_ MATERIAL SAFETY DATA SHEET
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1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Cav Grip
Synonyms: Solvent - based Adhesive
Manufacturer/Supplier Phone Numbers
Carlisle Coatings & Waterproofing Incorporated Medical Emergency:
900 Hensley Lane CHEMTREC (USA): (800) 424-9300
Wylie, TX 75098 CHEMTREC (International):
Internet Address: http://www.ccwcompanies.com/ MSDS Assistance: (972) 442-6545
Fax Number: (972) 442-0076 Fax On Demand: NA
Technical Assistance: (888) 229-
2199
Customer Service: (888) 229-0199
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SECTION 2 - HAZARDOUS INGREDIENTS/COMPOSITION INFORMATION
ALLOWABLE SARA VP
INGREDIENT % BY CAS NO. EXPOSURE LEVEL 313 mm Hg @
WGT PPM MG/CU.M. SKIN 20 DEG.C
CARBON DIOXIDE 124-38-9 TLV-TWA 5000
CO2 OSHA-PEL 5000
NITROGEN 7727-37-9 NONE ESTABLISHED
METHYL ACETATE 79-20-9 TLV-TWA 200/606
TLV-STEL 250/760
OSHA -PEL 200/610
OSHA -STEL 250/760
LFL 3.1 UFL 16.0
HEXANE 10 110-54-3 TLV-TWA 50/180 SKIN X 120
OSHA -PEL 500/1800
LFL 1.0 UFL 8.0
HEXANE ISOMERS HM2116 TLV-TWA 500/1800
TLV-STEL 1000/3600
METHYLCYCLOPENTANE 96-37-7 NONE ESTABLISHED
STYRENE, 1,3 BUTADIE 9003-55-8 NONE ESTABLISHED
NE POLYMER
LFL = LOWER FLAMMABILITY LIMIT PERCENT
UFL = UPPER FLAMMABILITY LIMIT PERCENT
SKIN = SKIN ABSORPTION MUST BE CONSIDERED AS A ROUTE OF EXPOSURE
C-CEILING= ALLOW. EXPOSURE LEVEL SHOULD NOT BE EXCEEDED FOR ANY TIME
PERIOD
MFR = MANUFACTURER RECOMMENDED EXPOSURE LIMIT
STEL = SHORT TERM EXPOSURE LIMIT
X-SARA 313 = CHEMICAL IS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313
OF TITLE III OF S.A.R.A. 40 CFR PART 372
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
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SECTION 3 - HAZARDS IDENTIFICATION
Ratings
Health 2 Flammability 4 Reactivity 0
EFFECTS OF SHORT TERM OVEREXPOSURE
SWALLOWING
Can cause gastrointestinal irritation, nausea, and vomiting. Aspiration of material into lung may cause
chemical pneumonitis which can be fatal.
INHALATION
May cause nose or throat irritation. High concentrations may cause acute central nervous system depression
characterized by headaches, dizziness, nausea and confusion.
EYE
May cause eye irritation.
SKIN
Skin contact with material exiting cylinder may cause frostbite. Eye and respiratory system contact will
cause irritation and possible thermal (cold frostbite) tissue damage.
May cause defatting and irritation of the skin.
EFFECTS OF REPEATED OVEREXPOSURE
Repeated overexposure to n-hexane may cause damage to the peripheral nervous system.
Exposure to Methyl Ethyl Ketone may enhance the neurotoxicity of n-Hexane and Methyl-n-Butyl Ketone.
This synergistic effect has resulted in peripheral neuropathy in humans. Reports have associated prolonged
and repeated occupational overexposure to solvents with permanent brain and nervous system damage.
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH.
None currently known
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SECTION 4 - FIRST-AID MEASURES
SWALLOWING
If swallowed do not induce vomiting. (Never give anything by mouth to an unconscious person). Call
Poison Control Center , Hospital Emergency Room, or Physician immediately.
INHALATION
Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep warm and quiet.
Get medical attention immediately.
EYE
Flush with large amounts of water, lifting upper and lower lids occasionally. Continue for at least 15
minutes. Get medical attention immediately.
SKIN
Remove contaminated clothing. Wash affected area with soap and water. Obtain medical attention if
irritation persists.
NOTES TO PHYSICIAN
Any treatment that might be required for overexposure should be directed at the control of symptoms and
the clinical conditions.
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SECTION 5 - FIRE-FIGHTING MEASURES
NFPA FLAMMABILITY CLASSIFICATION
FLASHPOINT -15 DEG.F, SFCC (-26 DEG.C,)
EXTINGUISHING MEDIA
Use NFPA Class B Fire extinguishers (carbon dioxide, all purpose dry chemical or alcohol foam) designed
to extinguish flammable liquid fires. Polymer foam is preferred for large fires.
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
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UNUSUAL FIRE AND EXPLOSION HAZARDS
During emergency conditions, overexposure to decomposition products may cause a health hazard.
Symptoms may not be immediately apparent. Obtain medical attention.
DANGER! EXTREMELY FLAMMABLE. VAPORS MAY CAUSE FLASH FIRE.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters should wear self-contained breathing apparatus. Water may be ineffective, but may be used to
cool exposed containers to prevent pressure build-up and possible auto-ignition or explosion when
exposed to extreme heat. If water is used, fog nozzles are preferable.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Refer to Section 8 and don respirators, eye, hand, and body protection appropriate for the size of the spill
and the exposures encountered. Keep spectators away. Eliminate all ignition sources (flames, hot
surfaces, and sources of electrical, static or frictional sparks). Dike and contain spill with inert material (e.g.
sand, earth). Transfer liquids to covered metal containers for recovery or disposal, or remove with inert
absorbent. Use only non-sparking tools. Place absorbent diking materials in covered metal containers for
disposal. Prevent contamination of sewers, streams, and groundwater with spilled material or used
absorbent.
WASTE DISPOSAL
Dispose in accordance with federal, state and local regulations.
RCRA CLASSIFICATION
This product, if discarded directly, would be classified a hazardous waste based on its ignitability
characteristic, i.e. has a flash point of 140 deg. F.(60 deg.C) or less. The proper RCRA classification would
be D001.
ENVIRONMENTAL HAZARDS
None known
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SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORA GE
DO NOT INCINERATE, PUNCTURE OR MISHANDLE CONTAINER VALVES OR HOSES. ALL
ATTACHMENTS MUST BE IN GOOD CONDITION AND PROPERLY DESIGNED FOR USE WITH
THIS CONTAINER.
Do not store above 115 deg.F (46 deg.C) store large quantities in compliance with OSHA 29CFR1910.106.
Exposure to direct sunlight or other sources of heat may cause container to rupture or explode.
OTHER PRECAUTIONS
If cylinder is returnable do not dispose. Read canister/cylinder label for additional information. Return via
authorized agent, ensuring the canister/cylinder is properly labeled with valve outlet, plugs or caps secured
and valve protection in place. Protect cylinders from physical damage. Non-returnable cylinders/canisters
must be disposed of in accordance with local, state and federal regulations. Store in cool dry, well
ventilated area. Do not puncture or incinerate. Do not spray near flame or hot surfaces.
Avoid breathing vapor or spray mist. Keep out of reach of children.
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SECTION 8 - EXPOSURE CONTROLS
RESPIRATORY PROTECTION
The absence of heat or aerosol generation reduces the likelihood of the need for respiratory protection.
Since conditions of use vary, it is the responsibility of each user of this product to evaluate potential
exposures within their facility. If such conditions indicate the need for respiratory protection, proper
selection depends upon many factors including duration and level of exposure and conditions of use. In
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
Cav Grip Page 3 of 6
general, e xposure to the substances listed in Section II of this MSDS may not require the use of respiratory
protection if exposures are maintained below recommended exposure limits. This can be accomplished by
the use of engineering controls. One example of such controls would be the use of properly designed
ventilation systems. If a respirator is to be worn, a NIOSH approved respirator with an appropriate
protection factor should be provided. If exposures are determined to be excessive, or if the use of
respirators is desired a positive pressure supplied air respirator will provide adequate protection. The use of
air purifying respirators may also be suitable in some situations. Please refer to the American Industrial
Hygiene Association Journal J. 47(7):393-398 (1986). Consult a qualified occupational health and safety
professional regarding conditions of use within your facility. Refer to OSHA 29 CFR 1910.134
"Respiratory Protection" and Respiratory Protection: A Manual And Guideline, American Industrial
Hygiene Association."
VENTILATION
Use general dilution and local exhaust ventilation in sufficient volume and pattern to keep concentrations of
hazardous ingredients listed in Section II below the lowest exposure limit stated. Fumes emitted while
baking this product must be properly vented. Refer to "Industrial Ventilation a Manual of Recommended
Practice"-ACGIH.
HAND PROTECTION
Solvent impermeable gloves are required for immediate or prolonged contact. Refer to glove
manufacturer's recommendations and specifications.
EYE PROTECTION
Wear chemical splash goggles (ANSI Z87.1 or equivalent) and face shield.
OTHER PROTECTIVE EQUIPMENT
Eyewash facility, safety shower.
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SECTION 9 - PHYS ICAL AND CHEMICAL PROPERTIES
BOILING RANGE: -109 DEG.F. ( -78 DEG.C.) TO 159 DEG.F.( 71 DEG.C.)
VAPOR DENSITY: Heavier than air. % VOLATILE BY VOLUME: 25
EVAPORATION RATE: Slower than Diethyl Ether
VOC: .51 lb/gal less water& NPRS* 61 g/l less water CALCULATED
WEIGHT LB./GAL.: 7.5 VOC .59 lb/gal solids 71 g/l solids CALCULATED
SPECIFIC GRAVITY: 0.9
All Physical data determined at 68 DEG. F. (20 DEG. C.) 760 mm Hg
?Negligibly Photochemically Reactive Materials
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SECTION 10 - STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid excessive heat (>115 F (46 C) and sources of ignition.
INCOMPATABILITY (MATERIALS TO AVOID)
oxidizers, reducers
HAZARDOUS DECOMPOSITION PRODUCTS
Burning, including when heated by welding or cutting, will produce smoke, carbon monoxide and carbon
dioxide, oxides of nitrogen, hydrogen cyanide, and various hydrocarbons
HAZARDOUS POLYMERIZATION
Will not occur
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
Cav Grip Page 4 of 6
CONDITIONS TO AVOID
None known
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SECTION 11 - TOXICOLOGICAL INFORMATION
No information available.
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SECTION 12 - ECOLOGICAL INFORMATION
No information available.
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SECTION 13 - DISPOSAL CONSIDERATIONS
See Section 6.
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SECTION 14 - TRANSPORT INFORMATION
MODE PROPER SHIPPING NAME CLASS I.D.# PKG GRP
IATA
MODE PROPER SHIPPING NAME CLASS I.D.# PKG GRP
(AIR) LIMITED TO SMALL QUANTITIES
ONLY CAN NOT BE SHIPPED IN
THIS CONFIGURATION
DOT (HM-181)
(DOMESTIC SURFACE) COMPRESSED GAS, FLAMMABLE, NOS 2.1 UN1954
(METHYL ACETATE, HEXANE)
NAERG: 115
IMDG CODE
(OCEAN) FORBIDDEN
NOTE! The assignment of Proper Shipping Names is in part a function of the size of the product container
and the transport mode. For example, the Proper Shipping Name for a bulk container can differ
significantly from the Proper Shipping Name for the same product packaged in a non-bulk container.
This can also be true for products shipped via different modes of transportation (i.e. ground, air, ocean).
The descriptions provided above are intended to provide some guidance. However, these descriptions may
not apply to your package size or mode of shipment. The U.S. Code of Federal Regulations, 49 CFR -
Transportation, regulations, and the policies established by some transporters, require that the shipper
properly classify and assign a Proper Shipping Name, and label, mark and package the material properly.
Therefore, the user of this information is cautioned to consult with applicable regulations and with qualified
advisors prior to the repackaging and or reshipment of this or other any product which contain this product.
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SECTION 15 - REGULATORY INFORMATION
All ingredients in this product are listed on the US TSCA Inventory.
INGREDIENT CAS NO. DETAIL INVENTORY LIST INFORMATION
CARBON DIOXIDE 124-38-9 DSL
CO2
NITROGEN 7727-37-9 DSL
METHYL ACETATE 79-20-9 TSCA(12b)
TSCA(4)
TSCA(8a PAIR)
TSCA(8d)
DSL
HEXANE 110-54-3 TSCA(12b)
TSCA(4)
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
Cav Grip Page 5 of 6
DSL
HEXANE ISOMERS HM2116 DSL
METHYLCYCLOPENTANE 96-37-7 TSCA(12b)
TSCA(4)
TSCA(8a PAIR)
TSCA(8d)
TSCA(8d term)
DSL
STYRENE, 1,3 BUTADIE 9003-55-8 DSL
NE POLYMER
DETAIL INVENTORY LIST DESCRIPTION
TSCA/Toxic Substances Control Act
DETAIL INVENTORY LIST DESCRIPTION
(12b)Notices of Export
(4)Test Rules
(8a PAIR)Preliminary Assessment Information Rules
(8d)Health and Safety Reporting Rules
(8d term)Health and Safety Reporting Rules termination
DSL/Canadian Domestic Substance List
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SECTION 16 - OTHER INFORMATION
DISCLAIMER: The data contained herein are furnished for information only and are believed to be
reliable. However, CCWI does not assume responsibility for any results obtained by persons over whose
methods CCWI has no control. It is the user's responsibility to determine the suitability of CCWI's products
or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may
be advisable for the protection of property and persons against any hazards that may be involved in the
handling and use of any of CCWI products. In light of the foregoing, CCWI specifically disclaims all
warranties, express or implied, including warranties of merchantability and fitness for a particular purpose,
arising from sale or use of CCWI products. CCWI further disclaims any liability for consequential or
incidental damages of any kind, including lost profits.
MSDS Revisions
Previous Version Date: 02/13/07
Section
Old Information:
New Information: 16- part MSDS version with updated Shipping Information
Prepared By: R&D Department Date: 11/11/08
Issued: 11/ 11/08
Supersedes: 07/ 01/ 08
Cav Grip Page 6 of 6
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