EMERGENCY PHONE: 1-800-424-9300 Chemtrec
INTERNATIONAL TRANSPORTATION ACCIDENTS: 1-703-527-3887 Chemtrec
I. CHEMICAL PRODUCT IDENTIFICATION
Product Name : 791WH White Strippable Booth Coating
03/18/08
Date Printed :
03/18/08
Revision Date : Revision Number : 3
Supercedes : 03/18/02 CHEMCO INFO:800-323-0431 WWW.CHEMCOMFG.COM
II. COMPOSITION/INFORMATION ON INGREDIENTS - (EXPOSURE LIMITS - SEE SECTION VIII)
INGREDIENT NAME CAS # %
Toluene 108-88-3 30.01 - 40.00
Acetone 67-64-1 30.01 - 40.00
Chlorinated paraffins 63449-39-8 5.01 - 10.00
Methyl ethyl ketone 78-93-3 1.01 - 5.00
Methanol 67-56-1 1.01 - 5.00
Isophorone 78-59-1 1.01 - 5.00
Propylene Oxide 75-56-9 0.10 - 1.00
If ingredient percentages do not total 100%, the balance is due to rounding or applies to ingredient(s) deemed nonhazardous under 29 CFR 1910.1200 (Hazard Communication Standard).
III. HAZARDS IDENTIFICATION
HMIS
2*
HEALTH
3
FLAMMABILITY
0
REACTIVITY
0 = Least 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Effects
Routes of Entry: Inhalation, Skin contact, Eye contact, Absorption, Ingestion.
Kidney disease, Skin disease including eczema and sensitization, Eye disease, Respiratory disease
Medical Conditions Aggravated:
including asthma and bronchitis, Skin allergies, Digestive tract disease, Liver disease.
Immediate (Acute) Health Effects:
Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.
Inhalation:
Harmful if inhaled. Harmful. Can cause systemic damage, see target organs below.High
concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness, and
even death with longer exposure.
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage.
Skin Contact:
Can cause severe irritation. Eye contact may result in corneal injury. Symptoms may include
Eye Contact:
discomfort or pain, excess blinking and tear production, with marked redness and swelling of the
conjunctiva. Temporary vision impairment (cloudy or blurred vision) is possible. Irritating and may
injure eye tissue if not removed promptly.
May cause irritation and minor systemic damage. Harmful if absorbed through the skin. Contains
Skin Absorption:
Methanol. May cause deterioration of the optic nerve if absorbed through the skin in large amounts.
Toxic if swallowed. May cause target organ failure and/or death. Can cause abdominal discomfort,
Ingestion:
nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis.
Nervous System, Heart, Kidneys, Respiratory System, Skin, Eyes, Liver, Digestive Tract.
Target Organ Acute Toxicity:
Long-Term (Chronic) Health Effects:
Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness,
Inhalation:
weakness, fatigue, nausea and headache. Prolonged or repeated inhalation may cause kidney and lung
damage. Repeated or prolonged inhalation may cause toxic effects.
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 1 of 5
Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not
Skin Contact:
likely to cause permanent damage.
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may result in corneal
Eye Contact:
injury. Symptoms may include discomfort or pain, excess blinking and tear production, with marked
redness and swelling of the conjunctiva. Temporary vision impairment (cloudy or blurred vision) is
possible.
Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause severe
Skin Absorption
irritation and systemic damage. Contains methanol. Upon prolonged or repeated exposure, may cause
deterioration of the optic nerve if large quantities are absorbed through the skin. Repeated absorption
of large quantities may lead to blindness
IARC: Yes NTP: Yes OSHA: No
Carcinogenicity:
Respiratory System, Nervous System, Heart, Kidneys, Skin, Eyes, Digestive Tract, Liver.
Target Organ Chronic Toxicity:
NOTICE - Reports have associated repeated and prolonged occupational overexposure to solvents with
brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal.
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
Inhalation:
breathing, give artificial respiration. Get medical attention immediately.
Immediately flush eyes with plenty of luke warm water for at least 20 minutes retracting eyelids often.
Eyes:
Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention and monitor the eye daily as advised by your physician.
Immediately flush with water for 15 minutes. Wash the contaminated skin with soap and water. If
Skin Contact:
irritation develops, call a physician.
Seek medical advice immediately. Provide ingredients information from Section II of this MSDS to
Ingestion:
the medical care provider. Contact your local Poison Control Center (listed in the telephone book), or
dial the local "Emergency" (911) number for additional information. Do not induce vomiting unless
instructed to do so by a physician or other competent medical personnel. Never give anything by
mouth to an unconscious person.
Acute massive exposure to toluene can cause transient hematuria and albuminuria. Cardiac
Notes to M.D.
arrhythmias can occur after massive inhalation.
V. FIRE FIGHTING MEASURES
Extremely Flammable
Flammability Summary:
-20 ?C; -4 ?F
Flash Point:
465 ?C; 869 ?F
Autoignition Temperature:
Autoignition Temperature:
0.8 7.0
Lower Flammable/Explosive Limit, % in air: Upper Flammable/Explosive Limit, % in air:
Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash
Fire Hazards:
point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and
flash back This product, when dried or cured, may support combustion when subjected to sources of
ignition or heat in sufficient amount.
Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog
Extinguishing Media:
may also be effective for extinguishing if swept across the base of the fire. Water can also be used to
absorb heat and keep exposed material from being damaged by fire.
Do not enter fire area without proper protection including self-contained toxic breathing apparatus and
Fire Fighting Instructions:
full protective equipment. Fight fire from a safe distance and a protected location due to the potential of
hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 2 of 5
than water and burn while floating on the surface. Use water spray/fog for cooling. Do not point solid
water stream directly into burning oil to avoid spreading.
Carbon dioxide, Carbon monoxide, Phosgene.
Hazardous Combustion Products:
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be severely irritating or toxic. Follow personal protective
Health Consideration for Spill Response:
equipment recommendations found in Section VIII of this MSDS. Personal protective equipment needs
must be evaluated based on information provided on this sheet and the special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,
and the expertise of employees in the area responding to the spill. Never exceed any occupational
exposure limits. Evaporation of volatile substances can lead to the displacement of air creating an
environment that can cause asphyxiation.
Spill Mitigation Procedures:
Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so.
General Methods:
Wear complete and proper personal protective equipment following the recommendation of Section
VIII at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a
sealed container pending a waste disposal evaluation. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area.
Ventilate the area by opening door and/or turning on fans and blowers.
Air Release:
Avoid runoff into storm sewers and ditches that lead to waterways. If runoff occurs, notify proper
Water Release:
authorities as required, that a spill has occurred.
Do not flush to sewer.
Land Spills:
VII. HANDLING AND STORAGE
Harmful or irritating; avoid overexposure to the material. Use only in a well ventilated area. Use spark-
Handling:
proof tools and explosion-proof equipment.
Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep
Storage:
container(s) closed when not in use. Keep away from sources of ignition.
VIII. ENGINEERING CONTROLS, PERSONAL PROTECTIVE EQUIPMENT, AND EXPOSURE LIMITS
Local exhaust ventilation, process enclosures, or other engineering controls are important when
Engineering Controls:
handling or using this product to avoid overexposure. Facilities storing or using this material should be
equipped with an eyewash and safety shower. Vapor concentrations should be monitored and
controlled in accordance with 29 CFR 1910.1000.
Protective Equipment:
If general or local exhaust ventilation is not available or sufficient to reduce exposure to below
Respiratory Tract:
acceptable levels, then respiratory protection is required to avoid overexposure when handling this
product.
Wear safety glasses with side shields when handling this product. When the possibility exists for eye
Eyes:
contact with splashing or spraying liquid, or airborne material, wear additional eye protection such as
chemical splash goggles and/or face shield. Do not wear contact lenses. Have an eye wash station
available.
Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals.
Skin:
Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water
before eating, drinking, and when leaving work. Do not wear surgical style latex gloves except to
protect against incidental contact with the material. Use impervious gloves.
Wear chemically resistant gloves and apron. (Consult your safety equipment supplier).
Protective Clothing:
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 3 of 5
CHEMICAL NAME CAS ACGIH TLV OSHA PEL IDLH
#
Toluene 108-88-3 50 ppm TWA 200 ppm TWAC 300 ppm 500 ppm IDLH
Acetone 67-64-1 500 ppm TWA750 ppm STEL 1000 ppm TWA; 2400 mg/m3 TWA 2500 ppm IDLH (lower explosive level)
Chlorinated paraffins 63449-39-8 No TLV No PEL established Not determined.
Methyl ethyl ketone 78-93-3 200 ppm TWA300 ppm STEL 200 ppm TWA; 590 mg/m3 TWA 3000 ppm IDLH
Methanol 67-56-1 200 ppm TWA250 ppm STEL 200 ppm TWA; 260 mg/m3 TWA 6000 ppm IDLH
Isophorone 78-59-1 No TLVC 5 ppm 25 ppm TWA; 140 mg/m3 TWA 200 ppm IDLH
Propylene Oxide 75-56-9 (20 ppm) TWA 100 ppm TWA; 240 mg/m3 TWA Potential NIOSH carcinogen.
IX. PHYSICAL DATA
White Liquid.
Appearance:
White
Color:
Hydrocarbon Mild
Odor:
N/A
pH:
Not Determined.
Octanol/Water Coeff:
Partial.
Solubility in Water:
Heavier than air. Vapors that evolve from this product will tend to settle and accumulate near the floor.
Vapor Density:
Faster than n-Butyl acetate.
Evaporation Rate:
0.943 / 7.87 Lbs./Gl.
Specific Gravity/Density:
4.9 Lbs/Gl less water & 588 g/l less water & 3.1 Lbs/Gl as
V.O.C.
exempt solvent; exempt solvent; packed
The VOC content is determined by using a percent solids basis, less water and exempt solvents, for adhesives, coatings and inks and the calculations of EPA
Reference Method 24 or equivalent ASTM method approved by the executive office.
The Federal EPA has delisted Acetone as a VOC. Even though this product contains Acetone (see Section II), the VOC listed above does not include Acetone
in the VOC calculation. Individual states may have other regulations. Please check with your state.
56 ?C; 133 ?F
Initial Boiling Point:
N/A
Initial Freezing Point:
X. STABILITY AND REACTIVITY
Stable under normal conditions.
Stability Information:
Sparks, open flame, other ignition sources, and elevated temperatures.Contamination., High
Conditions to Avoid:
temperatures
Strong acids, Strong oxidizing agents.
Chemical Incompatibility:
Carbon dioxide, Carbon monoxide, Chlorine containing gases, Phosgene.
Hazardous Decomposition Products:
XI. TOXICOLOGICAL INFORMATION
Chemical Name LD50/LC50
Toluene Inhalation LC50 Mouse : 5320 ppm/8H; Oral LD50 Rat : 5000 mg/kg; Dermal LD50 Rabbit : 14 g/kg
Acetone Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44 gm/m3/4H; Oral LD50 Rat : 5800 mg/kg;
Oral LD50 Mouse : 3 gm/kg
Paraffin waxes and hydrocarbon waxes, Oral LD50 Rat : >21500 uL/kg; Dermal LD50 Rabbit : >10 mL/kg
chlorinated
2-Butanone Inhalation LC50 Rat : 23500 mg/m3/8H; Inhalation LC50 Mouse : 32 gm/m3/4H; Oral LD50 Rat : 2737 mg/kg;
Oral LD50 Mouse : 4050 mg/kg; Dermal LD50 Rabbit : 6480 mg/kg
Methanol Inhalation LC50 Rat : 64000 ppm/4H; Oral LD50 Rat : 5628 mg/kg; Oral LD50 Mouse : 7300 mg/kg; Dermal
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 4 of 5
LD50 Rabbit : 15800 mg/kg
2-Cyclohexen-1-one, 3,5,5-trimethyl- Oral LD50 Rat : 1870 mg/kg; Oral LD50 Mouse : 2690 mg/kg; Dermal LD50 Rabbit : 1500 uL/kg
Propane, 1,2-epoxy- Inhalation LC50 Rat : 4000 ppm/4H; Inhalation LC50 Mouse : 1740 ppm/4H; Oral LD50 Rat : 380 mg/kg; Oral
LD50 Mouse : 440 mg/kg; Dermal LD50 Rabbit : 1500 uL/kg
XII. ECOLOGICAL INFORMATION
Care should be taken to minimize releases of any industrial chemicals to the environment.
Overview:
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Spent Product:
Information in this MSDS is provided only as a guide. Consult with competent authority to determine
Disposal Methods:
proper waste disposal procedures. Clean up and dispose of waste and clean-up materials in accordance
with all federal, state, and local environmental regulations.
D001, .
Potential EPA Waste Codes:
Some Components Possibly Subjected to USEPA Land Disposal Restrictions:
When disposing of unused products or any waste, the preferred options are to send to a licensed reclaimer or to permitted incinerators. There may be some other ingredients subject to LDR categories.
Toluene 108-88-3
Acetone 67-64-1
Methyl ethyl ketone 78-93-3
Methanol 67-56-1
XIV. TRANSPORTATION INFORMATION
Agency Basic Description and Label
Paint Related Material, 3, UN1263, PG II; Label Required: Flammable Liquid.
DOT
Hazardous Substance
Toluene final RQ = 1000 pounds (454 kg); also listed as Benzene, methyl-
Acetone final RQ = 5000 pounds (2270 kg); also listed as 2-Propanone
Ethyl methyl ketone final RQ = 5000 pounds (2270 kg); also listed as 2-Butanone; also listed as Ethyl methyl ketone
Methanol final RQ = 5000 pounds (2270 kg); also listed as Methyl alcohol
Isophorone final RQ = 5000 pounds (2270 kg)
Propylene oxide final RQ = 100 pounds (45.4 kg)
XV. REGULATORY INFORMATION
Regulation
SARA 313 Reportable : Toluene, Methyl ethyl ketone, Methanol, Propylene oxide
TSCA Inventory : All components of this product are listed in, or exempt from, the TSCA 8(b) Inventory.
M.S.D.S. Reportable HAP(s) : Toluene, Methyl ethyl ketone (2-Butanone), Methanol, Isophorone, Propylene oxide.
California Proposition 65 : The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986 -
Proposition 65: "WARNING: This product contains chemical(s) known to the State of California to cause cancer and/or birth
defects."
SARA/CERCLA Section 302 : Propylene oxide TPQ = 10,000 pounds; RQ = 100 pounds (does not meet toxicity criteria
but because of high production volume and recognized toxicity is
considered a chemical of concern)
XVI. ADDITIONAL INFORMATION
Major References: VENDOR'S MSDS's, PAINT & COATINGS HANDBOOK, EPA's LIST OF LISTS, AND OTHER PUBLISHED MATERIALS.
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, THEY ARE
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION, OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED
HERE ARE GIVEN GRATIS. NO OBLIGATIONS NOR LIABILITIES FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED
AT YOUR RISK.
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 5 of 5
|