Material Safety Data Sheet
(according to ?6 GefStoffV and Directive 91/155/EEC)
Article number: 53801
fischer 2K-Schnellschaum PU 2/402
st th
Prepared on: Reviewed on: Printing date:
02/21 /2003 12/20 /2005 10.01.2006
Version: Page:
1.3 1 of 5
1. Identification of the substance/preparation and company
1.1 Trade name: fischer 2K-Schnellschaum PU 2/402
1.2 Article number: 53081
1.3 Typical application: Fixing of door frames and installation of windows
1.4 Manufacturer/supplier: fischerwerke Artur Fischer GmbH & Co. KG
1.5 Address: D-72178 Waldachtal, Weinhalde 14 - 18
1.6 Contact: Mr. Werner Sch鋟ble
1.7 Telephone: 0049 7666/902-2965
1.8 Telefax: 0049 7666/902-2929
1.9 Emergency information: 0049 6132-84463 GBK Gefahrgut B黵o GMBH Ingelheim
2. Composition/information on ingredients
2.1 Chemical characterization: Urethaneprepolymer with liquefied propellants, non flammable, flammable and
under pressure
2.2 Dangerous components:
CAS ?No. EWG-No. Material Content [%] Symbol R-Phrases
20, 36/37/38,
101-68-8 202-966-0 Diphenylmethane-4,4`-diisocyanate 5,0 ?10 Xn
42/43
13674-84-5 237-158-7 tris(2-chloroisopropyl)phosphate 15 ?20 Xn 22, 52, 53
106-97-8 203-448-7 butane; pure 2,5 ?10 F+ 12
115-10-6 204-065-8 dimethyl ether 2,5 ?10 F+ 12
3. Hazards identification
3.1 Hazard description:
F+ Extremely flammable
Xn Harmful
3.2 Information pertaining to particular dangers for man and environment:
R 42/43 May cause sensitisation by inhalation and skin contact.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Additional information: Danger of bursting by heating. Increasing inside pressure.Do not activate container
at temperatures above 25 ?If necessary cool with water.
C.
The classification is in line with current EC lists. If is expanded, however, by information from technical literature and by
information furnished by supplier companies.
4. First aid measures
4.1 General information:
4.2 After inhalation: Supply fresh air; consult doctor in case of symptoms.
4.3 After skin contact: Instantly wash with water and soap and rise thoroughly.
4.4 After eye contact: Rinse opened eye for several minutes under running water. Then consult doctor.
4.5 After swallowing: Do not induce vomiting, instantly call for medical help.
4.6 Indications for the doctor: Danger: Irritant effects by pasting.
5. Fire-fighting measures
5.1 Suitable extinguishing media: CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-
resistant foam.
Alterations are marked: #
n.s. = not subject n.a. = not applicable
?by fischer 2001
Components of chemical sets are signed with A, B, .... .
Material Safety Data Sheet
(according to ?6 GefStoffV and Directive 91/155/EEC)
Article number: 53801
fischer 2K-Schnellschaum PU 2/402
st th
Prepared on: Reviewed on: Printing date:
02/21 /2003 12/20 /2005 10.01.2006
Version: Page:
1.3 2 of 5
5.2 For safety reasons unsuitable Water with a full water jet.
extinguishing media:
5.3 Special exposure hazards Can be released in case of fire.:
arising from the substance or Hydrogen fluoride ( HF )
preparation itself, combustion Hydrogen chloride ( HCl )
products, resulting gases:
5.4 Special protective equipment Do not inhale explosion gases on combustion gases.
for fire fighting:
5.5 Other information: Cool endangered container with water spay jet.
6. Accidental release measures
6.1 Person-related safety Wear protective clothing. Ensure adequate ventilation.
precautions:
6.2 Measures for environmental No special measures required.
protection:
6.3 Measures for Allow to solidify. Collect mechanically.
cleaning/absorption:
6.4 Other information: None.
7. Handling and storage
7.1 Handling:
7.1.1 Information for safe handling: Ensure good ventilation/ exhaustion at workplace. Keep away from heat and direct
sunlight. Ensure good interior ventilation, especially at floor level ( fumes are
heavier than air.
Attention: Do not activate the system at container temperatures above 25 ?If C.
necessary cool with water. After activation at container temperature of 25 ?the
C
content must be used completely during 3 minutes.
7.1.2 Information about protection Keep ignition sources away ?Do not smoke. Protect from heat.
against explosions and fires:
7.2 Storage:
7.2.1 Requirements to be met by Observe official regulations on storing packaging with pressurised containers.
storerooms and receptables:
7.2.2 Rules for the mixed storage of Observe recommendation of VCI.
chemicals:
7.2.3 Further information about Protect from heat and direct sunlight.
storage conditions: Best storage temperature: 18 ?22 ?C.
7.2.4 Storage class: 2 B (VCI)
8. Exposure controls and personal protection
8.1 Additional information about design of technical systems:
No further data; see item 7.
8.2 Components with limit values that require monitoring at the workplace:
CAS ?No. Material Content Type mg/m? ppm Fibre/m?br>
[%] (F/G)
101-68-8 diphenylmethane ?4,4`- 5 ?10 TVL 0,05 0,005 ---
diisocyanate
Alterations are marked: #
n.s. = not subject n.a. = not applicable
?by fischer 2001
Components of chemical sets are signed with A, B, .... .
Material Safety Data Sheet
(according to ?6 GefStoffV and Directive 91/155/EEC)
Article number: 53801
fischer 2K-Schnellschaum PU 2/402
st th
Prepared on: Reviewed on: Printing date:
02/21 /2003 12/20 /2005 10.01.2006
Version: Page:
1.3 3 of 5
115-10-6 dimethyl ether 2,5 ?10 TVL 1910 1000 ---
106-97-8 butane, pure 2,5 - 10 TVL 2350 1000 ---
8.3 Additional information:
The list that were valid during the compilation were used as basis.
8.4 Personal protective equipment:
Respiratory protection: Breathing equipment: Not necessary if room is well-ventilated.
Hand protection: Protective gloves (material: butyl rubber).
Eye protection: Safety glasses.
Body protection: Protective work clothing.
General protective and Avoid contact with the skin.
hygienic measures: The usual precautionary measures should be adhered to in handling the
chemicals.
9. Physical and chemical properties
9.1 Appearance:
Form: Aerosol
Colour: Light blue
Odour: Weak
9.2 Safety parameters:
Method:
Change in condition:
Boiling point/boiling range: Not applicable as aerosol
Melting point/melting range: Not applicable as aerosol
Flash point: Not applicable as aerosol
Ignition temperature: Propellant > 230 癈
Self igniting: Product is not selfigniting
Danger of explosion: Product is not explosive, however, formation of explosive air/steam mixture is
possible.
Explosion limits:
LEL: 1,5 Vol. - %
Applicable for the propellant
UEL: 18,6 Vol. - %
Vapour pressure: at 20 癈 5,5 ?6 bar
Density: at 20 癈 N.d.
Solubility:
Water: at ... 癈 Not miscible or difficult to mix
9.3 Further information: Decomposition temperature: The cured foam may decompose at temperature
above 100 ?At temperature above 300 ?self-ignition is possible
C. C
10. Stability and reactivity
10.1 Conditions to be avoided: No decomposition if used an stored according to specifications.
10.2 Materials to be avoided: No data.
Alterations are marked: #
n.s. = not subject n.a. = not applicable
?by fischer 2001
Components of chemical sets are signed with A, B, .... .
Material Safety Data Sheet
(according to ?6 GefStoffV and Directive 91/155/EEC)
Article number: 53801
fischer 2K-Schnellschaum PU 2/402
st th
Prepared on: Reviewed on: Printing date:
02/21 /2003 12/20 /2005 10.01.2006
Version: Page:
1.3 4 of 5
10.3 Hazardous decomposition No dangerous decomposition products known ( at combustion )
products:
10.4 Further information: Increasing inside pressure due warming up. Danger of bursting by overheating.
If the system is activated at container temperatures above 25 ?and the content is
C
not used during 3 minutes after activation, the pressure inside is increasing.
Danger of bursting.
11. Toxicological information
11.1 Acute toxicity: LD50/LC50 values which are relevant for classification: No data.
11.2 Specific symptoms in animal No data.
studies:
11.3 Irritant effects: On the skin: Irritant for skin when pasting.
On the eye: Irritant effect: danger of pasting.
11.4 Sensitization: Sensitisation possible by inhalation.
Not applicable for the cured foam.
12. Ecological information
12.1 Information on elimination: (Persistence and degradability): The cured foam is not biodegradable.
12.2 Behaviour in environmental No data available.
compartiments:
12.3 Ecotoxicological effects: No data available.
13. Disposal consideration
13.1 Product:
13.1.1 Recommendation: Must not be disposed of together with household garbage. Contact waste
processors for recycling information.
13.2 Contaminated packaging:
13.2.1 Recommendation: Disposal must be made according to official regulations.
In Germany: recycling by PDR
13.2.2 Recommended cleaning agent: fischer Polyurethane Cleaner PUR
14. Transport information
14.1 Land transport ADR/RID/GGVS/GGVE:
Classification: UN - No.:
2 1950
Description of goods: Aersols
Remarks: ADR, limited quantities
14.2 Inland navigation ADN/ADNR:
14.3 Transport by sea IMDG/GGVSea:
14.4 Air transport ICAO/IATA:
# 14.5 Transport/further Please contact Mr. Elmar M黮ler; telephone: ++49 7443/12-4896
information mobile: ++49 151 ?18504887
Alterations are marked: #
n.s. = not subject n.a. = not applicable
?by fischer 2001
Components of chemical sets are signed with A, B, .... .
Material Safety Data Sheet
(according to ?6 GefStoffV and Directive 91/155/EEC)
Article number: 53801
fischer 2K-Schnellschaum PU 2/402
st th
Prepared on: Reviewed on: Printing date:
02/21 /2003 12/20 /2005 10.01.2006
Version: Page:
1.3 5 of 5
15. Regulations
15.1 Labelling according to EC Directives/Gefahrstoffverordnung:
15.1.1 Symbol(s) and indication(s) of danger:
F+ - Extremely flammable
Xn - Harmful
15.1.2 Hazard-determing component(s) for labelling:
Contains: Highly flammable propellants, Diphenylmethane ?,4`-diisocyanate
15.1.3 R-Phrases:
R 42/43 May cause sensitisation by inhalation and skin contact.
R 36/37/38 Irritating for eyes, respiratory system and skin.
15.1.4 S-Phrases:
S2 Keep out of the reach of children.
S 23 Do not breathe gas/fumes/vapour/spray
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately with plenty of water and soap.
S 45 In case of accident or you feel unwell, seek medical advice immediately
S 37 Wear suitable gloves.
S 39 Wear protective goggles.
15.1.5 Special designations for certain preparations:
Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50 ?Do not pierce or burn,
C.
even after use. Do not spray into a naked flame or any incandescent object. Keep away from sources of ignition ?no
smoking. Without adequate ventilation formation of explosives mixtures may occur. Contains Isocyanates. Observe
manufacture`s instructions.
Name, address, an tel.-no. of supplier or distributor.
16. Other information
16.1 Further information:
The above information describes exclusively the safety requirements of the product(s) and is based on our present
knowlegde. It does not represent a guarantee for the properties of the product(s) described in terms of the legal
warranty regulations. Properties of the product are to be found in the repective product leaflet. This data sheet has
been created on basis of the information given by the departments, which are responsible for this product.
16.2 Department issuing MSDS: Department T-C (Environment and Safety)
fischer Group of companies, location Denzlingen
16.3 Contact: Mr. Werner Sch鋟ble; see chapter 1
16.4 Full text of the R-Phrases in chapter 2: R 20 Harmful by inhalation.
R 22 Harmful if swallowed.
R 36/37/38 Irritating for eyes, respiratory system and skin.
R 42/43 May cause sensitisation by inhalation and skin contact.
R 53 May cause long term adverse effects in the aquatic environment.
16.5 Alterations have been made in chapter: 14
Alterations are marked: #
n.s. = not subject n.a. = not applicable
?by fischer 2001
Components of chemical sets are signed with A, B, .... .
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