3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
Material Safety Data Sheet
Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 03/20/2003
Supercedes Date: 11/28/2001
Document Group: 10-2789-5
Product Use:
Specific Use: CONTACT ADHESIVE
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
NAPHTHA SOLVENT LIGHT 64741-84-0 15 - 25
POLYCHLOROPRENE 9010-98-4 10 - 20
N-HEXANE 110-54-3 10 - 20
ACETONE 67-64-1 10 - 20
METHYL ETHYL KETONE 78-93-3 7 - 13
MAGNESIUM RESINATE 68611-24-5 7 - 13
MIXED HEXANE ISOMERS Mixture 5 - 10
TOLUENE 108-88-3 3- 7
MIXED HEPTANES Mixture 1- 3
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: grey/green, strong petroleum odor.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Flammable liquid and
vapor. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive
harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
May be absorbed through skin and cause target organ effects.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and
decreased ability to concentrate.
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back
pain, increased protein in urine, and increased blood urea nitrogen (BUN).
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
Methyl ethyl ketone has been shown to potentiate the neurotoxic effects of n-hexane.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
-14 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
1 % volume
Flammable Limits - LEL
12.8 % volume
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive
pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective
covering for exposed areas of the head.
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may
travel long distances along the ground or floor to an ignition source and flash back. Not applicable. Flammable liquid and vapor.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Avoid contact with incompatible materials listed in the Reactivity Data
Section. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from
around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix
in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or
flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an
appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities. Seal the container.
Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
For industrial or professional use only. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all
windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without
adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite
matches, lighters, etc. Extinguish pilot lights and turn off stoves, ovens and other gas and electric appliances (space and water heaters,
furnaces, etc.), electric motors, and other sources of ignition during adhesive use and until all vapors are gone; i.e., until the odor of
vapors at the floor level has disappeared. Do not use electric light switches. Do not generate static sparks (such as by walking on
carpet, etc.). Use the same precautions in the work area and all connected areas. Be sure that any people in the area follow the
precautions. Attach a copy of the precautions to any other container to which this product may by transferred. Avoid prolonged
breathing of vapors. Avoid eye and skin contact. Keep container closed when not in use. If work area conditions prevent compliance
with any of the above precautions, do not use the product. Keep out of the reach of children. Not intended for consumer sale or use.
Follow OTHER PRECAUTIONARY INFORMATION below.
7.2 STORAGE
Keep container tightly closed. Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing
agents. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist,
vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece air-purifying respirator with organic vapor/acid gas cartridges and P95 particulate prefilters, Half
facepiece air-purifying respirator with organic vapor/acid gas cartridges and N95 particulate prefilters, Half facepiece air-purifying
respirator with organic vapor/acid gas cartridges and P100 particulate prefilters, Half facepiece or fullface air-purifying respirator
with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630
for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ACETONE ACGIH TWA 500 ppm
ACETONE ACGIH STEL 750 ppm
ACETONE OSHA TWA, 750 ppm
Vacated
ACETONE OSHA TWA 1000 ppm Table Z-1
ACETONE OSHA STEL, 1000 ppm
Vacated
N-HEXANE ACGIH TWA 50 ppm Skin Notation*
N-HEXANE OSHA TWA, 50 ppm Table Z-1A
Vacated
N-HEXANE OSHA TWA 500 ppm Table Z-1A
METHYL ETHYL KETONE ACGIH TWA 200 ppm
METHYL ETHYL KETONE ACGIH STEL 300 ppm
METHYL ETHYL KETONE OSHA TWA 200 ppm Table Z-1A
METHYL ETHYL KETONE OSHA STEL 300 ppm Table Z-1A
TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA, 100 ppm
Vacated
TOLUENE OSHA STEL, 150 ppm
Vacated
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous
membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
grey/green, strong petroleum odor.
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
-14 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
1 % volume
Flammable Limits - LEL
12.8 % volume
Flammable Limits - UEL
132 篎 [Details: CONDITIONS: acetone]
Boiling point
3 [Ref Std: AIR=1]
Vapor Density
180 mmHg [Details: CONDITIONS: @ 68F]
Vapor Pressure
.84 [Ref Std: WATER=1]
Specific Gravity
No Data Available
pH
No Data Available
Melting point
Slight (less than 10%)
Solubility in Water
>=2 [Ref Std: WATER=1]
Evaporation rate
Approximately 1.22 lb HAPS/lb solids [Test Method: Calculated]
Hazardous Air Pollutants
490 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
74 %
Percent volatile
587 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
200 - 1000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion
Ketones During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
Incinerate uncured product in a permitted hazardous waste incinerator.
As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.
Combustion products will include HCl. Facility must be capable of handling halogenated materials.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D035 (Methyl ethyl ketone)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-1357-2630-5, 62-1357-2631-3, 62-1357-5530-4, 62-1357-5535-3, 62-1357-6530-3, 62-1357-7530-2, 62-1357-8530-1, 62-
1357-8540-0, 62-1357-9530-0, 62-1357-9531-8, 62-1357-9532-6, 78-8990-0393-9
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
TOLUENE 108-88-3 3- 7
N-HEXANE 110-54-3 10 - 20
METHYL ETHYL KETONE 78-93-3 7 - 13
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
N-HEXANE 110-54-3 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
ACETONE 67-64-1 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
TOLUENE 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Grip(TM) High Performance Contact Adhesive 1357 03/20/2003
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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