MATERIAL SAFETY DATA SHEET
MSDS FORMAT MEETS ANSI Z400.1-1993 AND OSHA 1910.1200
SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT CODE P5107CT
PRODUCT NAME MR 374 PAINTABLE SILICONE RELEASE
MSDS REVISION NUMBER 2
DATE OF PREPARATION OR REVISION March 26, 2003
MANUFACTURER INFORMATION SUPPLIER INFORMATION
Plastic Moulding Supplies
24 Brunel Road
Corby
Northants
NN17 4JW
01536 403886
EMERGENCY:
Mfg. Part #: P5107CT Supplier Part #: MR374
SECTION 2 ?COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT, TECHNICAL DESCRIPTION CAS NUMBER OSHA PEL ACGIH TLV % WT
Liquefied Petroleum Gas 68476-85-7 1000 ppm 1000 ppm 60-70
Hexane 110-54-3 500 ppm 50 ppm 20-30
Alkyl Methyl Silicone Fluid Trade Secret N/E N/E
N/E = None Established
SECTION 3 ?HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CONTENTS EXTREMELY FLAMMABLE AND UNDER PRESSURE. STORE BELOW 120癋, OUT OF SUNLIGHT
AND AWAY FROM HEAT SOURCES. DO NOT PUNCTURE OR INCINERATE. AVOID CONTACT WITH SKIN
AND EYES. VAPOR HARMFUL. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
HMIS Ratings: Health-1 Fire-4 Reactivity-0 Protective Equipment-B
POTENTIAL HEALTH EFFECTS
EYE: Liquid or vapors may cause redness, burning, tearing, swelling and/or pain.
SKIN: Frequent or prolonged contact can result in defatting and drying of the skin which may result in skin irritation and
dermatitis (rash).
INGESTION: Due to being an aerosol, product does not lend itself to ingestion. Should ingestion occur, it may cause
irritation to membranes of the mouth, throat and gastrointestinal tract, resulting in vomiting and/or cramps.
MSDS P5107CT Rev. 2 chem-pak?INC. 26Mar03 - PAGE 1 of 4
MATERIAL SAFETY DATA SHEET
MSDS FORMAT MEETS ANSI Z400.1-1993 AND OSHA 1910.1200
INHALATION: Prolonged or repeated overexposure is anesthetic. May cause irritation of the respiratory tract, or acute
nervous system depression characterized by headache, dizziness, staggering gait, or confusion.
MEDICAL CONDITIONS AGGRAVATED: Skin contact may aggravate an existing dermatitis. Others unknown.
CARCINOGEN DATA: None of the ingredients in this product are listed with OSHA, IARC or NTP as carcinogenic.
SECTION 4 ?FIRST AID MEASURES
INGESTION: Unlikely due to being in aerosol form. Should actual ingestion occur, do not induce vomiting! Drink a glass of
water or milk to dilute. Call a physician or poison control center immediately. Never give anything by mouth to an
unconscious person.
EYE: Immediately flush with plenty of clear water for at least 15 minutes. Make sure to flush under the eyelids. Consult a
physician for definitive treatment.
SKIN: Remove with soap and water. Continue flushing with water for several minutes. Use skin cream to counter resulting
dryness. Consult a physician if irritation continues or if large skin area is affected.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek
medical attention if symptoms persist or if unconscious.
SECTION 5 ?FIRE FIGHTING MEASURES
FLASH POINT: Propellant < 0癋
FLAMMABLE LIMITS: LEL: 1.8% UEL: 9.5%
EXTINGUISHING MEDIA: For warehouse and storage conditions, use NFPA Class B extinguishers (CO2, dry chemical or
universal aqueous film forming foam).
SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool fire exposed aerosol containers for containers can
rupture violently from heat developed pressure.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Contents extremely flammable and under pressure. In addition, when
liquid or vapor comes into contact with flames or red hot metal, products of combustion will be created. Firemen
should wear self-contained breathing apparatus.
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
CONTAINMENT PROCEDURES: Product is an aerosol, therefore spills and leaks are unlikely. In case of rupture,
released content should be contained as any other solvent spill.
SPILL CLEANUP: Spills from aerosol cans are unlikely and are generally of small volume. Large spills are therefore not
normally considered a problem. In case of actual rupture, avoid breathing vapors and ventilate area well. Remove all
sources of ignition and use non-sparking equipment. Soak up material with inert absorbent and place in safety
containers for proper disposal.
SPECIAL INSTRUCTIONS: Aerosol products represent a limited hazard and will not spill or leak unless ruptured. In case
of rupture contents are generally evacuated from the can rapidly. Area should be ventilated immediately and
continuous ventilation provided until all fumes and vapors have been removed. Aerosol cans should never be
incinerated or burned. See Section 13 for disposal considerations.
REPORTING REQUIREMENTS: Spills due to the rupture of a single aerosol can are generally below any regulatory
reporting requirements. However, if larger spills somehow result, the reporting requirements of the EPA and other
local, state and federal agencies should be observed.
SECTION 7 ?HANDLING AND STORAGE
Avoid prolonged or repeated skin contact. Avoid breathing vapors. Store in area below 120癋. Do not incinerate (burn)
containers. Assure can is in a secure place to prevent knocking over and accidental rupture. Always replace overcap when
not in use. For storage of pallet quantities, compliance with ANSI/NFPA 30B is recommended.
MSDS P5107CT Rev. 2 chem-pak?INC. 26Mar03 - PAGE 2 of 4
MATERIAL SAFETY DATA SHEET
MSDS FORMAT MEETS ANSI Z400.1-1993 AND OSHA 1910.1200
SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION
SKIN PROTECTION: For brief contact, no precautions other than clean body-covering clothing should be needed. When
prolonged or repeated contact could occur, use protective clothing such as Sol-Vex?gloves or other clothing
impervious to the ingredients listed in section 2.
EYE PROTECTION: Safety glasses with side shields are recommended as a minimum for any type of industrial chemical
handling. Where eye contact could occur, chemical splash proof goggles are recommended.
RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory
protection is required an appropriate NIOSH approved respirator for organic vapor should be worn. If respirators are
needed, assure compliance with OSHA standard 29 CFR 1910.134.
ENGINEERING CONTROLS: General ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. Local exhaust ventilation or an enclosed handling system may be needed to control
air contamination below that of the lowest TLV/PEL rated ingredient from Section 2.
EXPOSURE GUIDELINE: Since this product is a mixture, an OSHA or ACGIH exposure value is not available. In
determination of any exposure procedures, protection or testing, use the lowest rated ingredient in Section 2.
SECTION 9 ?PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT ......................... : Propellant < 0癋
VAPOR PRESSURE .................... : No data
VAPOR DENSITY (Air=1) ............ : Above 1.0
WATER SOLUBILITY.................. : Negligible
SPECIFIC GRAVITY (H2O=1)....... : Below 1.0
PERCENT VOLATILE.................. : 97.0 % Wt Max
APPEARANCE AND ODOR.......... : Clear, colorless liquid with a hexane solvent odor
SECTION 10 ?STABILITY AND REACTIVITY
STABILITY................................. : Stable
HAZARD POLYMERIZATION ....... : Will not occur
CONDITIONS TO AVOID............. : Heat, sparks, flame, red hot metal
INCOMPATIBILITIES .................. : Strong oxidizing materials
DECOMPOSITION PRODUCTS ... : Oxides of carbon
SECTION 11 ?TOXICOLOGICAL INFORMATION
ACUTE ORAL LD50 .................... : Hexane >25 ml/kg (rat)
ACUTE DERMAL LD50................ : Hexane >6 ml/kg (rabbit)
ACUTE INHALATION LC50.......... : Liquefied Petroleum Gas 57.42% v/v (mice), Hexane 73680 ppm/6h (rat)
SECTION 12 ?ECOLOGICAL INFORMATION
This product has not been tested for environmental effects
SECTION 13 ?DISPOSAL CONSIDERATIONS
An aerosol container that does not contain a significant amount of liquid would meet the definition of scrap metal (40 CFR
261.1(c)(6)), and would be exempt from RCRA regulation under 40 CFR 261.6(a)(3)(iv) if it is to be recycled. If containers
are not recycled them must be managed under all applicable RCRA and state regulations.
MSDS P5107CT Rev. 2 chem-pak?INC. 26Mar03 - PAGE 3 of 4
MATERIAL SAFETY DATA SHEET
MSDS FORMAT MEETS ANSI Z400.1-1993 AND OSHA 1910.1200
SECTION 14 ?TRANSPORTATION INFORMATION
DOT HM -181 INFORMATION
Proper Shipping Name....... : Consumer Commodity
Hazard Class or Division ..... : ORM-D
Identification Number......... : none
Packaging Group................ : -
Label(s) Required............... : none
INTERNATIONAL TRANSPORTATION REGULATIONS
Proper Shipping Name....... : Consumer Commodity
Class or Division ................. : 9
Subsidiary Risk ................... : -
Hazard Label(s) .................. : Miscellaneous
Packaging Group................ : -
UN or ID Number................. : ID8000
SECTION 15 ?REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT: All of the ingredients in this product are on the TSCA inventory.
SARA TITLE III, SECTION 313: The following ingredients are subject to the reporting requirements of section 313 of Title
III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: None
CLEAN AIR ACT (CAA): The following ingredients appear on the List of Hazardous Air Pollutants (HAP - 42 USC 7412,
Title I, Part A, p112): Hexane
CLEAN WATER ACT (CWA): The following ingredients appear on the CWA List of Hazardous Substances (40 CFR 116.4):
None
CALIFORNIA PROPOSITION 65: The following ingredients appear on the Proposition 65 list(s): None
CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS): The following ingredients are
listed: LPG, Hexane
SECTION 16 ?OTHER INFORMATION
No other data available
DISCLAIMER: The information contained herein is based upon data provided to us by our suppliers, and reflects our best judgement. However, no warranty of merchantability, fitness for any use, or any otherwarranty
is expressed or implied regarding the accuracy of such data, or the results to be obtained from the use thereof. Since the information contained herein may be applied under conditions beyond our control and with which
we may be unfamiliar, we do not assume any responsibility for the results of such application. This information is furnished upon the condition that the persons receiving it shall make their own determination of the
suitability of the material for any particular purpose.
MSDS P5107CT Rev. 2 chem-pak?INC. 26Mar03 - PAGE 4 of 4
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