MATERIAL SAFETY DATA SHEET
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SECTION I - PRODUCT IDENTIFICATION
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CBOB Gasoline (No ethanol)
Product Name: LEGEND Health * 1
HMIS/NFPA
Fuel
Product Use:
Severe 4 Flammability 4
Class B - Division 2 - Flammable Liquid, Class D -
WHMIS Class: Serious 3
Physical Hazard
Division 2A, 2B 0
Moderate 2
Slight 1
Gasoline; Class 3; UN1203; PGII
DOT Classification: Personal Protection
B
Minimal 0
GASOLINE; Class 3; UN1203; PGII
TDG Classification:
Irving Oil Refining G.P.
Manufacturer/Supplier: 4
Box 1260
0
1
Saint John, NB E2L 4H6 CA
Phone: (506) 202-2000
Refinery: (506) 202-3000
Emergency Phone: 1-800-424-9300 (CHEMTREC)
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SECTION II - HAZARDOUS INGREDIENTS
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Ingredient(s) CAS # Wt% OSHA PELS ACGIH-TLV LC50 Oral LD50
Gasoline 8006-61-9 60 - 100 Not established Not established Not available 13600 mg/kg rat
Toluene 108-88-3 5 - 10 200 ppm - TWA; 300 20 ppm - TWA; ; 50 12.5 mg/l/4h rat 636 mg/kg rat
ppm - CEIL ppm - MIST
Xylene 1330-20-7 5 - 10 100 ppm - TWA 100 ppm - TWA; 6350 mg/l/4h rat 4300 mg/kg rat
150 ppm - STEL
N-Hexane 110-54-3 1-5 500 ppm - TWA 50 ppm - TWA; 38500 mg/l/4h rat 28710 mg/kg rat
1000 ppm - STEL
Benzene 71-43-2 0.1 - 1 1 ppm - TWA; 5 ppm 0.5 ppm - TWA; 2.5 13050 ppm rat; 690 mg/kg rat; 4700
- STEL; 25 ppm - ppm - STEL 13700 mg/l/4h rat mg/kg mouse
CEIL
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*Contains a variety of aromatic and aliphatic hydrocarbons including: benzene, n-hexane, toluene and xylene
Gasoline is a complex mixture of hydrocarbons. Its exact composition depends on the source of the crude oil from which it was
produced and the refining methods used. Gasoline contains hundreds of individual organic chemicals. This section identifies only
some of the well-known chemical constituents.
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SECTION III - PHYSICAL DATA
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27 - 220 癈 (80.60 - 428.00 癋) 0.73 - 0.75 @ 15癈
Boiling Point: Specific Gravity:
< -80 癈 (< -112.00 癋) Not available
Freezing Point: Coefficient of Water/Oil
Distribution:
150 - 500 mmHg @ 20癈
Vapor Pressure:
Not available
% Volatile:
2.5 - 4 (air = 1)
Vapor Density:
4 (butyl acetate = 1)
Evaporation Rate:
Not available
Solubility in Water:
Not applicable
pH:
Liquid
Physical State:
Not available
Viscosity:
Clear Liquid
Appearance:
~ 0.1 ppm
Odor Threshold:
Characteristic Gasoline
Odor:
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SECTION IV - FIRE AND EXPLOSION DATA
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Flammable by WHMIS/OSHA criteria.
Flammability:
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-43 癈 (-45.40 癋) LEL: 1.4 % (Typical) UEL: 7.6 % (Typical)
Flash Point (Closed Cup):
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May include and are not limited to: Oxides of carbon. Oxides of nitrogen.
Hazardous Combustion Products:
Aromatic and aliphatic hydrocarbons
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257 癈 (494.60 癋) (Typical)
Autoignition Temperature:
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Explosion Data:
Sensitivity to Mechanical Impact: Not expected to be sensitive to mechanical impact.
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Vapor: Yes.
Sensitivity to Static Discharge:
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Carbon dioxide. Dry chemical. Foam.
Means of Extinction:
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Firefighters should wear a self-contained breathing apparatus.
Special Fire Hazards:
Container may explode in heat of fire.
Vapors are heavier than air and may travel along the ground to some distant
source of ignition and flash back.
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SECTION V - REACTIVITY DATA
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Conditions for Chemical Instability: Stable under recommended storage conditions.
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Acids. Oxidizers.
Incompatible Materials:
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Heat, open flames, static discharge, sparks and other ignition sources. Do not mix with
Reactivity, and Under What
other chemicals.
Conditions:
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May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Aromatic
Hazardous Decomposition
hydrocarbons.
Products:
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SECTION VI - TOXICOLOGICAL PROPERTIES
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Eye, Skin contact, Skin absorption, Inhalation, Ingestion.
Route of Entry:
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EFFECTS OF ACUTE EXPOSURE:
Causes irritation.
Eye:
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Causes irritation.
Skin:
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation:
nervous system effects (headache, dizziness). Aspiration of material into lungs can
cause chemical pneumonitis.
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Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Ingestion:
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EFFECTS OF CHRONIC EXPOSURE:
Peripheral nerve damage has been observed following occupational exposure to hexane. Prolonged or repeated
overexposure can cause liver and kidney damage.
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Prolonged or repeated exposure can cause drying, defatting and dermatitis.
Skin:
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Skin, eyes, respiratory tract. Very serious irritant if trapped against skin.
Irritancy:
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Respiratory Tract Sensitization: Non-hazardous by WHMIS/OSHA criteria.
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Contains potential carcinogens.
Carcinogenicity:
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Contains potential teratogens. Toluene (benzene, methyl-) has caused fetotoxicity
Teratogenicity:
(reduced fetal weight), behavioural effects (effects on learning and memory) and hearing
loss (in males). These effects have been observed in the offspring of rats exposed by
inhalation to 1200 or 1800 ppm toluene. These effects were observed in the absence of
maternal toxicity.
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Non-hazardous by WHMIS/OSHA criteria.
Mutagenicity:
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Non-hazardous by WHMIS/OSHA criteria.
Reproductive Effects:
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Not available
Synergistic Materials:
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SECTION VII - PREVENTATIVE MEASURES
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TychemTM. Gloves.
Gloves:
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Face shield or chemical goggles.
Eye Protection:
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For confined spaces, wear a NIOSH-approved (or equivalent) full-facepiece airline
Respiratory Protection:
respirator in the positive pressure mode with emergency escape provisions. Respirator
should be selected by and used under the direction of a trained health and safety
professional following requirements found in OSHA's respirator standard (29 CFR
1910.134) and ANSI's standard for respiratory protection (Z88.2).
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Use of protective coveralls and long sleeves is recommended.
Other Protective Equipment:
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Local exhaust recommended.
Engineering Controls:
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Keep unnecessary personnel away. Remove sources of ignition. Before attempting clean
Leak and Spill Procedure:
up, refer to hazard data given above. Small spills may be absorbed with non-reactive
absorbent and placed in suitable, covered, labelled containers. Prevent large spills from
entering sewers or waterways. Contact emergency services and supplier for advice.
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Review federal, provincial, and local government requirements prior to disposal.
Waste Disposal:
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Use good industrial hygiene practices in handling this material. When using do not eat
Handling Requirements:
or drink. Wash hands before breaks and immediately after handling the product.
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Keep out of reach of children. Do not store at temperatures above 120癋 (49癈). Store
Storage Requirements:
in a tightly closed container in a cool, dry, well ventilated and dark place away from
incompatible materials. Keep away from heat, open flames or other sources of ignition.
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SECTION VIII - FIRST AID
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Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain
Eye:
medical attention if irritation persists.
CBOB Gasoline (No ethanol)(3022)
19045 Page 2 of 3
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Flush with cool water. Wash with soap and water. Obtain medical attention if irritation
Skin:
persists.
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If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention.
Inhalation:
If breathing has stopped, trained personnel should administer CPR immediately.
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Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is
Ingestion:
convulsing. Obtain medical attention.
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SECTION IX - PREPARATION INFORMATION
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Effective Date: 15-Mar-2009
Expiry Date: 15-Mar-2012
Issue Date: 17-Apr-2009
Prepared By: Dell Tech Laboratories Ltd. (519) 858-5021
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Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of
product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users
of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made
and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this
document.
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