MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : SHELBY 275 SCR PRT FC ADH 275
IDENTIFICATION NUMBER: FSA275 DATE PRINTED: 02/06/03
PRODUCT USE/CLASS :
SUPPLIER: MANUFACTURER:
Camie-Campbell Camie-Campbell
9225 Watson Industrial Park 9225 Watson Industrial Park
St. Louis, MO 63126 St. Louis, MO 63126
EMERGENCY TELEPHONE: 800-424-9300 EMERGENCY TELEPHONE: 800-424-9300
24 HOUR EMERGENCY PHONE 24 HOUR EMERGENCY PHONE
PREPARER: JLM, PHONE: 314/968-3222, PREPARE DATE: 02/06/03
REPLACES DATE: 09/11/01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
01 HEXANE 110-54-3 45.0 %
02 DIMETHYL ETHER 115-10-6 20.0 %
03 ACETONE 67-64-1 20.0 %
04 ETHANE, 1,1-DIFLUORO 75-37-6 10.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
01 50 ppm N.E. 500 ppm N.E. N.E. NO
02 N.E. N.E. N.E. N.E. 1000 ppm NO
03 500 ppm 750 ppm 1000 ppm N.E. N.E. NO
04 N.E. N.E. N.E. N.E. 1000 ppm NO
(See Section 16 for abbreviation legend)
SECTION 3 - HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***: Keep from reach of children. Do not puncture,
incinerate, or place aerosol product containers in compactors. Containers
of this material may be hazardous when emptied since containers retain
product residues (vapor, liquid, and/or solid). All hazardprecautions
given must be observed. Do not flame cut, braze or use welding torch.
Intentional misuse by deliberately concentrating and inhaling this product
may be harmful or fatal.
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Product: FSA275 Preparation Date: 02/06/03 Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Can cause severe irritation,
redness, tearing, blurred vision.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can
cause moderate irritation defatting, dermatitis.
EFFECTS OF OVEREXPOSURE - INHALATION: Excessive inhalation of vapors can
cause nasal and respiratory irritation, dizziness, weakness, fatigue,
nausea, headache, possible unconsciousness, and even asphyxiation.
Possible cardiac arrhythmias at high concentrations. Overexposure may
cause damage to the nervous system.
EFFECTS OF OVEREXPOSURE - INGESTION: No Information.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure to this material
(or its components) has apparently been found to cause the following
effects in laboratory animals: kidney damage, eye damage, liver damage,
lung damage, nasal damage, nervous system damage, testis damage,
Overexposure to this material (or its components) has apparently been found
to cause the following effects in humans: visual impairment, central
nervous system effects,
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION EYE
CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE CONTACT: Flush with large amounts of water, lifting upper
and lower lids occasionally, get medical attention.
FIRST AID - SKIN CONTACT: Thoroughly wash exposed area with soap and
water. Remove contaminated clothing. Launder contaminated clothing before
re-use. Get medical attention if irritation persists. Mineral oil, baby
oil, makeup remover, mineral spirits, or other similar mild solvent may be
used to remove the sticky resin residue left by the adhesive.
FIRST AID - INHALATION: Remove individual to fresh air. If breathing is
difficult, administer oxygen. Give artificial respiration if breathing has
stopped. Keep person warm and quiet. Get medical attention.
FIRST AID - INGESTION: Do not induce vomiting. Give two glasses of water
if conscious. Never give anything by mouth to an unconscious person. Get
immediate medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: -58 F LOWER EXPLOSIVE LIMIT: 1.0 %
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 18.0 %
AUTOIGNITION TEMPERATURE: N.D.
(Continued on Page 3)
Product: FSA275 Preparation Date: 02/06/03 Page 3
SECTION 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and travel
along the ground or may be moved by ventilation and ignited by ignition
sources at locations distant from material handling point. For aerosol
products - exposure to temperatures over 130F may cause containers to burst
releasing highly flammable gas.
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus
with a full facepiece operated in pressure-demand or other positive
pressure mode when fighting fires. Keep fire exposed containers cool with
water fog.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Eliminate
sources of ignition & ventilate area. Persons not properly equipped should
be excluded from area. Stop spill at source - prevent spreading. Avoid
inhalation of vapors. Avoid skin contact with liquid. Soak up on
absorbent material and place into proper container for disposal. Use
non-sparking scoops for flammable materials. Clean walking surfaces
thoroughly to reduce slipping hazard.
SECTION 7 - HANDLING AND STORAGE
HANDLING: Containers of this material may be hazardous when emptied, since
containers retain product residues (vapor, liquid, and/or solid). All
hazard precautions given must be observed. Do not flame cut, braze or use
welding torch on containers. Intentional misuse by deliberately
concentrating and inhaling the vapors from this product may be harmful or
fatal.
STORAGE: Do not store above 120F. Do not store in direct sunlight. Keep
away from heat sources, open flame, pilot lights, sparks, and other sources
of ignition. Do not store above 120F. Do not store in direct sunlight.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (general
and/or local exhaust) ventilation to maintain exposure below TLV(s).
RESPIRATORY PROTECTION: If work place exposure limits of product or any
component is exceeded, use a NIOSH/MSHA approved respirator. Consult your
safety equipment supplier for recommendations.
SKIN PROTECTION: Wear impervious gloves if method of use involves skin
contact with product. Consult your safety supply vendor for glove
recommendations.
(Continued on Page 4)
Product: FSA275 Preparation Date: 02/06/03 Page 4
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: Wear safety glasses at minimum, more extensive protection
may be necessary depending on how the product is to be used.
OTHER PROTECTIVE EQUIPMENT: Wear impervious clothing if bodily exposure is
anticipated. Consult your safety supply vendor for recommendations.
HYGIENIC PRACTICES: Wash hands before eating or smoking. Smoke in
designated areas only. Remove and launder clothing if contaminated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE : -13 - 159 F VAPOR DENSITY : Is heavier than air
ODOR : MINT WHEN WET ODOR THRESHOLD : N.D.
APPEARANCE : WHITE LIQUID EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : NEGLIGIBLE Acetate
FREEZE POINT : N.D. SPECIFIC GRAVITY: 0.7084
VAPOR PRESSURE : N.D. pH @ 0.0 % : N.D.
PHYSICAL STATE : LIQUID VISCOSITY : N.D.
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D.
(See Section 16 for abbreviation legend)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heat, sparks, welding arcs, open flame, pilot lights,
static electricity or other source of ignition.
INCOMPATIBILITY: oxidizing agents, acids, alkali, alkaline earth
metals, reducing agents, strong oxidizers,
HAZARDOUS DECOMPOSITION PRODUCTS: hydrofluoric acid and possibly carbonyl
fluoride. carbon monoxide and carbon dioxide, various hydrocarbons,
sulfur dioxide, sulfur monoxide,
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
No product or component toxicological information is available.
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No Information.
(Continued on Page 5)
Product: FSA275 Preparation Date: 02/06/03 Page 5
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with all local, state and
federal regulations.
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: Aerosols
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 2.1 HAZARD SUBCLASS: NONE
DOT UN/NA NUMBER: UN1950 PACKING GROUP: NONE RESP. GUIDE PAGE: 126
ADDITIONAL INFORMATION:: For domestic ground and air shipment this product
may be shipped as a Consumer Commodity ORM-D. Outer cartons must have the
ORM-D or ORM-D AIR designation. (our original cartons are preprinted with
the ORM-D designation for ground shipment)
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD PRESSURIZED
GAS HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
HEXANE 110-54-3 45.0 %
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
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Product: FSA275 Preparation Date: 02/06/03 Page 6
SECTION 15 - REGULATORY INFORMATION
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
: Hexane is a mixture of n-hexane and other compounds all falling under
the general chemical name light hydrotreated distillate CAS-68410-97-9.
The n-hexane content of our hexane is 60 to 70 percent. On June 30, 1993
the OSHA Z-1-A table was revoked and OSHA reverted back to their prior
exposure limits. The values on this MSDS reflect the roll back to the
prior values. Some states may continue to enforce the 1993 limits. On
June 16, 1995 EPA announced in a final rule that acetone would no longer be
considered a VOC for air attainment standards.(it is now an exempt
compound) The VOC calculations on this MSDS are based on acetone being an
exempt compound. The June 16 rule also removed acetone from the list of
SARA 313 reportable chemicals.
SECTION 16 - OTHER INFORMATION
HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 1
PREVIOUS MSDS REVISION DATE: 09/11/01
REASON FOR REVISION: SCHEDULED UPDATE
VOLATILE BY WEIGHT: 83.5%
VOC CONTENT: 60.8 % BY WEIGHT, 450 GRAMS/LITER TOTAL PRODUCT,
567 GRAMS/LITER LESS WATER AND EXEMPT, 0.54 LBS/CAN
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
:
The information contained on this MSDS is been checked and should be
accurate. However, it is the responsibility of the user to comply with all
Federal, State, and Local laws and regulations. The environmental
information and hazardous materials identification system have been
included by Camie-Campbell Inc. in order to provide additional health and
hazard classification information. The ratings recommend are based upon
the criteria supplied by the developers of these rating systems, together
with Camie-Campbell Inc.'s interpretation of the available data. Proper
personal protective equipment varies widely with conditions of use and
anticipated exposure. We recommend that a supervisor or other qualified
person determine proper PPE for intended use.
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