MATERIAL SAFETY DATA SHEET
SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Company Name Phone Number CHEMTREC
Nu-Calgon Wholesaler, Inc. (314) 469-7000 / (800) 554-5499 (800) 424-9300
Street Address City State Postal Code Last Update
2008 Altom Court St. Louis MO 63146-4151 5/24/10
Product Name Product Number Product Use EPA Registration #
Pan-Spray Black 4296-51 Seal cracks in condensate pan. N/A
SECTION 2 ?COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients % By Wt. CAS Number TLV PEL
XYLENE 1330-20-7 100 100
TOLUENE 108-88-3 50 100
N-HEXANE 110-54-3 50 500
SILICA, AMORPHOUS 7631-86-9 10 80
SILICA 66402-68-4 10 10
METHYL ACETATE 79-20-9 200 200
N-TALLOWALKYL 61791-53-5 N/A N/A
TRIMETHYLENEDIAMINE OLEATE
POLYBUTADIENE-CO-STYRENE 9003-55-8 N/A N/A
LIQUIFIED PETROLEUM GAS 68476-86-8 800 800
SECTION 3 ?HAZARD IDENTIFICATION
Emergency Overview: This product is classified as a hazardous substance and as dangerous goods according to the classification criteria of NOHSC and
ADG Code (Australia). Warning! Contents under pressure! Highly flammable liquid and vapor! Vapor may cause flash fire! Keep away from heat, sparks,
and open flames. Do not puncture or incinerate. Do not store above 130癋. Use only with adequate ventilation. Keep containers closed when not in use. Keep
away from children.
Potential Health Effects
Eyes: Possible irritation. Symptoms of Exposure: Stinging or burning sensation, redness, and watering.
Skin: Possible irritation and dermatitis (rash). Symptoms of Exposure: Possible irritation and dermatitis (rash), characterized by red, dry, itching skin.
Ingestion: Possible toxic effects. Harmful or fatal if swallowed. Symptoms of Exposure: Gastrointestinal discomfort, nausea, vomiting, and headache.
Inhalation: Upper respiratory irritation from sprays or mists. Symptoms of Exposure: Upper respiratory irritation from sprays or mists may cause coughing,
sneezing, and possible pulmonary injury.
Chronic Exposure: SKIN: Possible irritation and dermatitis (rash). May aggravate an existing dermatitis condition. INHALATION: Prolonged
overexposure of aspirated product may cause adverse effects to the lungs, blood-forming, and cardiovascular systems. Reports have associated repeated and
prolonged overexposure with possible pulmonary injury.
Carcinogenicity: None.
Medical Conditions Aggravated be Exposure: Frequent or prolonged contact may irritate and cause dermatitis.
SECTION 4 ?FIRST AID MEASURES
Eyes: Flush eyes thoroughly with copious amounts of water for at least 20 minutes, holding eyelids open to ensure complete flushing. Seek immediate
medical attention.
Skin: Remove contaminated clothing and wash affected areas with soap and water. If irritation persists, seek prompt medical attention. Launder clothing
before reuse.
Ingestion: Do not induce vomiting. Call a physician or poison control center for assistance and instructions. Seek immediate medical attention. If vomiting
occurs spontaneously, keep victim's head lowered (forward) to reduce the risk of aspiration.
Inhalation: Remove victim to fresh air at once. If breathing is difficult, provide supplemental oxygen. If breathing has stopped, provide artificial respiration.
Seek immediate medical attention. Provide supportive treatment, keeping victim warm and quiet.
SECTION 5 ?FIREFIGHTING MEASURES
Flash Point: Level 3 Aerosol癈 / Level 3 Aerosol癋
Autoignition Temp: ND癈 / ND癋
Hazardous Products of Combustion: No Data.
Flammable Limits in Air: No Data.
Extinguishing Media: Dry chemical, halon, alcohol foam, and indirect water spray or fog.
Fire and Explosion Hazards: Explosion Hazard! This product releases flammable vapors at well below ambient temperatures and readily forms flammable
mixtures with air exposed to an ignition source. It will burn in the open or be explosive in confined spaces. Its vapors are heavier than air and may travel long
distances to a point of ignition, an the flash back. Alkaline/Chlorine gas mixtures have produced explosions. Warning! Contents under pressure! Highly
flammable liquid and vapor! Vapor may cause flash fire! Aerosol containers subjected to high heat may explode or rupture and become projectiles. Vapor is
heavier than air. Flashback is possible.
Special Firefighting Procedures: Gas fires should not be extinguished unless the gas flow can be stopped immediately. Allow the fire to burn itself out.
Keep containers cool until well after the fire is out. Prevent runoff from fire control or dilution from entering sewers, drains, drinking water supply, or any
natural waterway. Firefighters should wear full-face, self-contained breathing apparatus (MSHA/NIOSH approved or the equivalent) and impervious
clothing.
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
Spill or Leak: Secure spill area, remove or minimize all sources of ignition, and maximize ventilation. Stop spill or leak at source if safely possible. Deny
entry to all unprotected individuals. Individuals involved in the cleanup must wear appropriate personal protective equipment. Recover free liquid or cover
with inert absorbent material and place into appropriate container(s) for disposal. If necessary, dike well ahead of the spill to prevent runoff into drains,
sewers or any natural waterway or drinking supply. Contact appropriate local and/or provincial authorities for assistance and/or reporting requirements.
SECTION 7 ?HANDLING AND STORAGE
Handling Procedures and Equipment: Use normal hygiene practices. Avoid breathing vapors. Avoid direct skin contact. Wash hands thoroughly after
using this product and before eating, drinking, or smoking. Readily available emergency fire, first aid, and spill response equipment and/or measures are
highly recommended.
Storage Requirements: Use and store in a cool, dry, well-ventilated area. Keep away from excessive heat, open flames, sparks, and other possible sources of
ignition. Contents under pressure. This product will become dangerously flammable at temperatures above 40?C. Do not store in unmarked containers or
storage devices.
SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: A respiratory protection program that meets ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a
respirators use. Odor is not an adequate warning of potentially hazardous concentrations in air. Releases of these gasses may cause a flammable atmosphere
with explosion potential.
Eye Protection: Splash goggles and a face shield are recommended.
Protective Clothing: Where contact is likely, impervious gloves are recommended. Do not wear rings, watches, or jewelry that could entrap the material
against the skin.
Exposure Guidelines: No Data.
Specific Engineering Controls (such as ventilation, enclosed process): General mechanical ventilation and local exhaust is required for use with this
product. Where Carbon Monoxide may be generated, special ventilation may be required.
SECTION 9 ?PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Black rubber coating Freezing Point: No Data.癈/No Data.癋 % Volatile by Weight: No Data.%
Color: Black rubber coating Vapor Density [air =1]: 0.89 Evaporation Rate: NE
Odor: Mild odor Vapor Pressure: 20癈: Heavier than air Specific Gravity: No Data.
Boiling Point: No Data.癈/No Data.癋 Solubility in Water: NIL pH (concentrate): No Data.
SECTION 10 ?STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Reactive Conditions to avoid: Open flames, sparks, high heat, and close proximity to incompatible substances. Temperatures above 130?F.
Decomposition Products: Oxides of carbon, sulfur, nitrogen, phosphorous, and other organic compounds.
SECTION 11 ?TOXICOLOGICAL INFORMATION
LD 50 of Ingredient LC50 of Ingredient
Hazardous Ingredients CAS # EINECS #
(Specify Species) (Specify Species)
Prolonged overexposure to solvents may
cause adverse effects to the liver, urinary,
blood-forming, cardiovascular, and
reproductive systems. Reports have
associated repeated and prolonged
overexposure to solvents with permanent
brain and nervous system damage.
SECTION 12 ?ECOLOGICAL INFORMATION
Hazardous Ingredients Aquatic Toxicity Data
The manufacturer has not reported any detailed studies on the environmental fate of the material. However,
prudent practice would dictate the material not be allowed to enter the environment.
The manufacturer has not reported any plant or animal effects.
This product, containing petroleum solvents, is expected to be harmful to aquatic life.
SECTION 13 ?DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose of in accordance with federal & provincial hazardous waste laws. Consult local authorities for proper waste disposal procedures.
Empty de-pressurized containers can not be reused. Cans which are pressurized or contain liquid must be disposed of in a permitted waste management
facility. Consult Federal, State, and local disposal authorities for approved procedures.
SECTION 14 ?TRANSPORTATION INFORMATION
Special Shipping Information: No Data.
Purview Proper Shipping Name UN Number Packing Group Hazard Class
CONSUMER COMMODITY, ORM-D No Data. No Data. ORM-D
DOT
(Land)
AEROSOLS UN1950 No Data. No Data.
IMO
(Water)
No Data. No Data. No Data. No Data.
ICAO
(Air)
SECTION 15 ?REGULATORY INFORMATION
WHMIS Classification: (Workplace A, B1, B2, D2B
Hazardous Material Information System)
SARA Title III: (Superfund Amendments & This product contains:
Reauthorization Act) TOLUENE (CAS# 108-88-3)- Acute, Flammable.
N-HEXANE (CAS# 110-54-3); Immediate, delayed, fire. N-Hexane is subject to the reporting
requirements of Section 313 of SARA Title III
and 40 CFR Part 373.
LIQUIFIED PETROLEUM GAS (CAS# 64876-86-8); Immediate, fire
SARA Threshold Planning Quantity:
TOLUENE (CAS# 108-88-3) 1000 LBS RQ; TOLUENE (CAS# 108-88-3) No TPQ
OSHA: (Occupational Safety & Health No Data.
Administration)
TSCA: (Toxic Substance Control Act) All chemical substances of this product are listed on the TSCA inventory or are otherwise exempt from
inventory status.
VOC: (volatile Organic Compounds) Maximum Incremental Reactivity (MIR) 64%
CPR: (Canadian Controlled Products This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations) Regulations.
EINECS: (European Inventory of Existing All ingredients are listed.
Commercial Chemical Substances)
DSL / NDSL: (Canadian Domestic Substance The components of this product are listed on the DSL/NDSL. None of the components of this product
List)(Non-Domestic Substance List) are listed on the priorities substances list.
CERCLA: (Comprehensive Response XYLENE (CAS# 1330-20-7); 1000 Lbs final RQ
Compensation & Liability Act) N-HEXANE (CAS# 110-54-3): 5000 lb final RQ
IDL: (Canadian Ingredient Disclosure List) No Data.
NFPA (HMIS) Rating: (Hazardous Materials HEALTH: 2
Identification System) FLAMMABILITY: 4
REACTIVITY: 0
PERSONAL PROTECTION: B
SECTION 16 ?OTHER INFORMATION
TOLUENE (CAS# 108-88-3);
Listed as a Hazardous Substance under the CWA.
Listed as a Priority Pollutant under the Clean Water Act.
Listed as a Toxic Pollutant under the Clean Water Act.
N-HEXANE (CAS# 110-54-3);
Listed as a hazardous air pollutant (HAP).
Xylene (CAS# 1330-20-7), can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania,
Minnesota, and Massachusetts. WARNING: This product contains Xylene, a chemical known to the state of California to cause birth
defects or other reproductive harm.
TOLUENE (CAS# 108-88-3), can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania,
Minnesota, and Massachusetts. WARNING: This product contains Toluene, a chemical known to the state of California to cause birth
defects or other reproductive harm.
N-HEXANE (CAS# 110-54-3), can be found on the following state right to know lists: New Jersey, Pennsylvania, Minnesota, and
Massachusetts. California no significant risk level.
SILICA, AMORPHORUS (CAS# 7631-86-9), can be found on the following state right to know lists: California, New Jersey, Pennsylvania,
Minnesota, and Massachusetts. California no significant risk level.
The information contained herein is based on the data available to us and is believed to be correct. However, Nu-Calgon Wholesaler Inc. makes no warranty,
expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu-Calgon Wholesaler Inc. assumes no liability
for injury from the use of the product described herin.
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