Silicone "S" (PIN # 01011) Page1 of 6
MATERIAL SAFETY DATA SHEET
G
MSDS FORMAT MEETS ANSI Z400.1 -1993 AND OSHA 1910.1200
SENTINEL'S
SILICONE "S"
REVISION# 1
MSDS # REVISION DATE: JANUARY 2, 2010
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Sentinel's Silicone "S"
PRODUCT NUMBER (S): 01011
SYNONYM: Sentinel's Silicone "S".
COMPANY IDENTIFICATION EMERGENCY TELEPHONE NUMBERS
Sentinel Lubricants Corp. HEALTH (24 hr) : (800) 842-6400 or (305) 625-6400
15755 N.W. 15th Ave. TRANSPORTATION (24 hr) : (800) 842-6400
Miami, FL 33169 or (305) 625-6400 Int'l collect calls accepted
PRODUCT INFORMATION: MSDS Requests: (800) 842-6400
Environmental, Safety, & Health Info: (800) 842-6400
Product Information: (800) 842-6400
2. 2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT, TECHNICAL DESCRIPTION CAS# OSHA PEL ACGIH TLV %WT
1. Hexane 110-54-3 500 ppm 50 ppm 50-60
2. Liquefied Petroleun Gas 68476-85-7 1000 ppm 1000 ppm 30-40
3. Dimethylpolysiloxane 63148-62-9 N/E N/E
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3. HAZARD IDENTIFICATION AND EMERGENCY AND FIRST AID PROCEDURES
EMERGENCY OVERVIEW
CONTENTS EXTREMELY FLAMMABLE AND UNDER PRESSURE. STORE BELOW 120癋, OUT OF SUNLIGHT AND
AWAY FROM HEAT SOURCES. DO NOT PUNCTURE OR INCINERATE. AVOID CONTACT WITH SKIN AND EYES.
VAPOR HARMFUL. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
MAY BE HARMFUL OR FATAL.
HMIS Ratings: Health-1 Fire-4 Reactivity-0 Protective Equipment-B
POTENTIAL HEALTH EFFECTS
EYE
Liquid or vapors may cause redness, burning, tearing, swelling and/or pain.
SKIN
Frequent or prolonged contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash).
INGESTION
Due to being an aerosol, product does not lend itself to ingestion. Should ingestion occur, it may cause irritation to membranes of the
mouth, throat and gastrointestinal tract, resulting in vomiting and/or cramps.
INHALATION
Prolonged or repeated overexposure is anesthetic. May cause irritation of the respiratory tract, or acute nervous system depression
characterized by headache, dizziness, staggering gait, or confusion.
MEDICAL CONDITIONS AGGRAVATED:
Skin contact may aggravate an existing dermatitis. Others unknown.
CARCINOGEN DATA
None of the ingredients in this product are listed with OSHA, IARC or NTP as being carcinogenic.
4. FIRST AID MEASURES
INGESTION
Unlikely due to being in aerosol form. Should actual ingestion occur, do not induce vomiting! Drink a glass of water or milk to dilute.
Call physician or poison control center immediately. Never give anything by mouth to an unconscious person.
EYE:
Immediately flush with plenty of clear water for at least 15 minutes. Make sure to flush under the eyelids. Consult a physician for
definitive treatment.
SKIN
Remove with soap and water. Continue flushing with water for several minutes. Use skin cream to counter resulting dryness. Consult
a physician if irritation continues or if large skin area is affected.
INHALATION
Remove to fre sh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention if
symptoms persist or if unconscious.
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5. FIRE FIGHTING MEASURES
FLASH POINT:
Propellant < 0癋
FLAMMABLE LIMITS:
LEL: 1.8% UEL: 9.5%
EXTINGUISHING MEDIA:
For warehouse and storage conditions, use NFPA Class B extinguishers (CO2, dry chemical or universal aqueous film forming foam).
SPECIAL FIRE FIGHTING PROCEDURES:
Use water spray to cool fire exposed aerosol containers for containers can rupture violently from heat developed pressure.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Contents extremely flammable and under pressure. In addition, when liquid or vapor comes into contact with flames or red hot metal,
products of combustion will be created. Firemen should wear self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
CONTAINMENT PROCEDURES:
Product is an aerosol, therefore spills and leaks are unlikely. In case of rup ture, released content should be contained as any other
solvent spill.
SPILL CLEANUP:
Spills from aerosol cans are unlikely and are generally of small volume. Large spills are therefore not normally considered a problem.
In case of actual rupture, avoi d breathing vapors and ventilate area well. Remove all sources of ignition and use non -sparking
equipment. Soak up material with inert absorbent and place in safety containers for proper disposal.
SPECIAL INSTRUCTIONS:
Aerosol products represent a limi ted hazard and will not spill or leak unless ruptured. In case of rupture contents are generally
evacuated from the can rapidly. Area should be ventilated immediately and continuous ventilation provided until all fumes and vapors
have been removed. Aerosol cans should never be incinerated or burned. See section 13 for disposal considerations.
REPORTING REQUIREMENTS:
Spills due to the rupture of a single aerosol can are generally below any regulatory reporting requirements. However, if larger spills
somehow result, the reporting requirements of the EPA and other local, state and federal agencies should be observed.
7. HANDLING AND STORAGE
Avoid prolonged or repeated skin contact. Avoid breathing vapors. Store in area below 120癋. Do not incinerate (burn) con tainers.
Assure can is in a secure place to prevent knocking over and accidental rupture. Always replace overcap when not in use. For storage
of pallet quantities, compliance with ANSI/NFPA 30B is recommended.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE GUIDELINE:
Since this product is a mixture, an OSHA or ACGIH exposure value is not available. In determination of any exposure procedures,
protection or testing, use the lowest rated ingredient in Section 2.
SKIN PROTECTION:
For brief contact, no precautions other than clean body-covering clothing should be needed. When prolonged or repeated contact could
occur, use protective clothing such as Sol-Vex gloves or other clothing impervious to the ingredients listed in section 2.
EYE PROTECTION:
Safety glasses with side shields are recommended as a minimum for any type of industrial chemical handling. Where eye contact could
occur, chemical splash proof goggles are recommended.
RESPIRATORY PROTECTION:
Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required an appropriate NIOSH
approved respirator for organic vapor should be worn. If respirators are needed, assure compliance with OSHA standard 29 CFR
1910.134.
ENGINEERING CONTROLS:
General ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Local
exhaust ventilation or an enclosed handling system may be needed to control air contamination below that of the lowest TLV/PEL rated
ingredient from Section 2.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT.....................: Propellant < 0癋
VAPOR PRESSURE.................. : No Data
VAPOR DENSITY (AIR = 1)...... : Above 1.0
WATER SOLUBILITY.............. : Negligible
SPECIFIC GRAVITY(H2O=1)...... : Below 1.0
PERCENT VOLATILE............... : 92.0% Wt Max
APPEARANCE AND ODOR....... : Straw colored liquid with a solvent-like odor
10. STABILITY AND REACTIVITY
STABILITY................................. : Stable.
HAZARDOUS POLYMERIZATION...: Will not occur.
CONDITIONS TO AVOID...............: Heat, sparks, flame, red hot metal
INCOMPATIBILITIES....................: Strong oxidizing materials
.
DECOMPOSITION PRODUCTS........: Oxides of Carbon
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11. TOXILOGICAL INFORMATION
ACUTE ORAL LD50...............: Hexane > 25 ml/kg (rat)
ACUTE DERMAL LD50.......... : Hexane > 5 ml/kg (rabbit)
ACUTE INHALATION LC50.....: LPG 57.42% v/v (mice), Hexane 73680 ppm/6h (rat)
12. ECOLOGICAL INFORMATION
This product has not been tested for environmental effects.
13. DISPOSAL CONSIDERATIONS
An aerosol container that does not contain a significant amount of liquid would meet the definition of scrap metal (40 CFR
261.1(c)(6)), and would be exempt from RCRA under 40CFR 261.6 (a)(3)(iv) if it is to be recycled. If containers not recycled they
are
must be managed under all applicable RCRA and state regulations.
1 14. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION
\
DOT HM-181 INFORMATION
Proper Shipping Name.... : Consumer Commodity
Hazard Class or Division.. : ORM-D
Identification Number......: none
Packaging Group............: -
Label(s) Required...........: none
INTERNATIONAL TRANSPORTATION REGULATIONS
Proper Shipping Name.....: Aerosols, Flammable NOS
Class or Division............: 2.1
Subsidiary Risk............. : -
Hazard Label(s).............: Flammable Gas
Packaging Group............ : -
UN or ID Number.......... : UN1950
NATIONAL MOTOR FREIGHT CLASSIFICATION
Item...........................: 50303
Article........................: Compounds, Lubricating
Class..........................: 55
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15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT:
All of the ingredients in this product are on the TSCA inventory.
SARA TITLE III, SECTION 313:
The following ingredients are subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372: None
CLEAN AIR ACT (CAA):
The following ingredients appear on the List of Hazardous Air Pollutants (HAP-42 USC 7412, Title I, Part A, p112): Hexane
CLEAN WATER ACT (CWA):
The following ingredients appear on the CWA List of Hazardous Substances (40 CFR 116.4): None
CALIFORNIA PROPOSITION 65:
The following ingredients appear on the Proposition 65 list(s): None
CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
The following ingredients are listed: LPG, Hexane
16. OTHER INFORMATION
HMIS RATINGS: Health 1; Flammability 4; Reactivity 0; PPE-B
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal
Protection Equipment Index recommendation, *- Chronic Effect Indicator).
These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection
Association (NFPA) or the National Paint and Coating Association (For HMIS ratings)
REVISION STATEMENT:
This is a new Material Safety Data Sheet.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity
RQ - Reportable Quantity PEL - Permissible Exposure Limit
C - Ceiling Limit CAS - Chemical Abstract Service Number
A1-5 - Appendix A Categories () - Change Has Been Proposed
NDA - No Data Available NA - Not Applicable
Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1)
The above information is based on the data of which we are aware and is believed to be correct as of data hereof. Since this
information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available
subsequent to the date. Hereof may suggest modification of the information, we do not assume any responsibility for the results of its
use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability
of the material for his particular purpose.
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