MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
TRADE NAME:
3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
ID NUMBER/U.P.C.:
62-4799-2631-3 00-21200-21354-0 62-4799-2635-4 - - -
62-4799-5530-4 - - - 62-4799-6530-3 00-21200-21357-1
62-4799-7530-2 00-21200-21358-8 62-4799-8530-1 00-21200-21359-5
62-4799-9530-0 00-21200-21360-1 62-4799-9531-8 - - -
XS-0414-1121-5 - - -
ISSUED: November 27, 2001
SUPERSEDES: May 24, 2001
DOCUMENT: 10-2754-9
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1. INGREDIENT C.A.S. NO. PERCENT
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PETROLEUM DISTILLATE.................... 64742-88-7 30.0 - 40.0
N-HEXANE................................ 110-54-3 10.0 - 20.0
TALC.................................... 14807-96-6 5.0 - 10.0
TOLUENE................................. 108-88-3 3.0 - 7.0
POLYISOPRENE............................ 9003-31-0 3.0 - 7.0
STYRENE-BUTADIENE POLYMER............... 9003-55-8 3.0 - 7.0
HYDROCARBON RESIN....................... 68478-07-9 3.0 - 7.0
ZINC RESINATE........................... 9010-69-9 3.0 - 7.0
MAGNESIUM RESINATE...................... 68611-24-5 1.0 - 5.0
ETHYL ALCOHOL........................... 64-17-5 0.1 - 1.0
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
This product is an article as defined by TSCA regulations, and is
exempt from TSCA Inventory listing requirements.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
N-HEXANE
TOLUENE
ZINC RESINATE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 2
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2. PHYSICAL DATA
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BOILING POINT:................. 140 F
(petroleum distillate)
VAPOR PRESSURE:................ 120 mmHg
@ 68F
VAPOR DENSITY:................. 3 Air=1
EVAPORATION RATE:.............. 2.50 Ether=1
SOLUBILITY IN WATER:........... slight
SPECIFIC GRAVITY:.............. 0.820 Water=1
PERCENT VOLATILE:.............. ca. 65 % by wt
pH:............................ N/D
VISCOSITY:..................... 7500 - 18000 centipoise
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
medium paste, black, mild odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... -14 F
FLAMMABLE LIMITS - LEL:........ 1 % by vol
FLAMMABLE LIMITS - UEL:........ 7 % by vol
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 3
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Oxidizing Agents.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Aldehydes, Ketones, Hydrocarbons,
Oxides of Zinc.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Cover with absorbent material. Collect using non-
sparking tools. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Dispose of waste product in a facility
permitted to accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 494 gms/liter calculated per SCAQMD rule
443.1.
VOC Less H2O & Exempt Solvents: 497 gms/liter calculated per SCAQMD rule
443.1.
Hazardous Air Pollutants: ca. 22 % by wt calculated.
Hazardous Air Pollutants: ca. .7 #/# solids calculated.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 4
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear vented goggles. Wear safety glasses with
side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: polyethylene/ethylene vinyl alcohol,
polytetrafluoroethylene (Teflon).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid prolonged breathing of vapors. Select one of the following
NIOSH approved respirators based on airborne concentration of
contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Keep container closed when not in use. Keep out of the reach of
children.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Flammable liquid and vapor. Keep
away from heat, sparks, open flame, and other sources of ignition.
Ground containers securely when transferring contents. Wear low
static or properly grounded shoes.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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PETROLEUM DISTILLATE................. 100 PPM TWA CMRG
N-HEXANE............................. 50 PPM TWA ACGIH Y
N-HEXANE............................. 50 PPM TWA OSHAV
OSHA VACATED PEL
N-HEXANE............................. 500 PPM TWA OSHA
TALC................................. 2 MG/M3 TWA OSHA
RESPIRABLE
TALC................................. 2 MG/M3 TWA ACGIH
RESPIRABLE
TALC................................. 0.5 MG/M3 TWA CMRG
AS RESPIRABLE DUST
TOLUENE.............................. 50 PPM TWA ACGIH Y
TOLUENE.............................. 100 PPM TWA OSHAV
OSHA VACATED PEL
TOLUENE.............................. 150 PPM STEL OSHAV
OSHA VACATED PEL
TOLUENE.............................. 200 PPM TWA OSHA
TOLUENE.............................. 300 PPM CEIL OSHA
TOLUENE.............................. 75 PPM STEL CMRG Y
POLYISOPRENE......................... NONE NONE NONE NONE
STYRENE-BUTADIENE POLYMER............ NONE NONE NONE NONE
HYDROCARBON RESIN.................... NONE NONE NONE NONE
ZINC RESINATE........................ NONE NONE NONE NONE
MAGNESIUM RESINATE................... NONE NONE NONE NONE
ETHYL ALCOHOL........................ 1000 PPM TWA ACGIH
ETHYL ALCOHOL........................ 1000 PPM TWA OSHA
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 6
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Peripheral Neuropathy: signs/symptoms can include tingling of
extremities, incoordination, numbness, weakness and tremors.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Ingestion may cause:
Central Nervous System Depression: signs/symptoms can include
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
MSDS: 3M(TM) Scotch-Grip(TM) Industrial Adhesive 4799
November 27, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
Aspiration Pneumonitis: signs/symptoms can include coughing,
difficulty breathing, wheezing, coughing up blood and pneumonia,
which can be fatal.
REPRODUCTIVE/DEVELOPMENTAL TOXINS:
WARNING: Contains a chemical which can cause birth defects. (108-88-
3)
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE May 24, 2001 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
Doc #: EX-85M057002 Issue Date: 05/24/01 Rev. Date: 11/27/01
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