Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 04.11.2005 Reviewed on 04.11.2005
* 1 Identification of substance:
?Product details:
?Trade name: CF 125-5W50; CF 125-50; CF 126N
?Application of the substance / the preparation Construction chemicals
?Manufacturer/Supplier:
Hilti AG
Feldkircherstr. 100
Postfach 333
FL-9494 Schaan Liechtenstein
Tel: +423 234 2111
Fax: +423 234 2965
?Informing department: see section 16
?Emergency information:
Tel.: 00423 / 234 - 2111
Fax.: 00423 / 234 - 2965
Schweizerisches Toxikologisches Informationszentrum - 24 h Service
Tel.: 0041 / 1 251 51 51 (international)
2 Composition/Data on components:
?Chemical characterization
?Description: Urethane prepolymer with propellant liquified under pressure, containing no CFC
?Dangerous components:
CAS: 13674-84-5 Tris(1-chloro-2-propyl)phosphate Xn; R 22 10-25%
EINECS: 237-158-7
CAS: 101-68-8 diphenylmethane-4,4'-di-isocyanante Xn; R 20-36/37/38-42/43 2,5-10%
EINECS: 202-966-0
CAS: 115-10-6 dimethyl ether F+; R 12 2,5-10%
EINECS: 204-065-8
CAS: 106-97-8 butane, pure F+; R 12 2,5-10%
EINECS: 203-448-7
?Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
?Hazard designation:
Xn Harmful
F+ Extremely flammable
?Information pertaining to particular dangers for man and environment
R 12 Extremely flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitisation by inhalation and skin contact.
Contains isocyanates. See information supplied by the manufacturer
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Keep out of the reach of children
?Classification system
The classification is in line with current EC lists. It has been expanded, however, by information from technical literature, by information furnished
by suppliers and by national regulations which have to be observed in chapter 15.
4 First aid measures
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact
Treat affected skin portions with cotton wool or cellulose. Then wash and rinse thoroughly with water and a mild cleaning agent.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing Do not induce vomiting; instantly call for medical help.
?Information for doctor
?The following symptoms may occur: Allergic reactions
5 Fire fighting measures
?Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
Can be released in case of fire
Carbon monoxide (CO)
Hydrogen chloride (HCl)
(Contd. on page 2)
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Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 04.11.2005 Reviewed on 04.11.2005
Trade name: CF 125-5W50; CF 125-50; CF 126N
(Contd. of page 1)
Hydrogen fluoride (HF)
Hydrogen cyanide (HCN)
?Protective equipment: Wear self-contained breathing apparatus.
?Additional information Cool endangered containers with water spray jet.
6 Accidental release measures
?Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
?Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
?Measures for cleaning/collecting:
Allow to solidify. Collect mechanically.
Dispose of contaminated material as waste according to item 13.
7 Handling and storage
?Handling
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Keep away from heat and direct sunlight.
Danger of bursting!
?Information about protection against explosions and fires:
Beware: Container is pressurized. Keep away from direct sun exposure and temperatures over 50癈. Do not open by force or throw into fire even
after use.
Do not spray on flames or red-hot objects.
Keep ignition sources away - Do not smoke.
?Storage
?Requirements to be met by storerooms and containers:
Keep containers securely closed and dry, store at 5 - 25癈.
Observe official regulations on storing packagings with pressurized containers.
?Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from flammable substances.
?Further information about storage conditions: Protect from heat and direct sunlight.
?Storage class As per VCI (1991) storage classification concept.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
115-10-6 dimethyl ether (2,5-10%)
TLV (European Union) 1920 mg/m? 1000 ppm
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Do not eat, drink or smoke while working.
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
?Breathing equipment: Use breathing protection in case of insufficient ventilation.
?Protection of hands: Protective gloves.
?Material of gloves Synthetic gloves
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Tightly sealed safety glasses.
?Body protection: Protective work clothing.
9 Physical and chemical properties:
?General Information
Container under gas pressure
Form:
Light yellow
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not applicable
(Contd. on page 3)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 04.11.2005 Reviewed on 04.11.2005
Trade name: CF 125-5W50; CF 125-50; CF 126N
(Contd. of page 2)
?Flash point: Not applicable, as aerosol
?Ignition temperature: 230癈
?Decomposition temperature: 100癈
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: In use, may form flammable/explosive vapour-air mixture.
?Critical values for explosion:
1,5 Vol %
Lower:
18,6 Vol %
Upper:
?Vapour pressure at 20癈: 5,5-6 bar
?Density at 20癈 0,9-1,1 g/cm3
?Solubility in / Miscibility with
Unsoluble
Water:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions
Reacts with alcohols, amines, aqueous acids and alkalis
With water (moisture): CO2 is produced; pressure may build up inside closed containers (danger of bursting)
?Dangerous products of decomposition: none, if stored and handled correctly.
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
13674-84-5 Tris(1-chloro-2-propyl)phosphate
Oral LD50 3600 mg/kg (ratte)
106-97-8 butane, pure
Inhalative LC50/4 h 658 mg/l (ratte)
115-10-6 dimethyl ether
Inhalative LC50/4 h 308 mg/l (ratte)
9016-87-9 diphenylmethanediisocyanate,isomeres and homologues
Oral LD50 >5000 mg/kg (ratte)
Inhalative LC50/4 h 0,49 mg/l (ratte)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization:
Sensitization possible by inhalation.
Sensitization possible by skin contact.
Hypersensitve persons may react at very low concentrations of isocyanate.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as
issued in the latest version:
Harmful
12 Ecological information:
?General notes:
The product reacts with water releasing CO2, to form a solid, insoluble polycarbamide with a high melting point which, according to present
knowledge, is inert and not degradeable.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
13 Disposal considerations
?Product:
?Recommendation For disposal, local regulations issued by the authorities must be observed.
?European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES
AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS
08 05 00 wastes not otherwise specified in 08
08 05 01 waste isocyanates
(Contd. on page 4)
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Page 4/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 04.11.2005 Reviewed on 04.11.2005
Trade name: CF 125-5W50; CF 125-50; CF 126N
(Contd. of page 3)
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: 2 Gases.
?UN-Number: 1950
?Designation of goods: Pressurised container
1950 AEROSOLS
?Remarks: Limited quantity: LQ 2
?Maritime transport IMDG:
?IMDG Class: 2.1
?UN Number: 1950
?Packaging group: II
?EMS Number: F-D,S-U
?Marine pollutant: No
?Correct technical name: AEROSOLS
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 2.1
?UN/ID Number: 1950
?Correct technical name: AEROSOLS
?Transport/Additional information: Limited quantity: LQ 2
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
?Code letter and hazard designation of product:
Xn Harmful
F+ Extremely flammable
?Hazard-determining components of labelling:
diphenylmethane-4,4'-di-isocyanante
?Risk phrases:
12 Extremely flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
42/43 May cause sensitisation by inhalation and skin contact.
?Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe aerosol.
25 Avoid contact with eyes.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
51 Use only in well-ventilated areas.
?Special designation of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Keep out of the reach of children
?National regulations
?Technical instructions (air):
Class Share in %
I 2,5-10
NK 10-25
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
Changes made since last issue dated 23-10-2004 at the following points: *
(Contd. on page 5)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 04.11.2005 Reviewed on 04.11.2005
Trade name: CF 125-5W50; CF 125-50; CF 126N
(Contd. of page 4)
?Relevent R-phrases
12 Extremely flammable.
20 Harmful by inhalation.
22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
42/43 May cause sensitisation by inhalation and skin contact.
?Department issuing data specification sheet:
Hilti Corp.
BU Chemicals
Quality/Safety/Environment
Hilti Entwicklungsgesellschaft mbH
Hiltistrasse 26
D-86916 Kaufering
Tel: +49 8191 90 6494
Fax: +49 8191 90 17 6494
?Contact: Michael Kaindl
?* Data compared to the previous version altered.
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