MATERIAL SAFETY DATA SHEET
Polyken 1027 Primer
1. PRODUCT AND COMPANY IDENTIFICATION
Polyken 1027 Primer
Product Name
Pipe Corrosion Protection
Product Description
Berry Plastics Corporation, Tapes and Coatings Division
Manufacturer/Supplier
2320 Bowling Green Road
Address
Franklin, Kentucky
(270) 586-3261 (Monday ?Friday 8:00 am to 5:00 pm)
Phone Number
(800) 424-9300
Chemtrec Number
May 16, 2008
Revision Date:
November 15, 2007
MSDS Date:
This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200)
2. HAZARDS IDENTIFICATION
EU Main Hazards
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R45 May cause cancer.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
Routes of Entry
- Absorption - Eye contact - Ingestion - Inhalation - Skin contact
Carcinogenic Status
See Section 11.
Target Organs
Central Nervous System - Skin - Eye - Liver - Kidney - Respiratory System - Reproductive
Health Effects - Eyes
Liquid, mist or vapor may cause pain, transient irritation and superficial corneal effects.
Health Effects - Skin
Material may cause irritation. Repeated or prolonged contact may produce defatting of the skin leading
to irritation and dermatitis. Material can be absorbed through the skin and cause effects similar to
those resulting from inhalation.
Health Effects - Ingestion
Swallowing may have the following effects:
- abdominal pain - vomiting - central nervous system depression - kidney damage - liver damage ?br>
testis damage ?aspiration into the lungs may occur during ingestion or vomiting causing lung damage
A large dose may have the following effects:
- systemic effects similar to those resulting from inhalation
Revision Date: May 16, 2008 Page 1 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
2. HAZARDS IDENTIFICATION
Health Effects - Inhalation
Exposure to vapor may have the following effects:
- irritation of nose, throat and respiratory tract - central nervous system depression - dizziness -
drowsiness - headache - mental confusion
Exposure to vapor at high concentrations may have the following effects:
- nerve damage leading to numbness and muscle weakness - lung damage - liver damage - kidney
damage - testis damage ?adverse reproductive effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS#/Codes Concentration R Phrases Classification
Aliphatic Petroleum Distillate 64742-89-8 60 - 80% R45, R65 T, Xn, Carc Cat. 2
265-192-2
Toluene 108-88-3 5 - 10% R11, R38, R48/20, F, Xn
203-625-9 R63, R65, R67
Carbon Black 1333-86-4 <5% None None
215-609-9
Polymers and Resins N.A. <25% None None
4. FIRST AID MEASURES
Eyes
Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain
medical attention if soreness or redness persists.
Skin
Immediately flood the skin with large quantities of water for at least 15 minutes, preferably under a
shower. Remove contaminated clothing and continue washing. Contaminated clothing should be
washed or dry-cleaned before re-use. Obtain medical attention if blistering occurs or redness persists.
Ingestion
Do not induce vomiting, unless directed to do so by a physician. Have victim drink 1-3 glasses of water
to dilute stomach contents. If there is difficulty in breathing, give oxygen. Obtain medical attention
immediately.
Inhalation
Remove from exposure. If there is difficulty in breathing, give oxygen. Obtain medical attention
immediately.
Advice to Physicians
Treat symptomatically.
5. FIRE- FIGHTING MEASURES
Extinguishing Media
Use foam, dry chemical or carbon dioxide. Be aware of the possibility of re-ignition. Keep containers
and surroundings cool with water spray.
Unusual Fire and Explosion Hazards
Vapors can travel a considerable distance to a source of ignition and flashback. Flashback can occur if
air temperature exceeds flash point. Be aware of possibility of re-ignition.
Protective Equipment for Fire-Fighting
Wear full protective clothing and self-contained breathing apparatus.
Revision Date: May 16, 2008 Page 2 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
6. ACCIDENTAL RELEASE MEASURES
Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for
recovery or disposal. Wear appropriate protective clothing. Eliminate all sources of ignition. Use non-
sparking scoops for flammable materials. Vapors can accumulate in low areas. Consider need for
evacuation. Prevent the material from entering drains or watercourses. Notify authorities if spill has
entered watercourse or sewer or has contaminated soil or vegetation.
7. HANDLING AND STORAGE
Use in well ventilated area. Use local exhaust ventilation. Avoid inhaling vapor. Avoid contact with
eyes, skin and clothing. Keep container tightly closed when not in use.
Store away from sources of heat or ignition. Storage area should be: - cool - dry - well ventilated - out
of direct sunlight ?away form sources of ignition(heat, sparks, flames, pilot lights) - away from
incompatible materials (see Section 10)
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards
Exposure limits are listed below, if they exist.
Toluene
3
ACGIH: TLV 20ppm (75 mg/m ) 8h TWA
OSHA: PEL 200ppm 8h TWA. 300 ppm CEILING, 500 ppm 10-min peak per shift.
Aliphatic Petroleum Distillate
3
ACGIH: TLV 300ppm (1370 mg/m ) 8h TWA (as VM&P naphtha 8032-32-4)
3
OSHA: PEL 500ppm (2000 mg/m ) 8h TWA. (as Petroleum distillates)
Carbon Black
3
ACGIH: TLV 3.5 mg/m 8h TWA
3
OSHA: PEL 3.5 mg/m 8h TWA
Polymers and Resins
None assigned.
Engineering Control Measures
Use engineering methods to prevent or control exposure. Methods include process or personnel
enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions.
Respiratory Protection
Wear respiratory protection if there is a risk of exposure to high vapor concentrations, aerosols or if
applied to hot surfaces. A NIOSH approved full face respirator may be worn. The specific respirator
selected must be based on the airborne concentration found in the workplace and must not exceed the
working limits of the respirator.
Hand Protection
Butyl gloves are recommended.
Eye Protection
Chemical goggles or safety glasses with side shields. Consider the use of a face shield if splashing is
possible.
Body Protection
If there is danger of splashing, wear: - overall or apron
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical State
Black
Color
Light Hydrocarbon
Odor
No data
pH
Revision Date: May 16, 2008 Page 3 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
9. PHYSICAL AND CHEMICAL PROPERTIES
No data
Density (lbs/gal)
No data
Boiling Range/Point (癈/F)
Not applicable
Melting Point (癈/F)
Est. 40 ?50 癋
Flash Point (癋)
No data
Vapor Pressure
Slower than ether
Evaporation Rate
Negligible
Solubility in Water
Heavier than air.
Vapor Density
78.9%
VOC
10. STABILITY AND REACTIVITY
Stability
Stable under normal conditions.
Conditions to Avoid
- Heat, sparks, flames - High temperatures - sources of ignition - contact with incompatible materials
Materials to Avoid
- Strong oxidizing agents - acids - bases - reducing agents - halogens - hydrogen
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products
- oxides of carbon - hydrocarbons ?phenolic vapors ?aldehydes -smoke -fumes
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Toluene: Oral LD50 rat >2,000 mg/kg. Dermal LD50 rabbit >3,000 mg/kg
Chronic Toxicity/Carcinogenicity
Aliphatic Petroleum Distillate (as VM&P naphtha 8032-32-4): ACGIH Carcinogen Category: A3
(Confirmed Animal Carcinogen with Unknown Relevance to Humans)
This product contains carbon black which is classified by IARC as a Group 2B possible human
carcinogen. When encapsulated in the liquid matrix the risk of exposure is reduced.
Genotoxicity
This product is not expected to cause any mutagenic effects.
Reproductive/Developmental Toxicity
Toluene: In laboratory studies, birth defects, increased fetal lethality and delayed fetal development
have been observed in offspring of female animals exposed during pregnancy. Toluene has been
demonstrated to be embryofetotoxic and teratogenic in laboratory animals.
12. ECOLOGICAL INFORMATION
Mobility
No relevant studies identified.
Persistence/Degradability
No relevant studies identified.
Bio-accumulation
No relevant studies identified.
Revision Date: May 16, 2008 Page 4 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toluene: LC50 Fathead minnow (Pimephales promelas) 96 h 26 ppm. EC50 Daphnia magna 48 h
11.5 ppm
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local and national regulations. Labels should not be
removed from containers until they have been cleaned. Do not cut, puncture or weld on or near to the
container. Use non-sparking tools. Do not incinerate closed containers. Empty containers may contain
hazardous residues. Dispose of containers with care.
14. TRANSPORT INFORMATION
Coating Solution (3) UN1139, ll
DOT CFR 172.101 Data
Coating Solution
UN Proper Shipping Name
(3)
UN Class
UN1139
UN Number
ll
UN Packaging Group
Consult current IATA Regulations prior to shipping by air.
Classification for AIR
Transportation (IATA)
15. REGULATORY INFORMATION
EU Label Information
Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC
including amendments(2001/60/EC and 2006/8/EC)
EU Hazard Symbol and Indication of Danger
T- Toxic
F- Flammable
R phrases
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R45 May cause cancer.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
S phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
S45 In case of accident or if you feel unwell, seek medical advice immediately.
S53 Avoid exposure ?obtain special instructions before use.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container
or label.
US REGULATIONS (Federal, State) and INTERNATIONAL CHEMICAL REGISTRATION LAWS
TSCA Listing
All ingredients have been verified for inclusion on the EPA Toxic Substance Control Act Chemical
Substance Inventory.
Revision Date: May 16, 2008 Page 5 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
15. REGULATORY INFORMATION
EINECS Listing
All ingredients in this product have not been verified for inclusion on the European Inventory of
Existing Commercial Chemical Substances (EINECS).
DSL (Canadian) Listing
All ingredients in this product have not been verified for inclusion on the Domestic Substance List
(DSL).
MA Right To Know Law
This product contains the following chemicals found on the Massachusetts Substance List (MSL).
Toluene (108-88-3) 5 -10 %?Methanol (67-56-1) <1% - Xylene (1330-20-7) <1%
PA Right To Know Law
This product contains the following chemicals found on the Pennsylvania Hazardous Substance List:
Carbon black (1333-86-4) < 5% - Toluene (108-88-3) 5 -10 % ?Methanol (67-56-1) <1% - Xylene
(1330-20-7) <1% - Ethylbenzene (100-41-4) <0.1%
NJ Right To Know Law
This product contains the following chemicals found on the NJ Right To Know Hazardous Substance
List: Toluene (108-88-3) 5 -10 % ?Methanol (67-56-1) <1% - Xylene (1330-20-7) <1% - Carbon black
(1333-86-4) < 5%
California Proposition 65
This product contains the following materials which the State of California has found to cause cancer,
birth defects or other reproductive harm: Toluene (108-88-3) - Ethylbenzene (100-41-4) -
Formaldehyde (50-00-0) trace ?Benzene ( 71-43-2)
WHMIS Classification
B2.D2A
This product was classified in accordance with the hazard criteria of the Canadian Controlled
Products Regulations and the MSDS contains all the information required by these regulations.
SARA Title III Sect. 311/312 Categorization
Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard, Fire Hazard
SARA Title III Sect. 313
This product contains a chemical that is listed in Section 313 at or above de minimis concentrations.
The following listed chemicals are present: Toluene (108-88-3)
16. OTHER INFORMATION
NFPA Ratings
NFPA Code for Flammability - 4
NFPA Code for Health - 2
NFPA Code for Reactivity - 0
NFPA Code for Special Hazards ?None
HMIS Ratings
HMIS Code for Flammability - 4
HMIS Code for Health - 2
HMIS Code for Reactivity - 0
HMIS Code for Personal Protection - See Section 8
Abbreviations
N/A: Denotes no applicable information found or available
CAS#: Chemical Abstracts Service Number
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
Revision Date: May 16, 2008 Page 6 of 7
Berry Plastics Corporation Material Safety Data Sheet
Tapes and Coatings Division Polyken 1027 Primer
16. OTHER INFORMATION
NTP: National Toxicology Program
IARC: International Agency for Research on Cancer
R: Risk
S: Safety
msdstechnical@berryplastics.com
For further Information email:
EnviroNet LLC.
Prepared By:
The information and recommendations presented in this MSDS are based on sources believed to be
accurate Berry Plastics Corporation, Tapes and Coatings Division assumes no liability for the accuracy
or completeness of this information. It is the user's responsibility to determine the suitability of the
material for their particular purposes. In particular, we make NO WARRANTY OF
MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such
information, and we assume no liability resulting from its use. Users should ensure that any use or
disposal of the material is in accordance with applicable Federal, State, and local laws and
regulations.
Revision Date: May 16, 2008 Page 7 of 7
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