Material Safety Data Sheet
Revision Date: 09/29/2006 Issue date: 09/29/2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: FREKOTE AC4368 AE Item No. : 83490
Product type: Mold Release Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
n-Hexane 60-100 50 ppm TWA 1800 mg/m?TWA None
110-54-3 500 ppm TWA other than 500 ppm TWA
n-Hexane
1000 ppm STEL other
than n-Hexane
(skin)
Liquefied petroleum gas 10-30 1000 ppm TWA 1000 ppm TWA None
68476-85-7 1800 mg/m?TWA
Stoddard solvent 1-5 100 ppm TWA 2900 mg/m?TWA None
8052-41-3 500 ppm TWA
Xylene 0.1-1 100 ppm TWA 100 ppm TWA None
1330-20-7 150 ppm STEL 435 mg/m?TWA
Ethyl benzene 0.1-1 100 ppm TWA 100 ppm TWA None
100-41-4 125 ppm STEL 435 mg/m?TWA
Tetrakis(trimethylsiloxy)silane 0.1-1 None None None
3555-47-3
1,2,4-Trimethylbenzene 0.1-1 25 ppm TWA None None
95-63-6
Toluene 0-0.1 50 ppm TWA 200 ppm TWA None
108-88-3 (skin) 300 ppm Ceiling
Non hazardous components
Proprietary resin blend less than 5%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Aerosol HEALTH: 2
Color: Colorless FLAMMABILITY: 4
Odor: Slight, Solvent PHYSICAL HAZARD: 0
Personal Protection: See Section 8
DANGER: EXTREMELY FLAMMABLE LIQUID AND VAPOR
HARMFUL IF INHALED.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
Item No. : 83490 Product name: FREKOTE AC4368 AE
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Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects
Inhalation: Vapors and mists will irritate nose and throat and possibly eyes.
Skin contact: May cause skin irritation with discomfort or rash. Repeated or prolonged contact can result in drying of
skin.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: Harmful if swallowed.
Existing conditions aggravated by Other pre-existing skin conditions.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If discomfort persists seek medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical
attention.
Ingestion: Keep individual calm. Do not induce vomiting. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Flash point: Less than 21癈 (70癋)
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Use dry chemical, CO2, water spray or `alcohol` foam.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water
should be used to cool closed containers to prevent pressure build-up and possible autoignition or
explosion when exposed to extreme heat.
Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Acrid smoke and fumes.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Remove sources of ignition. Prevent further leakage or spillage if safe to do so. Do not allow material to
contaminate ground water system.
Clean-up methods: Spilled liquid is combustible and can be ignited by heat, flames, sparks, or other sources of ignition.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Store in a closed metal container until ready for disposal.
Item No. : 83490 Product name: FREKOTE AC4368 AE
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7. HANDLING AND STORAGE
Handling: Use only in area provided with appropriate exhaust ventilation. Keep away from heat, spark and flame.
Use only with adequate ventilation. Do not get in eyes. Do not get on skin or clothing.
Storage: Store away from heat, sparks, flames, or other sources of ignition. Keep in a cool, well ventilated area.
Store in original container until ready to use.
Incompatible products: Oxidizing and spontaneously flammable products.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Ensure adequate ventilation, especially in confined areas. Work should be done in an adequately
ventilated area (i.e., ventilation sufficient to maintain concentrations below one half of the PEL and
other relevant standards). Local exhaust ventilation is recommended when general ventilation is not
sufficient to control airborne contamination.
Respiratory protection: Use a NIOSH approved air purifying respirator with an organic vapor cartridge if the potential to exceed
established exposure limits exists. In case of mist, spray or aerosol exposure wear suitable personal
respiratory protection and protective suit.
Skin protection: Nitrile-butadiene or nitrile gloves should be used. Use impermeable gloves and protective clothing as
necessary to prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Aerosol
Color: Colorless
Odor: Slight, Solvent
Vapor pressure: Greater than 2000 mm Hg
pH: Not applicable
Boiling point/range: Not available
Melting point/range: Not available
Specific gravity: .712
Vapor density: Heavier than air
Evaporation rate: Not available
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available
VOC content: 92%; 655 grams/liter
10. STABILITY AND REACTIVITY
Stability: Stable.
Hazardous polymerization: Will not occur.
Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors.
Incompatability: Oxidizing agents.
Conditions to avoid: Heat, flames and sparks.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Item No. : 83490 Product name: FREKOTE AC4368 AE
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Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
n-Hexane No No No
110-54-3
Liquefied petroleum gas No No No
68476-85-7
Stoddard solvent No No No
8052-41-3
Xylene No No No
1330-20-7
Ethyl benzene No Group 2B Yes
100-41-4
Tetrakis(trimethylsiloxy)silane No No No
3555-47-3
1,2,4-Trimethylbenzene No No No
95-63-6
Toluene No No No
108-88-3
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
n-Hexane Developmental, Irritant, Lung, Nervous System, Reproductive
110-54-3
Liquefied petroleum gas Central nervous system, Lung, Irritant, Cardiac, Skin
68476-85-7
Stoddard solvent Central nervous system, Irritant
8052-41-3
Xylene Cardiac, Central nervous system, Irritant, Kidney, Liver
1330-20-7
Ethyl benzene Central nervous system, Irritant
100-41-4
Tetrakis(trimethylsiloxy)silane Irritant
3555-47-3
1,2,4-Trimethylbenzene Central nervous system, Irritant, Respiratory
95-63-6
Toluene Behavioral, Cardiac, Central nervous system, Developmental, Ear, Irritant
108-88-3
12. ECOLOGICAL INFORMATION
Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this
material; however, commonly available data on the material indicate that uncontrolled releases to soil,
groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the
quantity and concentration of such releases. Releases of volatile components to the atmosphere are
not believed to entail significant ecological consequences provided such releases are within the
exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to
avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which
may occur should be contained and cleaned up immediately in accordance with Section 6.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Do not puncture or
incinerate pressurized cans.
EPA hazardous waste number: D001: Ignitable.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Aerosols, flammable
Hazard class or division: ORM-D 2.1
Identification number: UN 1950
Packing group: None
Item No. : 83490 Product name: FREKOTE AC4368 AE
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Exceptions: ORM-D Consumer Commodity (Up to 1liter when shipped as originally packaged by Henkel only)
International Air Transportation (ICAO/IATA):
Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Fire
CERCLA/SARA 313: n-Hexane (CAS# 110-54-3).
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.
Canada Regulatory Information
CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances list.
WHMIS hazard class: A, B.5, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 2,8
Prepared by: Dan Shaw, Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
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