MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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880-001
Product number
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Product name Gel Vandal Mark Remover
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24-Nov-2009
Effective date
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Sprayway, Inc.
Claire Manufacturing Co.
Company information
500 Vista Ave.
484
Addison, IL 60101 United States
United States
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General Assistance 630-543-7600
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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04
Version #
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12-Mar-2008
Supersedes date
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2. Hazards Identification
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EXTREMELY FLAMMABLE. VAPOR HARMFUL.
Emergency overview
CONTENTS UNDER PRESSURE. Aerosol. Will be easily ignited by heat, spark or
flames. Irritating to skin. Irritating to eyes. Irritating to respiratory system. Prolonged
exposure may cause chronic effects.
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Potential health effects
Skin contact. Ingestion. Inhalation.
Routes of exposure
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Causes eye irritation.
Eyes
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This product may be harmful if it is absorbed through the skin. Irritating to skin.
Skin
Prolonged or repeated contact can result in defatting and drying of the skin which may
result in skin irritation and dermatitis (rash).
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
Irritating to respiratory system. Prolonged inhalation may be harmful.
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Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage.
Ingestion
Components of the product may be absorbed into the body by ingestion.
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Kidney.
Target organs
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
repeated and prolonged and may cause blood damage. These effects have not been
observed in humans.
Blood. Central nervous system. Liver. Lungs.
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Unconsciousness. Liver injury may occur. Kidney injury may occur. May cause central
Chronic effects
nervous system disorder (e.g., narcosis involving a loss of coordination, weakness,
fatigue, mental confusion, and blurred vision) and/or damage. May cause delayed lung
damage.
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Discomfort in the chest. Narcosis. Cyanosis. Liver enlargement. Jaundice. Defatting of
Signs and symptoms
the skin. Irritation.
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3. Composition / Information on Ingredients
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Components CAS # Percent
Toluene 108-88-3 20 - 30
Propane 74-98-6 10 - 15
n-Butane 106-97-8 8 - 10
Acetone 67-64-1 5-8
2-Butoxyethanol 111-76-2 3-5
Diethylene Glycol Monobutyl Ether 112-34-5 3-5
9-Octadecenoic Acid 112-80-1 1-3
Non-hazardous and other components below reportable levels 20 - 40
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops or persists.
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Remove and isolate contaminated clothing and shoes. Wash off with warm water and
Skin contact
soap. Get medical attention if irritation develops or persists.
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Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, get medical
Inhalation
attention.
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If material is ingested, immediately contact a poison control center. Rinse mouth. Do not
Ingestion
induce vomiting without advice from poison control center. If vomiting occurs naturally,
have victim lean forward to reduce risk of aspiration. Do not use mouth-to-mouth method
if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device.
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5. Fire Fighting Measures
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Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may
Flammable properties
cause fire or explosion hazard.
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Extinguishing media
Water fog. Foam. Dry chemical. Carbon dioxide (CO2).
Suitable extinguishing media
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Protection of firefighters
Fire may produce irritating, corrosive and/or toxic gases.
Specific hazards arising from
the chemical
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In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
Protective equipment and
including helmet, self-contained positive pressure or pressure demand breathing
precautions for firefighters
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into
waterways, sewers, basements or confined areas.
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Should not be released into the environment. Use a non-combustible material like
Methods for cleaning up
vermiculite, sand or earth to soak up the product and place into a container for later
disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Use only in area provided with
appropriate exhaust ventilation. Do not use if spray button is missing or defective. Do not
get this material in contact with eyes. Do not get this material in contact with skin. Wear
personal protective equipment. Avoid prolonged exposure.
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Level 2 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Keep away from heat, sparks, and
flame. Avoid exposure to long periods of sunlight. Store in cool place. Keep in an area
equipped with sprinklers. Keep out of the reach of children. Do not store, incinerate, or
heat this material above 120 degrees Fahrenheit.
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Toluene 108-88-3 20 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
n-Butane 106-97-8 1000 ppm Not established Not established
Acetone 67-64-1 500 ppm 750 ppm Not established
2-Butoxyethanol 111-76-2 20 ppm Not established Not established
Diethylene Glycol Monobutyl 112-34-5 20 ppm Not established Not established
Ether
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OSHA
Components CAS # TWA STEL Ceiling
Toluene 108-88-3 200 ppm Not established 300 ppm
Propane 74-98-6 1000 ppm Not established Not established
Acetone 67-64-1 1000 ppm Not established Not established
2-Butoxyethanol 111-76-2 50 ppm Not established Not established
Diethylene Glycol Monobutyl 112-34-5 100 ppm Not established Not established
Ether
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant
Skin protection
clothing.
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Wear positive pressure self-contained breathing apparatus (SCBA). If permissible levels
Respiratory protection
are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied
respirator.
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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179.6 癋 (82.2 癈) estimated
Boiling point
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Tan.
Color
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20.727 kJ/g estimated
Flammability (HOC)
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Yes
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Solvent.
Odor
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12.42 - 13.42
pH
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Liquid.
Physical state
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60 - 75 psig @ 70F
Pressure
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Partially
Solubility
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0.8229 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Risk of ignition. Instability caused by elevated temperatures. May form explosive
Chemical stability
peroxides.
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Heat, flames and sparks.
Conditions to avoid
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Hazardous decomposition products Irritants. Toxic gas. May include oxides of nitrogen.
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11. Toxicological Information
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Acute LD50: 4005 mg/kg estimated, Rat, Dermal
Acute effects
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
2-Butoxyethanol 111-76-2 Inhalation LC50 Rat 2.21 mg/L 4 h; Inhalation LC50 Rat 450 ppm 4 h; Oral LD50 Rat
470 mg/kg; Dermal LD50 Rat 2270 mg/kg; Dermal LD50 Rabbit 220 mg/kg
9-Octadecenoic Acid 112-80-1 Oral LD50 Rat 25 g/kg
Acetone 67-64-1 Oral LD50 Rat 5800 mg/kg
Diethylene Glycol Monobutyl Ether 112-34-5 Oral LD50 Rat 3384 mg/kg; Dermal LD50 Rabbit 2700 mg/kg
n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h
Propane 74-98-6 Inhalation LC50 Rat 658 mg/L 4 h
Toluene 108-88-3 Inhalation LC50 Rat 12.5 mg/L 4 h; Inhalation LC50 Rat >26700 ppm 1 h; Oral LD50
Rat 636 mg/kg; Dermal LD50 Rabbit 8390 mg/kg; Dermal LD50 Rat 12124 mg/kg
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
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12. Ecological Information
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Components of this product are hazardous to aquatic life.
Ecotoxicity
LC50 91.39 mg/L estimated, Fish, 96.00 Hours,
EC50 40.7 mg/L estimated, Daphnia, 48.00 Hours,
IC50 11587 mg/L estimated, Algae, 72.00 Hours,
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
D018: Waste Benzene
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Contents under pressure. Dispose of this material and its container at hazardous or
Disposal instructions
special waste collection point. Do not incinerate sealed containers. Do not allow this
material to drain into sewers/water supplies. If discarded, this product is considered a
RCRA ignitable waste, D001. Dispose in accordance with all applicable regulations.
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
5F
Item
None
Labels required
2
Transport Category
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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IATA
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1
Labels required
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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
2-Butoxyethanol 111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
Diethylene Glycol Monobutyl Ether 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
Toluene 108-88-3 1.0 % de minimis concentration
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
Toluene: 1000.0000
Acetone: 5000.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of New and Existing Chemicals (EINECS) Yes
Europe European List of Notified Chemical Substances (ELINCS) Yes
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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WARNING: This product contains a chemical known to the State of California to cause
State regulations
cancer and birth defects or other reproductive harm.
U.S. - Pennsylvania - RTK (Right to Know) List
2-Butoxyethanol 111-76-2 Present
9-Octadecenoic Acid 112-80-1 Present
Acetone 67-64-1 Environmental hazard
Diethylene Glycol Monobutyl Ether 112-34-5 Environmental hazard
n-Butane 106-97-8 Present
Propane 74-98-6 Present
Toluene 108-88-3 Environmental hazard
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16. Other Information
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HMIS?is a registered trade and service mark of the NPCA.
Further information
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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Health: 2*
HMIS?ratings
Flammability: 3
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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This document has undergone significant changes and should be reviewed in its entirety.
MSDS sections updated
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Regulatory Compliance
Prepared by
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Product #: 880-001 Vandal Mark Remover
Revision date: 24-NOV-2009 Print date: 24-NOV-2009
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