful if swallowed.
Chronic effects:
Not determined

IV. First Aid Measures

First Aid Measures for Accidental:
Eye Exposure:
Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. Remove contact lenses after
flushing.
Skin Exposure:
Wash affected area with soap and water. Get medical attention if irritation develops or persists.
Inhalation:
Remove to fresh air. Seek medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion:
Get immediate medical attention or advice. Never give anything by mouth to an unconscious person.

V. Fire Fighting Measures

Fire Hazard Data:
Autoignition Temperature: ND
Flash Point: <230篎
Flammability Limits (vol/vol%): Lower: ND Upper: ND
Extinguishing Media:
Foam, Carbon Dioxide, or dry chemical
Special Fire Fighting Procedures:
Firefighters should use self contained breathing apparatus with full-face piece operated in the pressure demand or
other positive pressure mode.
Unusual Fire and Explosion Hazards:
May generate ammonia and nitrogen oxide gases under fire conditions. Incomplete combustion may form carbon
monoxide. Fire or intense heat may cause violent rupture of packages. Flash back possible over considerable distance.
May form explosive mixtures in air.
Hazardous Decomposition Materials (Under Fire Conditions):
Combustion produces oxides of carbon, phosphorus and nitrogen, amines, hydrogen chloride, acroliene, nitric acid,
ketones, aldehydes and silicon dioxide.

VI. Accidental Release Measures

Cleanup and Disposal of Spill:
Isolate spill or leak area immediately. Keep unauthorized personnel away. Contain and absorb large spillage onto an
inert, non-flammable adsorbent carrier such as earth or sand. Shovel into open-top drums or plastic bags for further
decontamination, if necessary. Dispose of materials according to the applicable Federal, State, or local regulations.




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VII. Handling and Storage

Handling:
Avoid contact with skin and eyes. Avoid breathing vapors, mists or dusts of this material. Use only with adequate
ventilation to ensure that the occupational exposure limit is not exceeded. Wash thoroughly after handling. Wash hands
before eating, drinking, smoking, or using toilet facilities. As with all chemicals, good industrial hygiene practices should
be followed when handling this material.
Storage:
Store in cool, dry, well-ventilated areas away from sources of ignition. Keep containers closed when not in use.

VIII. Exposure Controls / Personal Protection

Exposure Guidelines:
Exposure limits
Component ACGIH NIOSH OSHA-PELs
Polyol NA NA NA
Water NA NA NA
Halogenated Phosphate Ester ND ND ND
0.75 ppm (8 hrs)
Polyether Polyol 0.3 ppm (15 min ceiling) ND
2 ppm (15 min)
0.05 ppm (skin)
Amine Catalyst ND ND
0.15 ppm (STEL)
200 ppm (TWA) 400 ppm (REL)
Trade Secret 400 ppm
400 ppm (STEL) 500 ppm (STEL)

Engineering Controls:
Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s) outlined in the
MSDS.
Respiratory Protection:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH
or EN approved respirator when necessary.
Eye / Face Protection:
Wear appropriate face-shield or chemical goggles as described by OSHA's eye and face protection regulations in
29CFR 1910.133 or European Standard EN166.
Skin Protection:
Use chemical resistant gloves such as nitrile. Work clothing sufficient to prevent all skin contact should be worn, such
as coveralls and long sleeves.

IX. Physical and Chemical Properties

Physical Appearance: Cream-colored Opaque liquid
Odor: Mild amine
Boiling Point: >300?C
pH: 9-10
Density: 1.14
Water Solubility: Insoluble
Melting Point Range: NA



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Viscosity: 400-800 cp
Percent Volatiles by Volume: ND

X. Stability and Reactivity

Chemical Stability:
Stable under standard use and storage conditions.
Conditions to Avoid:
High temperatures and freezing.
Materials / Chemicals to be Avoided:
Strong oxidizers, acids, bases
Hazardous Decomposition Products:
Oxides of carbon, phosphorus and nitrogen, amines, hydrogen chloride, acroliene, nitric acid, ketones, aldehydes and
silicon dioxide.
Hazardous Polymerization:
Will not occur.

XI. Toxicological Information

For Polyether Polyol
LD50/LC50: Oral rat LD50: 2000-5000 mg/kg; Skin rabbit LD50: 1000-2000 mg/kg

For Amine Catalyst
Rabbit-skin LD 50: 280 mg/kg Rat Oral LD 50 1630 mg/kg

Inhalation
Vapor, mist or dust of product may be moderately to severely irritating to the respiratory tract and mucous membranes.
Skin Contact
Contact with skin may cause moderate to severe irritation.
Eye Contact
Contact with eyes may cause moderate to severe irritation. Symptoms may include stinging, tearing, redness, swelling,
and blurred vision.
Ingestion
This product may be harmful if swallowed.
Carcinogenic Effects
The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by
OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects
There is no substantial evidence of mutagenic potential.
Reproductive Effects
No adverse reproductive effects are anticipated.
Teratogenic Effects
Not Determined

XII. Ecological Information

Ecotoxicological Information:
Not Determined
Chemical Fate Information:
Not Determined



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XIII. Disposal Considerations

Waste Disposal Method:
Discard any product, residue, disposable container or liner in full compliance with federal, state, and local regulations.
Container Handling and Disposal:
Dispose of container and unused contents in accordance with federal, state, and local regulations.

XIV. Transportation Information

US Department of Transportation Shipping Name:
US Department of Transportation Proper Shipping Name Not Regulated
Hazard Class Not Regulated
ID Number Not Regulated
Packaging Group Not Regulated
Label Statement Not Regulated

XV. Regulatory Information

Federal Regulations:
SARA Title III Hazard Classes:
Fire Hazard: NO
Reactive Hazard: NO
Release of Pressure: NO
Acute Health Hazard: YES
Chronic Health Hazard: NO
Toxic Substances Control Act (TSCA):
All components are included in the inventory or are not required to be listed.

Other Federal Regulations:
State Regulations:
The components identified with an X are present on the respective state's Right To Know lists:
Component MA PA MI NJ IL
Polyol
Water
Polyether Polyol
Halogenated Phosphate Ester
Amine Catalyst X
Trade Secret

XVI. Other Information

National Fire Protection Association Hazard Ratings ?NFPA?
Health Hazard: 2
Flammability: 1
Reactivity: 1




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Key Legend Information:
N/A ?Not Applicable
ND ?Not Determined
ACGIH ?American Conference of Governmental Industrial Hygienists
OSHA ?Occupational Safety and Health Administration
TLV ?Threshold Limit Value
PEL ?Permissible Exposure Limit
TWA ?Time Weighted Average
STEL ?Short Term Exposure Limit
NTP ?National Toxicology Program
IARC ?International Agency for Research on Cancer


The information contained herein is based on the data available to us and is believed to be correct. However Urethane
Soy Systems Company makes no warranty, expressed or implied regarding the accuracy of these data or the results
to be obtained from the use thereof.




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