SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
SOUDAFOAM FR
1. Identification of the substance/preparation and the company
1.1 Identification of the substance or preparation:
Not applicable
1.2 Use of the substance or the preparation:
Polyurethane
1.3 Company/undertaking identification:
SOUDAL N.V.
Everdongenlaan 18-20
B-2300 Turnhout
Tel. : +32 14 42 42 31
Fax : +32 14 44 39 71
1.4 Telephone number for emergency:
+32 14 58 45 45
Brandweerinformatiecentrum voor gevaarlijke stoffen (B.I.G.)
Technische Schoolstraat 43 A, B-2440 Geel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
tris(2-chloro-1-methylethyl) 13674-84-5 < 25 - 52/53 (1)
phosphate
237-158-7
polymethylene polyphenyl 9016-87-9 30 - 60 Xn 20-36/37/38-42/43
isocyanate (1)
-
halogenated polyetherpolyol 86675-46-9 1 - 10 Xn 22 (1)
-
norflurane 811-97-2 1 - 10 - -
212-377-0
dimethyl ether 115-10-6 1 - 10 F+ 12 (1)
204-065-8
isobutane 75-28-5 1 - 10 F+ 12 (1)
200-857-2
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Extremely flammable
- Harmful by inhalation
- Irritating to eyes, respiratory system and skin
- May cause sensitization by inhalation and skin contact
Printing date : 10-2004 1/11
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
! +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 15-07-2004 Revision date : 12-10-2004
Reference number : BIG\40671GB Revision number : 001
Reason for revision : See 2 -15
SOUDAFOAM FR
4. First aid measures
4.1 Eye contact:
- Rinse immediately with plenty of water
- Seek medical advice
4.2 Skin contact:
- Rinse immediately with plenty of water
- If irritation persists: seek medical advice
4.3 After inhalation:
- Remove the victim into fresh air
- Seek medical advice
4.4 After ingestion:
- Never give water to an unconscious person
- Do not induce vomiting
- Seek medical advice
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Quantities of water
- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- None
5.3 Special exposure hazards:
- Gas/vapour spreads at floor level: ignition hazard
- Gas/vapour flammable with air within explosion limits
- On heating: release of toxic/combustible gases/vapours: hydrogen cyanide
- Aerosol may explode under the effect of heat
5.4 Instructions:
- Cool closed containers with water if they are exposed to the fire
- Dilute toxic gases with water spray
- Do not move the load if exposed to heat
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Use appropriate containment to avoid environmental contamination
6.3 Methods of cleaning up:
- Allow product to solidify and remove it by mechanical means
- Remove uncured foam with acetone
Printing date : 10-2004 2/11
SOUDAFOAM FR
7. Handling and storage
7.1 Handling:
- Observe very strict hygiene - avoid contact
- Use spark-/explosionproof appliances and lighting system
- Remove contaminated clothing immediately
- Clean contaminated clothing
7.2 Storage:
- Keep out of direct sunlight
- Store in a cool area
- Store in a dry area
- Ventilation at floor level
- Keep away from: heat sources, ignition sources, acids, bases
Storage temperature : < 50 癈
Quantity limits : N.D. kg
Storage life : 365 days
Materials for packaging :
- suitable : aerosol dispenser
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
POLYMETHYLENE POLYPHENYL ISOCYANATE:
mg/m3
TLV-TWA : ppm
mg/m3
TLV-STEL : ppm
mg/m3
TLV-Ceiling : ppm
mg/m3
MEL-LTEL : 0.02(-NCO) - ppm
mg/m3
MEL-STEL : 0.07(-NCO) - ppm
NORFLURANE:
mg/m3
OES-LTEL : 4240 1000 ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : 4200 1000 ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 4200
mg/m3
MAC-TGG 15 min. :
mg/m3
MAC-Ceiling :
DIMETHYL ETHER:
mg/m3
OES-LTEL : 766 400 ppm
mg/m3
OES-STEL : 958 500 ppm
mg/m3
MAK : 1900 1000 ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 950
mg/m3
MAC-TGG 15 min. : 1500
mg/m3
MAC-Ceiling :
mg/m3
GWBB-8 h : 1920 1000 ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : 1920 1000 ppm
mg/m3
EC-STEL :- - ppm
Printing date : 10-2004 3/11
SOUDAFOAM FR
PROPANE:
mg/m3
MAK : 1800 1000 ppm
mg/m3
TRK : ppm
ISOBUTANE:
mg/m3
MAK : 2400 1000 ppm
mg/m3
TRK : ppm
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Use only in well ventilated area
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- In case of insufficient ventilation: respiratory protection with
filtertype A
8.3.2 hand protection:
- Chemically resistant gloves
8.3.3 eye protection:
- Safety glasses
8.3.4 skin protection:
- Suitable protective clothing
9. Physical and chemical properties
9.1 General information:
Appearance (at 20癈) : Aerosol
Odour : Characteristic
Colour : Variable in colour
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : N.D. 癈
Flashpoint : Contains a (highly) flammable
component
Explosion limits : N.D. Vol%
Vapour pressure (at 20癈) : N.D. hPa
Vapour pressure (at 50癈) : N.D. hPa
Relative density (at 20癈) : N.D.
Water solubility : Insoluble
Soluble in : Organic solvents
Relative vapour density : >1
Viscosity (at 20癈) : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 癈
Auto-ignition point : N.D. 癈
g/m3
Saturation concentration : N.D.
Printing date : 10-2004 4/11
SOUDAFOAM FR
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Unstable on exposure to heat
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources, acids, bases
10.3 Hazardous decomposition products:
- On heating: release of toxic/combustible gases/vapours: hydrogen cyanide
- May polymerize on exposure to temperature rise
- On burning: release of toxic and corrosive gases/vapours: phosphorus
oxides, nitrous vapours, hydrogen chloride, hydrofluoric acid, carbon
monoxide, carbon dioxide and formation of small quantities of hydrobromic
acid
- Polymerizes with many compounds e.g.: (strong) bases and amines
- Reacts violently with (some) acids/bases
11. Toxicological information
11.1 Acute toxicity:
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE:
LD50 oral rat : 3600 mg/kg
LD50 dermal rabbit : > 2000 mg/kg
LD50 dermal rabbit : > 2000 mg/kg
LC50 inhalation rat : >5 mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
POLYMETHYLENE POLYPHENYL ISOCYANATE:
LD50 oral rat : > 10000 mg/kg
LD50 dermal rabbit : N.D. mg/kg
LD50 dermal rabbit : > 5000 mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
NORFLURANE:
LD50 oral rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : > 2000 mg/l/4 h
LC50 inhalation rat : > 500000 ppm/4 h
DIMETHYL ETHER:
LD50 oral rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : 309 mg/l/4 h
LC50 inhalation rat : 163991 ppm/4 h
PROPANE:
LD50 oral rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : 513 mg/l/4 h
LC50 inhalation rat : 280000 ppm/4 h
ISOBUTANE:
LD50 oral rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : > 50 mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
Printing date : 10-2004 5/11
SOUDAFOAM FR
11.2 Chronic toxicity:
NORFLURANE:
Teratogenicity (MAK) : Group C
DIMETHYL ETHER:
Teratogenicity (MAK) : Group D
11.3 Routes of exposure: inhalation, eyes and skin
11.4 Acute effects/symptoms (upon overexposure):
AFTER INHALATION:
- Dry/sore throat
- Coughing
- Irritation of the respiratory tract
- Irritation of the nasal mucous membranes
- Runny nose
FOLLOWING SYMPTOMS MAY APPEAR LATER:
- Inflammation of the respiratory tract
- Risk of lung oedema
- Respiratory difficulties
AFTER SKIN CONTACT:
- Tingling/irritation of the skin
AFTER EYE CONTACT:
- Irritation of the eye tissue
- Lacrimation
11.5 Chronic effects:
- May cause sensitization by skin contact
- May cause sensitization by inhalation
- Contains substance of group C (MAK-Schwangerschaftsgruppe) (norflurane)
- Not listed in mutagenicity class (EC,MAK)
ON CONTINUOUS EXPOSURE/CONTACT:
- Body temperature rise
- Tremor
- Feeling of weakness
- Headache
- Skin rash/inflammation
- May stain the skin
- Dry skin
- Risk of pneumonia
Printing date : 10-2004 6/11
SOUDAFOAM FR
12. Ecological information
12.1 Ecotoxicity:
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE:
- LC50 (96 h) : 56.2 mg/l (BRACHYDANIO RERIO)
- EC50 (48 h) : 65/335 mg/l (DAPHNIA MAGNA)
- EC50 (96 h) : 57/97 mg/l (SELENASTRUM CAPRICORNUTUM)
12.2 Mobility:
- Volatile organic compounds (VOC): > 12.9%
- Insoluble in water
For other physicochemical properties see section 9
12.3 Persistence and degradability:
- Biodegradation BOD5 : N.D. % ThOD
- Water : No data available
- Soil : T? N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :2 (classification based on the components in compliance
with Verwaltungsvorschrift wassergef鋒rdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone
layer (1999/45/EC)
- Greenhouse effect : No data available
- Effect on waste water purification : No data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 05 01* (waste isocyanates)
- Waste material code (Flanders): 015; 651
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Specific treatment
- Do not discharge into drains or the environment
13.3 Packaging:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 10-2004 7/11
SOUDAFOAM FR
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 1950
CLASS : 2.2
SUB RISKS : -
PACKING : -
PROPER SHIPPING NAME :
UN 1950, Aerosols
14.2 ADR (transport by road)
CLASS : 2
PACKING :
CLASSIFICATION CODE : 5A
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 2.2
14.3 RID (transport by rail)
CLASS : 2
PACKING :
CLASSIFICATION CODE : 5A
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 2.2
14.4 ADNR (transport by inland waterways)
CLASS : 2
PACKING :
CLASSIFICATION CODE : 5A
DANGER LABEL TANKS : -
DANGER LABEL PACKAGES : 2.2
14.5 IMDG (maritime transport)
CLASS : 2.2
SUB RISKS : -
PACKING : -
MFAG : -
EMS : F-D, S-U
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 2.2
SUB RISKS : -
PACKING : -
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 203/Y203
PACKING INSTRUCTIONS CARGO AIRCRAFT : 203
14.7 Special precautions in connection with : None
transport
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be complied
with:
each package shall display a diamond-shaped figure with the following
inscription:
- 'UN 1950'
or, in the case of different goods with different identification numbers within
a single package:
- the letters 'LQ'
Printing date : 10-2004 8/11
SOUDAFOAM FR
15. Regulatory information
Labelling in accordance with directives 67/548/EEC and 1999/45/EC
Extremely flammable Harmful
Contains : polymethylene polyphenyl isocyanate
R20 : Harmful by inhalation
R36/37/38 : Irritating to eyes, respiratory system and skin
R42/43 : May cause sensitization by inhalation and skin contact
S23 : Do not breathe spray
S36/37/39 : Wear suitable protective clothing gloves, and eye/face
protection
S38 : In case of insufficient ventilation, wear respiratory equipment
S45 : In case of accident or if you feel unwell, seek medical advice
(show the label where possible)
Contains isocyanates. See information supplied by the
manufacturer.
Keep away from sources of ignition - No smoking.
Keep out of reach of children.
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50癈.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material
Printing date : 10-2004 9/11
SOUDAFOAM FR
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered
as a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other material or in
any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA 2004
OES : Occupational Exposure Standards - United Kingdom 2003
MEL : Maximum Exposure Limits - United Kingdom 2003
MAK : Maximale Arbeitsplatzkonzentrationen - Germany 2002
TRK : Technische Richtkonzentrationen - Germany 2002
MAC : Maximale aanvaarde concentratie - The Netherlands 2004
VME : Valeurs limites de Moyenne d'Exposition - France 1999
VLE : Valeurs Limites d'Exposition ?court terme - France 1999
GWBB: Grenswaarde beroepsmatige blootstelling - Belgium 2002
GWK : Grenswaarde kortstondige blootstelling - Belgium 2002
EC : Indicative occupational exposure limit values - Directive 2000/39/EC
I : Inhalable fraction = T : Total dust = E : Einatembarer Aerosolanteil
R : Respirable fraction = A : Alveoleng鋘giger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/謑nebel (oil mist)
p: poussi鑢e (dust) part: particles
Chronic toxicity:
K: List of the carcinogenic substances and processes - The Netherlands 2004
Full text of any R-phrases referred to under heading 2:
R12 : Extremely flammable
R20 : Harmful by inhalation
R22 : Harmful if swallowed
R36 : Irritant to the eyes
R36/37/38 : Irritating to eyes, respiratory system and skin
R42/43 : May cause sensitization by inhalation and skin contact
R52/53 : Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic
environment
Printing date : 10-2004 10/11
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