GenFlex Roofing Systems
Material Safety Data Sheet
June 1, 2009
Material Name: Bonding Adhesive
* * * Section 1 - Chemical Product and Company Identification * * *
Product Use: Adhesive
Manufacturer Information
GenFlex Roofing Systems, LLC Phone: 317-575-7190 (Non-Emergency)
250 West 96th Street
Indianapolis, IN 46260 Emergency # 1-800-424-9300 (CHEMTREC)
International # 1-703-527-3887 (CHEMTREC)
General Comments
NOTE: CHEMTREC telephone number is to be used only in the event of chemical emergencies involving a spill, leak, fire,
exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service.
* * * Section 2 - Hazards Identification * * *
Emergency Overview
Product is a flammable amber yellow liquid. This product may be harmful or fatal if swallowed or inhaled. Inhalation of
vapors in large amounts may cause CNS depression. This product is a pulmonary aspiration hazard.
Potential Health Effects: Eyes
This product may cause irritation to the eyes. Vapors, fumes, or particles from this material will cause eye irritation.
Symptoms include redness, swelling, tearing and blurred vision.
Potential Health Effects: Skin
This product may cause irritation to the skin. Prolonged or repeated contact may cause redness, cracking and may dry and/or
defat the skin.This product may be harmful if it is absorbed through the skin.
Potential Health Effects: Ingestion
This product may be harmful or fatal if swallowed. Ingestion can cause gastrointestinal irritation, nausea, vomiting and
diarrhea. Aspiration of small amounts into the lung may produce severe lung damage, including chemical pneumonitis.
Potential Health Effects: Inhalation
This product is harmful or fatal if inhaled. Inhalation of vapors may cause irritation of the respiratory tract. Other symptoms
may include signs of CNS depression involving weakness, dizziness, giddiness, loss of coordination and judgement. Severe
overexposure may cause coma and death due to respiratory failure. This product contains significant amounts of n-hexane,
which can damage the peripheral nervous system and produce paralysis, numbness, or tingling in the extremities. Chronic
overexposure to vapors may produce symptoms including permanent damage to the central nervous system (e.g., chronic
headaches, memory loss, behavioral changes, hallucinations), birth defects and reproductive hazards.
HMIS Ratings: Health: 2* Fire: 3 Reactivity: 0 Pers. Prot.: chemical goggles, impervious gloves
(Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard)
* * * Section 3 - Composition / Information on Ingredients * * *
CAS # Component Approx.
Percent
108-88-3 Toluene 50-75
142-82-5 Heptane (n-) 5-20
110-54-3 Hexane 5-20
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes with plenty of water for at least 15 minutes.
First Aid: Skin
For skin contact, promptly wash with soap and water. If irritation develops, get medical attention.
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
First Aid: Ingestion
If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting unless instructed to do so
by medical personnel.
First Aid: Inhalation
If inhaled, remove immediately to fresh air. If symptoms develop or persist, seek immediate medical attention.
First Aid: Notes to Physician
This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately.
* * * Section 5 - Fire Fighting Measures * * *
Flash Point: 0篎 (-19.4篊) Method Used: Tag Closed Cup
Upper Flammable Limit (UFL): 7.5% Lower Flammable Limit (LFL): 1.1%
Auto Ignition: Not available Flammability Classification: Flammable
Rate of Burning: Not available
General Fire Hazards
Product is a flammable liquid. Fire and explosion hazards are moderate when this product is exposed to heat or flame.
Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back. Empty
containers may retain product residue including Flammable or Explosive vapors. Do not cut, drill, grind, or weld near full,
partially full, or empty product containers.
Hazardous Combustion Products
Upon combustion the product may yield smoke, fumes, aldehydes, carbon monoxide, carbon dioxide and other low molecular
weight hydrocarbons.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog. Use water to cool fire-exposed containers and to protect personnel. Water
may be an ineffective extinguishing medium.
Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self contained breathing apparatus.
NFPA Ratings: Health: 2 Fire: 3 Reactivity: 0
(Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe)
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Contain by any means necessary. Eliminate all sources of ignition or flammables that may come into contact with a spill of
this material.
Clean-Up Procedures
Absorb spilled material with nonflammable inert absorbent. Do not allow the spilled product to enter public drainage system
or open water courses. Ventilate the contaminated area. Thoroughly wash the area with water after a spill or leak clean-up.
Evacuation Procedures
Evacuate the area promptly. Keep upwind of the spilled material and isolate exposure.
Special Procedures
Avoid skin contact and inhalation of vapors during disposal of spills.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Do not breathe gas/fumes/vapor/spray. Use this product with adequate ventilation. Do not get this material in your eyes, on
your skin, or on your clothing. Wash thoroughly after handling. Keep this product from heat, sparks, or open flame.
Storage Procedures
Keep this material in a cool, well-ventilated place. Eliminate all sources of ignition.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Exposure Guidelines
A: General Product Information
Follow all applicable exposure limits.
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
B: Component Exposure Limits
Toluene (108-88-3)
ACGIH: 50 ppm TWA
skin - potential for cutaneous absorption
OSHA: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
NIOSH: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
Hexane (110-54-3)
ACGIH: 50 ppm TWA
skin - potential for cutaneous absorption
OSHA: 500 ppm TWA; 1800 mg/m3 TWA
NIOSH: 50 ppm TWA; 180 mg/m3 TWA
Heptane (n-) (142-82-5)
ACGIH: 400 ppm TWA
500 ppm STEL
OSHA: 500 ppm TWA; 2000 mg/m3 TWA
NIOSH: 85 ppm TWA; 350 mg/m3 TWA
C 440 ppm; C 1800 mg/m3 (15 min)
Engineering Controls
Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces. Special care must be taken to
avoid inhalation exposure when using this product at high temperatures.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear chemical goggles; face shield (if splashing is possible).
Personal Protective Equipment: Skin
Use impervious gloves. Use of protective coveralls and long sleeves is recommended.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively remove vapors or mists, appropriate NIOSH approved respiratory protection must
be provided.
Personal Protective Equipment: General
Use good industrial hygiene practices in handling this material.
* * * Section 9 - Physical & Chemical Properties * * *
Amber yellow liquid. Typical solvent odor
Appearance: Odor:
Liquid Not available
Physical State: pH:
Not available Heavier than air
Vapor Pressure: Vapor Density:
149?231篎 Not available
Boiling Point: Melting Point:
Insoluble 0.86555
Solubility (H2O): Specific Gravity:
Faster than n-Butyl Acetate 84.9% (vol)
Evaporation Rate: Weight % Volatile:
0?F (-19?C)
Flash Point:
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
Stable under normal conditions.
Chemical Stability: Conditions to Avoid
Avoid open flame and excessive temperatures. Keep away from ignition sources and incompatible materials.
Incompatibility
This product may react with strong acids, strong bases and oxidizing agents Avoid extreme heat which can result in thermal
decomposition releasing toxic gases.
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
Hazardous Decomposition
Upon decomposition this product may yield smoke, fumes, aldehydes, carbon monoxide, carbon dioxide and other low
molecular weight hydrocarbons.
Hazardous Polymerization
Hazardous polymerization will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Toxicity
A: General Product Information
No information available for the product.
Vapors may be irritating to the skin, eyes and respiratory system. Overexposure to this product may cause central nervous
system (CNS) depression with symptoms including nausea, vomiting, weakness, dizziness, giddiness, loss of coordination
and judgement Severe overexposure may cause coma and death due to respiratory failure.
Intentional misuse by deliberately concentrating and inhaling vapor may be harmful or fatal.
Continued overexposure to toluene may produce nervous system damage including muscle tingling, numbness, coma and
death. This solvent may pass through intact skin producing toxicities, and may also produce cardiac sensitization as well as
damage to the liver, kidneys and bone marrow. Excessive inhalation of solvent vapors may produce sudden death due to
cardiac sensitization. It has been reported in experimental rats that hexane acted synergistically with toluene to induce
hearing loss in high airborne concentrations.
N-hexane is a mild irritant and CNS depressant in acute exposure, but its principal effects are damage to the sensory and
motor peripheral nerves.
Heptane causes eye, skin, and respiratory irritation. Inhalation causes fatigue, incoordination, hyperactivity, tremors, and
other CNS effects. Ingestion causes diarrhea, slight CNS depression, difficulty breathing, and tremors. Some components of
this mixture have produced kidney damage in rats in a subchronic oral laboratory study. Aspiration of the liquid may result
in chemical pneumonitis.
B: Component Analysis - LD50/LC50
Toluene (108-88-3)
Inhalation LC50 Rat : 49 gm/m3/4H
Inhalation LC50 Mouse : 400 ppm/24H
Oral LD50 Rat : 636 mg/kg
Dermal LD50 Rabbit : 14100 uL/kg
Hexane (110-54-3)
Inhalation LC50 Rat : 48000 ppm/4H
Oral LD50 Rat : 28710 mg/kg
Heptane (n-) (142-82-5)
Inhalation LC50 Rat : 103 gm/m3/4H
Carcinogenicity
A: General Product Information
No information available for this product.
B: Component Carcinogenicity
Toluene (108-88-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 71, 1999; Monograph 47, 1989 (Group 3 (not classifiable))
Epidemiology
No information available for this product.
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
Neurotoxicity
No information available for this product.
Toluene may cause central nervous system depression which produces lightheadedness, nausea, headache and ataxia at low
doses and confusion behavioral and intelligence effects, coma and death at high doses. Repeated exposure to toluene has a
cumulative effect on the nervous system. The neurological effects of chronic exposure to high levels of toluene gradually
progress to an irreversible state. Besides effects on behavior and intelligence, degeneration of the optic nerve and nerve
deafness have also been reported in excessive exposure.
This product contains significant amounts of n-hexane, which can damage the peripheral nervous system and produce
paralysis, numbness, or tingling in the extremities.
Mutagenicity
No information available for the product.
Toluene was not mutagenic in the Ames Salmonella/microsome assay. The results of chromosomal assays have been mixed.
In vitro sister chromatid exchange and chromosome aberrations using human lymphocytes have been both positive and
negative.
Teratogenicity
No information available for the product.
Women exposed to toluene in laboratory work had a approximately 5-fold increased risk of spontaneous abortions, without
an increase in birth defects. Intentional and deliberate abuse of toluene has produced birth defects that include
microencephaly, CNS deficiencies, and facial abnormalities, as well as disturbances in growth. The spectrum of defects in
children of women who have abused toluene and other solvents has been called Fetal Solvent Syndrome. Several animal
studies using rats, mice, and rabbits have shown that exposure to toluene during gestation has caused fetotoxicity, fetal
biochemical/behavioral changes, and developmental effects.
n-hexane caused degeneration of the testes in experimental rats.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for product. Organic solvents may produce significant toxicity to aquatic organisms and
ecosystems.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Toluene (108-88-3)
Test & Species Conditions
LC50 (96 hr) fathead minnow (1 day 25.0-36.0 mg/L. Flow-through, 25 篊, pH 8.3, 80.0 mg/L CaCO3.
old)
LC50 (96 hr) rainbow trout 24.0 mg/L. Static, 15 篊, pH 7.2-7.5, 40.0-50.0 mg/L
CaCO3.
LC50 (96 hr) bluegill 24.0 mg/L. Static, 25 篊, pH 7.5, 20.0 mg/L CaCO3.
EC50 (30 min) Photobacterium 19.7 mg/L
phosphoreum Microtox test.
EC50 (48 hr) water flea 11.3-19.6 mg/L.
EC50 (48 hr) water flea 310-313 mg/L.
Hexane (110-54-3)
Test & Species Conditions
LC50 (96 hr) rainbow trout 4.14 mg/L.
LC50 (96 hr) fathead minnow 5.10 mg/L.
LC50 (96 hr) bluegill 4.12 mg/L.
LC50 (48 hr) water flea 3.87 mg/L.
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
Heptane (n-) (142-82-5)
Test & Species Conditions
LC50 (24 hr) 4.0 mg/L.
goldfish
LC50 (24 hr) 4900 mg/L.
mosquito fish
LC50 (96 hr) cichlid 375.0 mg/L.
fish
Environmental Fate
No information available for the product.
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
If discarded as supplied, this product is considered a RCRA ignitable waste, D001. Waste should be tested using methods
described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes.
B: Component Waste Numbers
Toluene (108-88-3)
RCRA: waste number U220
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
* * * Section 14 - Transportation Information * * *
US DOT, IATA/ICAO Information
Shipping Name: Adhesives (Contains: Toluene , Hexane , Heptane (n-) )
Hazard Class: 3
UN/NA #: UN1133
Packing Group: II
Required Label(s): Flammable Liquid
Additional Info.: The Reportable Quantity for Hexane is 5000 lbs.(2270 kg). For shipments, in a single container,
exceeding the RQ for Hexane RQ must follow the proper shipping name. If shipping by passenger aircraft the container can
not be larger than 5L, for cargo aircraft, container can be no larger than 60L.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
No additional information.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR
355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Toluene (108-88-3)
SARA 313: form R reporting required for 1.0% de minimis concentration
CERCLA: final RQ = 1000 pounds (454 kg)
Hexane (110-54-3)
SARA 313: form R reporting required for 1.0% de minimis concentration
CERCLA: final RQ = 5000 pounds (2270 kg)
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements. This product contains trace amounts (<0.1%) of
formaldehyde.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Toluene 108-88-3 Yes Yes Yes Yes Yes Yes
Hexane 110-54-3 No Yes Yes Yes Yes Yes
Heptane (n-) 142-82-5 Yes Yes Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition
65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects.
Other Regulations
A: General Product Information
No additional information.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Toluene 108-88-3 Yes Yes Yes
Hexane 110-54-3 Yes Yes Yes
Heptane (n-) 142-82-5 Yes Yes Yes
C: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS #
Toluene 108-88-3 1%; English Item 1578; French
Item 1622
Hexane 110-54-3 1%; English Item 828; French
Item 965
Heptane (n-) 142-82-5 1%; English Item 806; French
Item 940
* * * Section 16 - Other Information * * *
Date of Previous MSDS: April 4, 2007
Changes Since Previous MSDS: Section 1 ?Product name change and company address change.
Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of
Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for
Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health
Administration; NFPA = National Fire Protection Association; HMIS = Hazardous Material Identification System; CERCLA
= Comprehensive Environmental Response, Compensation and Liability Act; SARA = Superfund Amendments and
Reauthorization Act
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GenFlex Roofing Systems
Material Safety Data Sheet
Material Name: TPO Bonding Adhesive June 1, 2009
* * * Disclaimer * * *
The information contained herein is based on data considered accurate which has been obtained from other companies and
organizations. However, no warranty or representation is expressed or implied that the information, is accurate, complete or
representative. GenFlex Roofing Systems, LLC, a subsidiary of Bridgestone Firestone Diversified Products, LLC, assumes no
responsibility for injury to the buyer, the buyer's employees, or any third persons, if reasonable safety procedures are not followed.
Additionally, GenFlex Roofing Systems, LLC assumes no responsibility for injury to buyer, the buyer's employees, or any third
persons caused by abnormal use of this material, even if reasonable safety procedures are followed.
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