SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Identification of the : 50% Deoxo-FluorTM in Toluene
substance/preparation
Company : Air Products and Chemicals,Inc
7201 Hamilton Blvd.
Allentown
Postcode 18195-1501
Telephone :
Emergency telephone number : 800-523-9374 USA
01-610-481-7711 International
2. COMPOSITION/INFORMATION ON INGREDIENTS
Components EINECS / ELINCS CAS Number Concentration Classification
(Weight)
Toluene 203-625-9 108-88-3 50 % F ; Xn
R11 ; R38 ;
R48/20 ; R63 ;
R65 ; R67 ;
Repr.Cat.3
SULFUR, TRIFLUOR [2- 202289-38-1 50 % T;E
METHOXY-N-(2- R35 ; R25 ; R 2 ;
METHOXYETHYL) R14
ETHANAMINATO-k N]-,(T-4)
Refer to section 16 for full text of each relevant R-phrase.
3. HAZARDS IDENTIFICATION
Classification
R11 Highly flammable.
R14 Reacts violently with water.
R20 Harmful by inhalation.
R25 Toxic if swallowed.
R35 Causes severe burns.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapors may cause drowsiness and dizziness.
Emergency Overview
Corrosive.
Keep away from heat and sources of ignition.
Components of the product may affect the nervous system.
Reproductive toxin.
Flammable.
Severe respiratory irritant.
Severe skin irritant.
Severe eye irritant.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Reacts violently with water.
Toxic if swallowed.
Potential Health Effects
Inhalation : Inhalation of aerosol may cause irritation to the upper respiratory tract. Risk of
serious damage to the lungs (by inhalation). May cause nose, throat, and lung
irritation. Can cause severe eye, skin and respiratory tract burns. May cause
central nervous system effects, such as headache, nausea, dizziness,
confusion, breathing difficulties. Severe cases of overexposure can result in
respiratory failure. Inhalation of vapors and/or aerosols in high concentration
may cause irritation of respiratory system.
Eye contact : Causes eye burns. May cause blindness. Severe eye irritation.
Skin contact : Causes skin burns. If absorbed through the skin, may cause central nervous
system effects, such as headache, nausea, dizziness, confusion, breathing
difficulties.
Ingestion : If ingested, severe burns of the mouth and throat, as well as a danger of
perforation of the oesophagus and the stomach. May cause central nervous
system effects, such as headache, nausea, vomiting, abdominal pain,
dizziness, confusion, breathing difficulties. Severe cases of overexposure can
result in respiratory failure. May be fatal if swallowed. Toxic if swallowed.
Chronic Health Hazard : This product contains no listed carcinogens according to Directive 67/548/EEC,
IARC, ACGIH and/or NTP in concentrations of 0.1 percent or greater.
Reproductive toxin. Prolonged contact may result in chemical burns and
permanent damage.
Aggravated Medical : Asthma.
Condition Eye disease
Skin disorders and Allergies.
Neurological disorders
Liver disorders
Kidney disorders
Target Organs : Respiratory system.
Skin.
Eyes.
Kidney.
Liver.
Central nervous system.
Bladder
Reproductive hazard.
Symptoms : Repeated and/or prolonged exposure to low concentrations of vapors and/or
aerosols may cause: Sore throat. Irritating to eyes and respiratory system.
Breathing difficulties. Symptoms may be delayed.
4. FIRST AID MEASURES
General advice : Prompt medical attention is required in all cases of overexposure. The potential
for hydrogen fluoride formation exists with every exposure, therefore its toxicity
must also be considered. Seek medical advice. If breathing has stopped or is
labored, give assisted respirations. Supplemental oxygen may be indicated. If
the heart has stopped, trained personnel should begin cardiopulmonary
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
resuscitation immediately.
Eye contact : Hold eyelids apart, initiate and maintain gentle and continuous irrigation until
the patient receives medical care. If medical care is not promptly available,
continue to irrigate for one hour. Seek medical treatment immediately. Trained
personnel should administer 1% calcium gluconate solution by continuous drip.
Skin contact : Immediately remove contaminated clothing, and any extraneous chemical, if
possible to do so without delay. Initiate and maintain gentle and continuous
irrigation until the patient receives medical care. If medical care is not promptly
available, continue to irrigate for one hour. Cover wound with sterile dressing.
With gloved hand apply 2.5% calcium gluconate gel to the burn area.
Alternative treatment is to soak the affected areas in an iced 0.13% water
solution (1:750) of Zephiran?chloride (benzalkonium chloride solution, NF).
Use ice cubes, not shaved ice, to prevent frostbite. If soaking is impractical,
soaks or compresses may be used. (Do not us Zephiran?for burns of the
eye.) If immersion is impractical, soaked compresses of the same solution
should be applied to the area. Immersion or compresses must be used
continuously for two hours. Burns covering an area greater than fifty-two square
centimeters (8 square inches) require immediate treatment by a medical doctor.
Ingestion : If a person vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person. Do not induce
vomiting. Prevent aspiration of vomit. Turn victim's head to the side.
Inhalation : If breathing has stopped or is labored, give assisted respirations.
Supplemental oxygen may be indicated. If the heart has stopped, trained
personnel should begin cardiopulmonary resuscitation immediately. A physician
should be consulted for all exposures. Mouth to mouth resuscitation is not
recommended. In case of shortness of breath, give oxygen. As soon as
possible give 2.5% to 3% calcium gluconate solution by nebulizer. Move to
fresh air.
Notes to physician
Treatment : If pain persists after above topical treatments, it may be necessary to inject 5%
aqueous calcium gluconate beneath, around and into the burn area. This will
more likely be necessary in the treatment of extensive burns or small burns
where treatment has been delayed. Do not use local anesthetics. Resolution of
pain is means to determine effective medical treatment. The patient should be
observed for clinical symptoms of hypocalcemia following ingestion or
inhalation or following extensive burns. Serum calcium, potassium and
magnesium determinations must be performed immediately and periodically to
monitor for hypocalcemia and electrolyte imbalance. EKGs should be done
immediately and periodically to monitor for arrhythmias, hypocalcemia and
hyperkalemia. If additional information is needed call the Air Products'
Emergency Number (Section 1) or consult the Air Products' Safetygram 29
"Treatment Protocol for Hydrofluoric Acid Burns."
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : For smaller fires, use dry chemical or carbon dioxide, do not use water. For
large fires, flood fire area with water from as far as possible, using a protective
barrier and appropriate personal protective equipment.
Carbon dioxide (CO2).
Dry chemical.
Dry sand.
Limestone powder.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Extinguishing media which : Water.
must not be used for safety Alcohol-resistant foam.
reasons
Specific hazards : Incomplete combustion may form carbon monoxide. Fire or intense heat may
cause violent rupture of packages. Flash back possible over considerable
distance. May form explosive mixtures in air. Burning produces obnoxious and
toxic fumes. Reacts violently with water.
Special protective equipment : Use personal protective equipment. Wear self contained breathing apparatus
for fire-fighters for fire fighting if necessary.
Further information : Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use self-contained breathing apparatus and chemically protective clothing.
Remove all sources of ignition. Evacuate personnel to safe areas.
Environmental precautions : Shut off or remove all ignition sources. Construct a dike to prevent spreading.
Prevent spilled product from entering streams or drinking water supplies. Local
authorities should be advised if significant spillages cannot be contained.
Methods for cleaning up : Approach suspected leak areas with caution. Contact Air Products' Emergency
Response Center for advice. Absorb with inert absorbent materials such as:
Dry sand. Vermiculite. Activated charcoal. Polypropylene. Place in appropriate
chemical waste container.
Additional advice : Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous. Protect from water. If possible, stop flow of
product.
7. HANDLING AND STORAGE
Handling
Avoid contact with skin and eyes. Use only in well-ventilated areas. Avoid breathing vapors and/or aerosols.
Avoid contact with eyes. Use personal protective equipment. When using, do not eat, drink or smoke.
Storage
To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of
ignition. Keep in a dry, cool place. Keep away from Oxidizers. Store in an area suitable for water reactive
materials. Minimize exposure to air. Exposure may cause material to degrade. Store under a nitrogen
atmosphere.
Technical measures/Precautions
Keep away from open flames, hot surfaces and sources of ignition.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures
Use explosion-proof equipment.
Provide readily accessible eye wash stations and safety showers.
Provide natural or explosion-proof ventilation adequate to ensure concentrations are kept below exposure limits.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Personal protective equipment
Respiratory protection : Wear appropriate respirator when ventilation is inadequate. Use Air Purifying
Respirator with organic vapor cartridges when exposure is likely.
Hand protection : Polyvinyl Alcohol Gloves (PVA).
Nitrile rubber.
Impervious gloves.
The breakthrough time of the selected glove(s) must be greater than the
intended use period.
Eye protection : Full face shield with goggles underneath.
Chemical resistant goggles must be worn.
Skin and body protection : Impervious clothing.
Full rubber suit (rain gear).
Rubber or plastic boots.
Long sleeve shirts and trousers without cuffs.
Environmental exposure : Shut off or remove all ignition sources. Construct a dike to prevent spreading.
controls Prevent spilled product from entering streams or drinking water supplies. Local
authorities should be advised if significant spillages cannot be contained.
9. PHYSICAL AND CHEMICAL PROPERTIES
Color : Yellow.
Molecular Weight : 130 g/mol
Relative density : 1.01 (water = 1)
Vapor pressure : 18.80 mmHg
Flash point : -4 癈
Autoignition temperature : 321 癈
Upper flammability limit : 7.1 %(V)
Lower flammability limit : 1.1 %(V)
Water solubility : Reacts violently with water.
Reacts violently with water.
10. STABILITY AND REACTIVITY
Stability : Stable under normal conditions.
Conditions to avoid : Heat, flames and sparks. Exposure to moisture.
Materials to avoid : Oxidizing agents.
Humid air.
Water.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Alcohols.
Reacts energetically with water.
Reaction with water or contaminants or excessive heat may result in sufficient
pressure to burst container.
Hazardous decomposition : Carbon monoxide.
products Carbon dioxide (CO2).
Hazardous reactions : Reacts violently with water.
11. TOXICOLOGICAL INFORMATION
Acute Health Hazard
Ingestion : No data is available on the product itself.
Ingestion - Components
Toluene LD50 : 636 mg/kg Species : Rat.
SULFUR, TRIFLUOR [2-METHOXY-N- LD50 : > 50 - < 200 mg/kg Species : Rat.
(2-METHOXYETHYL)
ETHANAMINATO-k N]-,(T-4)
Inhalation : No data is available on the product itself.
Inhalation - Components
Toluene LC50 (4 h) : 49 mg/l Species : Rat.
Skin. : No data is available on the product itself.
Skin. - Components
Toluene LD50 : 12,200 mg/kg Species : Rabbit.
Eye irritation/corrosion : Severe eye irritation.
Acute dermal : Severe skin irritation.
irritation/corrosion
Chronic Health Hazard
Exposure to toluene has been shown to cause adverse effects in the liver, central nervous system, kidney,
bladder and reproductive system.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Aquatic toxicity : No data is available on the product itself.
Toxicity to fish - Components
Toluene EC50 (48 h) : 6.78 mg/l Species : Rainbow
trout (Oncorhynchus
mykiss).
Toxicity to daphnia - Components
Toluene EC50 (48 h) : 6 mg/l Species : Daphnia
Toluene EC50 (48 h) : 6.56 mg/l Species : Daphnia
Toxicity to other organisms : No data available.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Persistence and degradability
Mobility : No data available.
Bioaccumulation : No data is available on the product itself.
Bioaccumulation - Components
Toluene Low bioaccumulation potential.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused : Contact supplier if guidance is required.
products
Contaminated packaging : Dispose of container and unused contents in accordance with federal, state,
and local requirements.
14. TRANSPORT INFORMATION
ADR
Proper shipping name : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (Bis(2-Methoxyethyl)
Aminosulfur Trifluoride, Toluene )
Class : 3 (6.1, 8)
UN/ID No. : UN3286
Packing group : II
ADR/RID Hazard ID no. : 368
IATA
Proper shipping name : Flammable liquid, toxic, corrosive, n.o.s. (Bis(2-Methoxyethyl) Aminosulfur
Trifluoride, Toluene )
Class : 3 (6.1, 8)
UN/ID No. : UN3286
Packing group : II
IMDG
Proper shipping name : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (Bis(2-Methoxyethyl)
Aminosulfur Trifluoride, Toluene )
Class : 3 (6.1, 8)
UN/ID No. : UN3286
Packing group : II
RID
Proper shipping name : FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (Bis(2-Methoxyethyl)
Aminosulfur Trifluoride, Toluene )
Class : 3 (6.1, 8)
UN/ID No. : UN3286
Packing group : II
15. REGULATORY INFORMATION
Labelling according to EEC Directive
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
Hazard symbol : T Toxic
F Highly flammable
C Corrosive.
R-phrase(s) : R11 Highly flammable.
R14 Reacts violently with water.
R20 Harmful by inhalation.
R25 Toxic if swallowed.
R35 Causes severe burns.
R48/20 Harmful: danger of serious damage to health by prolonged exposure
through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapors may cause drowsiness and dizziness.
S-phrase(s) : S16 Keep away from sources of ignition. - No smoking.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Country Regulatory list Notification
USA TSCA Included on Inventory.
EU EINECS Not on Inventory.
Canada DSL Not on Inventory.
Australia AICS Not on Inventory.
Japan ENCS Not on Inventory.
South Korea ECL Not on Inventory.
China SEPA Included on Inventory.
Philippines PICCS Not on Inventory.
16. OTHER INFORMATION
Ensure all national/local regulations are observed.
R-phrase(s) - Components
R11 Highly flammable.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapors may cause drowsiness and dizziness.
R35 Causes severe burns.
R25 Toxic if swallowed.
R 2 Risk of explosion by shock, friction, fire or other sources of ignition.
R14 Reacts violently with water.
Repr.Cat.3 Toxic to Reproduction Category 3
Prepared by : Air Products and Chemicals, Inc. Global EH&S Product Safety Department
For additional information, please visit our Product Stewardship web site at
http://www.airproducts.com/productstewardship/
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
SAFETY DATA SHEET
Version 1.1 MSDS Number 300000006570
Revision Date 26.01.2006 Print Date 26.01.2006
This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to
all countries that have translated the Directives in their national laws.
Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of
this document, no liability for injury or damage resulting from its use canbe accepted.
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Air Products and Chemicals,Inc 50% Deoxo-Fluor# in Toluene
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