MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
TRADE NAME:
3M Blue Glue NF Carpet Adhesive
ID NUMBER/U.P.C.:
62-4224-7530-1 00-21200-21158-4 62-4224-8530-0 00-21200-21159-1
62-4224-9530-9 00-21200-21160-7
ISSUED: November 28, 2001
SUPERSEDES: May 24, 2001
DOCUMENT: 10-2981-8
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1. INGREDIENT C.A.S. NO. PERCENT
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WATER................................... 7732-18-5 55.0 - 65.0
ACRYLIC POLYMER......................... 9017-68-9 35.0 - 45.0
ACRYLIC POLYMER......................... 25212-88-8 .1 - .75
AMMONIA................................. 7664-41-7 0.1 - .75
TOLUENE................................. 108-88-3 .01 - .2
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
The components of this product are in compliance with the chemical
notification requirements of TSCA.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
AMMONIA
TOLUENE
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2. PHYSICAL DATA
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BOILING POINT:................. > 210.00 F
VAPOR PRESSURE:................ N/A
VAPOR DENSITY:................. N/A
EVAPORATION RATE:.............. N/A
SOLUBILITY IN WATER:........... Disperses in water
SPECIFIC GRAVITY:.............. 1.040 Water=1
PERCENT VOLATILE:.............. ca. 57.00 % by wt
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Blue Glue NF Carpet Adhesive
November 28, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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pH:............................ 8.00 - 8.50
VISCOSITY:..................... 9000.0 - 10000.0 centipoise
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
liquid, blue, distinct odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... N/A
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Not applicable.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 0 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Not applicable.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Aldehydes, Ketones, Toxic Vapors,
Gases or Particulates.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Blue Glue NF Carpet Adhesive
November 28, 2001 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Cover with absorbent material.
Collect spilled material. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility in the presence of
a combustible material. Dispose of completely cured (or polymerized)
material in a sanitary landfill.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 1 gms/liter South Coast Air Quality Mgmt Dist
Method Rule 443.1, calculated.
VOC Less H2O & Exempt Solvents: 2 gms/liter South Coast Air Quality Mgmt
Dist Method Rule 443.1, calculated.
Hazardous Air Pollutants: < .12 % by wt calculated.
Hazardous Air Pollutants: ca. .003 #/# solids calculated.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S.
EPA Hazardous).
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Blue Glue NF Carpet Adhesive
November 28, 2001 PAGE 4
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
Wear safety glasses with side shields.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material. A pair of gloves made from the
following material(s) are recommended: butyl rubber, neoprene,
nitrile rubber.
RECOMMENDED VENTILATION:
Use with functioning spray booth or local exhaust. Use in a well-
ventilated area. Provide sufficient ventilation to maintain
emissions below recommended exposure limits.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures above 32 degrees F (O degrees C). Keep
container closed when not in use. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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WATER................................ NONE NONE NONE NONE
ACRYLIC POLYMER...................... NONE NONE NONE NONE
ACRYLIC POLYMER...................... NONE NONE NONE NONE
AMMONIA.............................. 25 PPM TWA ACGIH
AMMONIA.............................. 35 PPM STEL ACGIH
AMMONIA.............................. 35 PPM STEL OSHAV
OSHA VACATED PEL
AMMONIA.............................. 50 PPM TWA OSHA
TOLUENE.............................. 50 PPM TWA ACGIH Y
TOLUENE.............................. 100 PPM TWA OSHAV
OSHA VACATED PEL
TOLUENE.............................. 150 PPM STEL OSHAV
OSHA VACATED PEL
TOLUENE.............................. 200 PPM TWA OSHA
TOLUENE.............................. 300 PPM CEIL OSHA
TOLUENE.............................. 75 PPM STEL CMRG Y
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Blue Glue NF Carpet Adhesive
November 28, 2001 PAGE 5
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
INHALATION:
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE May 24, 2001 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Blue Glue NF Carpet Adhesive
November 28, 2001 PAGE 6
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
MATERIAL SAFETY DATA SHEET
Greenline
I. PRODUCT IDENTIFICATION
GL62
Name: GL62 High-Performance Carpet Adhesive
Description: Filled, latex adhesive
II. DEPARTMENT OF TRANSPORTATION INFORMATION
Prepared 01/02
SHIPPING NAME: Not Classified. HAZARD CLASS: N/A. ID#: N/A.
EMERGENCY ONLY CONTACT: CHEM-TEL-1-800-255-3924
The W.W. Henry Company
III. HMIS (0=minimal hazard; 4 = severe hazard) 400 Ardex Park Drive
Aliquippa, PA 15001
Health = 0 Flammability = 0 Reactivity = 0
(724) 203-8499
Visit our Website: http://www.wwhenry.com
IV. PRODUCT CONTENT
This product does not contain chemicals subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR 372. All
components are on TSCA inventory. This product does NOT con-
tain asbestos.
V. HAZARDOUS INGREDIENTS
INGREDIENT: PERCENT: OCCUP. EXPOS. LMT.
NONE N/A N/A
VI. PHYSICAL DATA X. SPILL OR LEAK PROCEDURES
APPEARANCE: Smooth, off-white paste. BOILING POINT: STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Approximately 212F (water). MELTING POINT: N/A. VAPOR Contain spill, preventing it from entering sewer lines or water-
PRESSURE: Water. VAPOR DENSITY: Water. % VOLATILE BY ways. Use absorbent to assist with the pick-up of material. Scrape
WEIGHT (30 min. @ 275F): 30%. EVAPORATION RATE: Water. up product and place into container. Residual of product, while
WT/GAL (water=8.3): 9.52 lb. SOLUBILITY IN WATER: still wet, can be cleaned up with warm soapy water. WASTE DIS-
Dilutable. SPECIFIC GRAVITY: 1.14. VOC: 0 g/l calculated at POSAL METHOD: Dispose of container and any unused contents
70F/21C, SCAQMD. pH: 9.3. in accordance with Federal, State, and Local Waste Disposal
Regulations. Do not flush unused contents or residue down
VII. FIRE AND EXPLOSION HAZARD DATA drains. Do not reuse container.
FLASH POINT (METHOD): > 200F (Setaflash Closed Tester). XI. SAFE HANDLING AND USE INFORMATION
FLAMMABLE RANGE: LEL: N/A; UEL: N/A. EXTINGUISHING
MEDIA: Carbon dioxide, dry chemical, water spray. SPECIAL VENTILATION: Normal, ambient ventilation should be sufficient.
FIRE FIGHTING PROCEDURES: Protect fire fighters from toxic RESPIRATORY PROTECTION: Should not be required. SKIN
products of combustion by wearing self-contained breathing AND EYE PROTECTION: It is always a good safety practice to
apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: avoid contact with eyes and prolonged contact with skin. Use
Closed containers in a fire may rupture due to pressure build-up; spectacle-type glasses and latex or rubber gloves to avoid con-
use water to cool containers to prevent this. tact.
VIII. HEALTH HAZARD DATA XII. SPECIAL PRECAUTIONS
PRIMARY ROUTE(S) OF ENTRY: N/A. TARGET ORGANS: N/A. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
EFFECTS OF OVEREXPOSURE: SKIN AND EYES: May produce Recommended storage temperature is below 90 F. OTHER PRE-
slight transient irritation to the eyes and skin. INHALATION: N/A. CAUTIONS: None. WORK SITE ENVIRONMENT: Establish and
CARCINOGENICITY: NTP: No. IARC Monographs: No. OSHA maintain adequate ventilation of the work area. Persons who are
Regulated: No. MEDICAL CONDITIONS GENERALLY AGGRA- sensitive to odors and/or chemicals should be advised to avoid
VATED BY EXPOSURE: None. FIRST AID PROCEDURES: EYES: the work area.
Flush any eye contact with plenty of water. With skin contact,
The information presented herein is supplied as a guide to those
wash with soap and water. Refer to physician if irritation devel-
who handle or use this product. Safe work practices must be
ops or symptoms persist. INHALATION: N/A.
employed when working with any materials. It is important that
IX. REACTIVITY DATA the end user makes a determination regarding the adequacy of
the safety procedures employed during the use of this product.
STABILITY: Stable. INCOMPATIBILITY: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monox-
N/A - not applicable or not available
ide, carbon dioxide, and other toxic vapors and gases that are
common to thermal degradation of organic compounds. HAZ-
ARDOUS POLYMERIZATION: Will not occur.
475 Hi-Tack Carpet Adhesive
MATERIAL SAFETY DATA SHEET Page: 1
PRODUCT NAME: 475 Hi-Tack Carpet Adhesive HMIS CODES: HFRP
PRODUCT CODE: 475D 100B
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: CHICAGO ADHESIVE PRODUCTS CO.
ADDRESS: 1165 ARBOR DRIVE
ROMEOVILLE, IL 60446
EMERGENCY PHONE : 800-424-9300 DATE REVISED : 03/13/2000
DATE PRINTED : 02/08/2001
INFORMATION PHONE : 630-679-9100 NAME OF PREPARER: Chris Gonzalez
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
COMPONENTS CAS NUMBER MM HG @ TEMP PERCENT
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*** No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are
present. Hazardous ingredients must be reported when present at 1.0% or greater.***
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING POINT: 212 Degrees F. SPECIFIC GRAVITY (H2O=1): 1.17
VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than Ether.
SOLUBILITY IN WATER: Soluble.
APPEARANCE AND ODOR: Light tan soft paste - Slight ammonia odor
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT: NA METHOD USED: NA
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: NA UPPER: NA
EXTINGUISHING MEDIA: Will not support combustion.
SPECIAL FIRE FIGHTING PROCEDURES: None
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: Stable
CONDITIONS TO AVOID: NA
INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents and caustics
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Oxides of carbon if co-burned with flammable material
HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: None Known
==================== SECTION VI - HEALTH HAZARD DATA =======================
475 Hi-Tack Carpet Adhesive
MATERIAL SAFETY DATA SHEET Page: 2
ROUTES OF ENTRY: Inhalation and skin contact are expected to be the primary routes of occupational exposure with
this product. This material is not expected to cause adverse effects when good industrial hygiene and safety practices are
followed.
HEALTH HAZARDS: None known
SIGNS & SYMPTOMS OF EXPOSURE: None
ACUTE EFFECTS OF OVEREXPOSURE: None known to occur
CHRONIC EFFECTS OF OVER EXPOSURE: None known to occur
CARCINOGENICITY: NTP: No known effect
IARC MONOGRAPHS: No
OSHA REGULATED: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
None known
EMERGENCY AND FIRST AID PROCEDURES:
Eyes - Flush with water for 15 minutes, lifting eyelids occasionally.
Skin - Wash with soap and water;
Ingestion - Do not induce vomiting. CALL PHYSICIAN IMMEDIATELY.
Inhalation - Should inhalation problems occur, move victim to fresh air and aid in breathing if necessary.
**IF IRRITATION SHOULD DEVELOP OR PERSIST FROM THE ABOVE EXPOSURES, CALL
PHYSICIAN IMMEDIATELY.***
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Scrape up excess and place in D.O.T. approved container. Clean with soapy water.
HAZARDOUS SUBSTANCE SUPERFUND: NA
WASTE DISPOSAL METHOD: Dispose of as per local, state and federal
regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and store in cool dry
place.
OTHER PRECAUTIONS: NA
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION: None required
VENTILATION: Local exhaust; Use with adequate ventilation. Open doors and windows to create cross ventilation
during use and until adhesive dries.
PROTECTIVE CLOTHES/GLOVES: Impervious gloves
EYE PROTECTION: Safety goggles required
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required
475 Hi-Tack Carpet Adhesive
MATERIAL SAFETY DATA SHEET Page: 3
WORK/HYGENIC PRACTICES: Thorough washing of skin with soap and water before eating, or drinking.
===================== SECTION IX - SHIPPING INFORMATION =================
D.O.T. PROPER SHIPPING NAME: Adhesives
HAZARDOUS SUBSTANCE 49CFR CERCLA: NA
HAZARD CODE: NA
D.O.T. HAZARD CLASS: Not Regulated
D.O.T. LABELS REQUIRED: NA
D.O.T. PLACARDS REQUIRED: NA
POISON CONSTITUENT: NA
BILL OF LADING DESCRIPTION: Adhesives
CC NO: NA
UN/NA CODE: NA
CHEMICAL EMERGENCY: CHEMTREC 24 HOURS: 1-800-424-9300
================== SECTION XI - OTHER REGULATORY INFOMATION =============
TSCA INVENTORY STATUS: Listed on Inventory: Yes
PROPOSITION 65:
If your business resides in the state of California or if you supply products directly or indirectly into California, we are
providing this information to you pursuant to the California Safe Drinking Water and Toxic Act of 1986 (commonly
known as proposition 65). This law requires, in part, that "no person in the course of doing business shall knowingly and
intentionally expose any individual to chemicals known to the state to cause cancer or reproductive toxicity without first
exempt from the warning requirements "an exposure for which the person responsible can show that the exposure poses
no significant risk..." (Section 25249.10).
There may be small, perhaps undetectable amounts, of other naturally occuring chemicals that are known to the State of
California to cause cancer, birth defects or other reporductive harm. This warning is provided in the absence of definitive
testing to prove that these risks do not exist. These amounts are typical quantities and may be below the Proposition 65
level of concern, or could even be zero.
OSHA Standard 29CFR 1910.1200 requires that information be provided to employees regarding the hazards of
chemicals by means of a hazard communication program including labeling, material safety data sheets, training and
access to written records. We request that you and it is your legal duty to, make all information in this material safety data
sheet available to your employees.
The Following ingredients are considered to be classified as per OSHA HazardCommunication Standard
(29CFR1910.1200):
NA
475 Hi-Tack Carpet Adhesive
MATERIAL SAFETY DATA SHEET Page: 4
====================== SECTION X - DISCLAIMER INFOMATION ==================
***THE CRITERIA FOR LISTING COMPONENTS IN THE HAZARDOUS INGREDIENTS SECTIONS IS AS
FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1% OR GREATER; COMPONENTS
WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT
1.0% OR GREATED.
While this information and recommendations set forth herein are believed to be accurate as of the date hereof,
Chicago Adhesive Products Co. (CHAPCO) MAKES NO WARRANTY WITH RESPECT HERETO AND
DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.
The information contained within the MSDS is considered propriety and is a trade secret. Unauthorized
distribution or duplication of this information is prohibited.
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