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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
1 Identification of substance
?Product details
?Trade name: 77721,77724 XXX Adhesion Promoter
?Article number: 77721, 77724
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Information department:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Emergency information: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
108-88-3 toluene 25-50%
Danger: 2.6/2; 3.10/1, 3.7/2
Warning: 3.2/2, 3.3/2A, 3.8/3
64742-89-8 Solvent naphtha (petroleum), light aliph. 25-50%
Danger: 2.6/1; 3.10/1
123-86-4 n-butyl acetate 10-25%
Warning: 2.6/3; 3.8/3
67-64-1 acetone 1-2.5%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
3 Hazards identification
?Hazard description:
Toxic
Highly flammable
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
May cause cancer.
Highly flammable.
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
Danger of serious damage to health by prolonged exposure.
Possible risk of harm to the unborn child.
Harmful: may cause lung damage if swallowed.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 1)
?NFPA ratings (scale 0 - 4)
Health = 2
3 Fire = 3
2 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 3
FIRE 3
Reactivity = 0
REACTIVITY 0
?GHS label elements
Danger
2.6/2 - Highly flammable liquid and vapour.
Danger
3.6/1B - May cause cancer.
3.10/1 - May be fatal if swallowed and enters airways.
3.7/2 - Suspected of damaging fertility or the unborn child.
Warning
3.1/4 - Harmful if inhaled.
3.2/2 - Causes skin irritation.
3.3/2A - Causes serious eye irritation.
3.8/3 - May cause respiratory irritation.
?Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
?Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 2)
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
Do NOT induce vomiting.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use for extinction: CO2, powder or water spray.
?Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
4 First aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 3)
Open and handle receptacle with care.
Prevent formation of aerosols.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
108-88-3 toluene
PEL Short-term value: C 300; 500* ppm
Long-term value: 200 ppm
*10-min peak per 8-hr shift
REL Short-term value: 560 mg/m? 150 ppm
Long-term value: 375 mg/m? 100 ppm
TLV 75 mg/m? 20 ppm
123-86-4 n-butyl acetate
PEL 710 mg/m? 150 ppm
REL Short-term value: 950 mg/m? 200 ppm
Long-term value: 710 mg/m? 150 ppm
TLV Short-term value: 950 mg/m? 200 ppm
Long-term value: 713 mg/m? 150 ppm
67-64-1 acetone
PEL 2400 mg/m? 1000 ppm
REL 590 mg/m? 250 ppm
TLV Short-term value: 1782 mg/m? 750 ppm
Long-term value: 1188 mg/m? 500 ppm
BEI
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 4)
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 56癈 (133癋)
-19癈 (-2癋)
?Flash point:
370癈 (698癋)
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
In use, may form flammable/explosive vapour-air mixture.
?Danger of explosion:
?Explosion limits:
1.2 Vol %
Lower:
7.5 Vol %
Upper:
?Vapor pressure at 20癈 (68癋): 29 hPa (22 mm Hg)
0.82 g/cm?br>
?Density at 20癈 (68癋):
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 5)
?Solvent content:
95.5 %
Organic solvents:
93.0 %
VOC content:
762.0 g/l / 6.36 lb/gl
4.5 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic.
12 Ecological information
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 6)
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
3
?Hazard class:
UN1263
?Identification number:
II
?Packing group:
?Proper shipping name (technical name): PAINT
3
?Label
?Land transport TDG (Canada) and ADR/RID (Europe):
3 Flammable liquids
?Hazard class:
1263
?UN-Number:
II
?Packaging group:
3
?Label:
1263 PAINT, special provision 640D
?Description of goods:
?Maritime transport IMDG:
3
?IMDG Class:
1263
?UN Number:
3
?Label
II
?Packaging group:
F-E,S-D
?EMS Number:
No
?Marine pollutant:
PAINT
?Propper shipping name:
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1263
?UN/ID Number:
3
?Label
II
?Packaging group:
(Contd. on page 8)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 7)
PAINT
?Propper shipping name:
?UN "Model Regulation": UN1263; PAINT; 3; II
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
108-88-3 toluene
78-93-3 butanone
?TSCA (Toxic Substances Control Act):
108-88-3 toluene
64742-89-8 Solvent naphtha (petroleum), light aliph.
123-86-4 n-butyl acetate
67-64-1 acetone
78-93-3 butanone
?Proposition 65
?Chemicals known to cause cancer:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
108-88-3 toluene
?Cancerogenity categories
?EPA (Environmental Protection Agency)
108-88-3 toluene D
67-64-1 acetone D
78-93-3 butanone D
?IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
108-88-3 toluene A4
67-64-1 acetone A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
(Contd. on page 9)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 01/31/2008 Reviewed on 01/31/2008
Trade name: 77721,77724 XXX Adhesion Promoter
(Contd. of page 8)
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Toxic
Highly flammable
?Hazard-determining components of labelling:
toluene
Solvent naphtha (petroleum), light aliph.
?Risk phrases:
May cause cancer.
Highly flammable.
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
Danger of serious damage to health by prolonged exposure.
Possible risk of harm to the unborn child.
Harmful: may cause lung damage if swallowed.
?Safety phrases:
Avoid exposure - obtain special instructions before use.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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