Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Material Name Toluene
:
Recommended Uses : Raw material for use in the chemical industry.Solvent.
Other names : Methyl benzol TOLUENE
Product Code : T1402, Q9138, Q9131, Q9250, Q9300, Q9308, X211H
Supplier : The Shell Company of Australia Ltd.
ABN: 46 004 610 459
Shell Chemicals
8 Redfern Road
Hawthorn East VIC 3123
Australia
Telephone : +61 1300 669988
Fax : +61 1300 669987
Local Contact
Telephone : 1300 669988
Fax : 1300 669987
Emergency Telephone : 1800 127 406 (24 hours) / (International) +64 3 353 0199
Number
2. HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
Classified as hazardous according to the criteria of NOHSC, and as Dangerous Goods according
to the Australian Dangerous Goods Code.
Symbol(s) : F Highly flammable.
Xn Harmful.
R-phrase(s) : R11 Highly flammable.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by
prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
S-phrase(s) : S2 Keep out of reach of children.
S36/37 Wear suitable protective clothing and gloves.
S62 If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.
S46 If swallowed, seek medical advice immediately and show
this container or label.
Health Hazards : Harmful: danger of serious damage to health by prolonged
exposure through inhalation. Vapours may cause drowsiness
and dizziness. Slightly irritating to respiratory system. Irritating
to skin. Moderately irritating to eyes. Harmful: may cause lung
1/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
damage if swallowed. Possibility of organ or organ system
damage from prolonged exposure; see Chapter 11 for details.
Target organ(s): Auditory system. Central nervous system
(CNS). Respiratory system. Visual system. Possible risk of
harm to the unborn child.
Signs and Symptoms : Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision. Skin
irritation signs and symptoms may include a burning sensation,
redness, swelling, and/or blisters. If material enters lungs,
signs and symptoms may include coughing, choking,
wheezing, difficulty in breathing, chest congestion, shortness of
breath, and/or fever. The onset of respiratory symptoms may
be delayed for several hours after exposure. Breathing of high
vapour concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness,
headache, nausea and loss of coordination. Continued
inhalation may result in unconsciousness and death. Auditory
system effects may include temporary hearing loss and/or
ringing in the ears. Visual system disturbances may be
evidenced by decreases in the ability to discriminate between
colours.
Aggravated Medical : Pre-existing medical conditions of the following organ(s) or
Condition organ system(s) may be aggravated by exposure to this
material: Auditory system. Central nervous system (CNS).
Respiratory system. Eyes. Skin. Visual system. Kidney.
Safety Hazards : Highly flammable. In use, may form flammable/explosive
vapour-air mixture. Electrostatic charges may be generated
during pumping. Electrostatic discharge may cause fire.
Environmental Hazards : Not classified as dangerous under EC criteria.
SUSDP Schedule : 6
3. COMPOSITION/INFORMATION ON INGREDIENTS
Material Formal Name : Benzene, methyl
CAS No. : 108-88-3
INDEX No. : 601-021-00-3
EINECS No. : 203-625-9
Hazardous Components
Chemical Name CAS EINECS Symbol(s) R-phrase(s) Conc.
R11; R38;
Toluene 108-88-3 203-625-9 F, Xn 100.00 %
R48/20;
R63; R65;
R67
Additional Information : Refer to chapter 16 for full text of EC R-phrases.
4. FIRST AID MEASURES
General Information : Keep victim calm. Obtain medical treatment immediately.
Inhalation : DO NOT DELAY. Remove to fresh air. If rapid recovery does
not occur, transport to nearest medical facility for additional
2/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Eye Contact : Immediately flush eyes with large amounts of water for at least
15 minutes while holding eyelids open. Transport to the
nearest medical facility for additional treatment.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Advice to Physician : Potential for chemical pneumonitis. Consider: gastric lavage
with protected airway, administration of activated charcoal.
Potential for cardiac sensitisation, particularly in abuse
situations. Hypoxia or negative inotropes may enhance these
effects. Consider: oxygen therapy.
5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
Specific Hazards : The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Will float and can be reignited on
surface water. Carbon monoxide may be evolved if incomplete
combustion occurs.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Wear full protective clothing and self-contained breathing
Firefighters apparatus.
Additional Advice : Keep adjacent containers cool by spraying with water.
Hazchem Code : 3[Y]E - For fire fighting, use foam (alcohol resistant foam may
be required). Risk of explosion. Breathing apparatus,
firefighting gear and chemically impervious protective gloves
should be worn. Prevent spillage from entering drains or
watercourses. Evacuation of people from the neighbourhood of
an incident should be considered.
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with spilled or released material. Immediately remove all contaminated clothing.
For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety
Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Material Safety
Data Sheet. Observe all relevant local and international regulations.
Protective measures : Isolate hazard area and deny entry to unnecessary or
unprotected personnel. Stay upwind and keep out of low areas.
Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment (of product and fire fighting water) to
avoid environmental contamination. Prevent from spreading or
3/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapour or to direct
its flow to a safe location for example by using fog sprays.
Take precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment. Ventilate contaminated area thoroughly.
Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Vapour may form an explosive
mixture with air. See Chapter 13 for information on disposal.
7. HANDLING AND STORAGE
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. On
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material.
Handling : Avoid contact with skin, eyes, and clothing. Extinguish any
naked flames. Do not smoke. Remove ignition sources. Avoid
sparks. Electrostatic charges may be generated during
pumping. Electrostatic discharge may cause fire. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment. Restrict line velocity during pumping in order to
avoid generation of electrostatic discharge (<= 1 m/sec until fill
pipe submerged to twice its diameter, then <= 7 m/sec). Avoid
splash filling. Do NOT use compressed air for filling,
discharging, or handling operations. Handle and open
container with care in a well-ventilated area.
Storage : Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system. Bulk storage tanks should
be diked (bunded). Must be stored in a diked (bunded) well-
ventilated area, away from sunlight, ignition sources and other
sources of heat. Keep away from aerosols, flammables,
oxidizing agents, corrosives and from other flammable
products which are not harmful or toxic to man or to the
environment. The vapour is heavier than air. Beware of
accumulation in pits and confined spaces.
4/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
Product Transfer : Keep containers closed when not in use. Do not use
compressed air for filling, discharging or handling.
Recommended Materials : For containers, or container linings use mild steel, stainless
steel.
Unsuitable Materials : Natural, butyl, neoprene or nitrile rubbers.
Container Advice : Containers, even those that have been emptied, can contain
explosive vapours. Do not cut, drill, grind, weld or perform
similar operations on or near containers.
Additional Information : Ensure that all local regulations regarding handling and storage
facilities are followed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Material Source Type ppm mg/m3 Notation
Toluene AU OEL TWA 50 ppm 191 mg/m3
AU OEL STEL 150 ppm 574 mg/m3
AU OEL SKIN_DES Can be absorbed through
the skin.
Biological Exposure Index (BEI) - See reference for full details
Material Determinant Sampling time BEI Reference
Toluene o-Cresol in urine End of shift 0.5 mg/l ACGIH (2003)
Hippuric acid in End of shift 1.6 g/g ACGIH (2003)
urine creatinine
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Use sealed systems as far as
possible. Adequate ventilation to control airborne
concentrations below the exposure guidelines/limits. Local
exhaust ventilation is recommended. Firewater monitors and
deluge systems are recommended. Eye washes and showers
for emergency use.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are suitable, select an appropriate combination of
mask and filter. Select a filter suitable for organic gases and
vapours [boiling point >65 癈 (149 ?meeting EN141. Where
F)]
respiratory protective equipment is required, use a full-face
mask. Where air-filtering respirators are unsuitable (e.g.,
airborne concentrations are high, risk of oxygen deficiency,
confined space) use appropriate positive pressure breathing
5/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
apparatus.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection: Longer term protection: Viton.
Incidental contact/Splash protection: Nitrile rubber. Suitability
and durability of a glove is dependent on usage, e.g. frequency
and duration of contact, chemical resistance of glove material,
glove thickness, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced.
Eye Protection : Chemical splash goggles (chemical monogoggles).
Protective Clothing : Chemical resistant gloves/gauntlets. Where risk of splashing or
in spillage clean up, use chemical resistant one-piece overall
with integral hood.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Examples of sources of recommended air
monitoring methods are given below or contact supplier.
Further national methods may be available. National Institute of
Occupational Safety and Health (NIOSH), USA: Manual of
analytical Methods
http://www.cdc.gov/niosh/nmam/nmammenu.html Occupational
Safety and Health Administration (OSHA), USA: Sampling and
Analytical Methods http://www.osha-
slc.gov/dts/sltc/methods/toc.html Health and Safety Executive
(HSE), UK: Methods for the Determination of Hazardous
Substances http://www.hsl.gov.uk/search.htm
Berufsgenossenschaftliches Institut f黵 Arbeitssicherheit (BIA),
Germany http://www.hvbg.de/d/bia/pub/grl/grle.htm L'Institut
National de Recherche et de Securit? (INRS), France
http://www.inrs.fr/indexnosdoss.html
Environmental Exposure : Local guidelines on emission limits for volatile substances must
Controls be observed for the discharge of exhaust air containing vapour.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Colourless Liquid.
Odour : Aromatic
Odour threshold : 1.74 ppm
pH : Not applicable.
Boiling point : Typical 110 - 111 ?/ 230 - 232 ?br>
C F
Melting / freezing point : Typical -95 ?/ -139 ?br>
C F
Flash point : 4 ?/ 39 ?br>
C F(Abel)
Explosion / Flammability : 1.2 - 8 %(V)
limits in air
Auto-ignition temperature : 480 - 536 ?/ 896 - 997 ?br>
C F(ASTM E-659)
Vapour pressure : Typical 1 kPa at 0 ?/ 32 癋Typical 3 - 3.5 kPa at 20 癈 / 68
C
癋Typical 12 kPa at 50 ?/ 122 ?br>
C F
Specific gravity : Data not available.
Density : Typical 871 kg/m3 at 15 ?/ 59 ?br>
C F
Water solubility : 0.515 kg/m3
Solubility in other solvents : Soluble in hydrocarbons and acetone
6/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
n-octanol/water partition : 2.65
coefficient (log Pow)
Kinematic viscosity : 0.63 mm2/s at 25 癈 / 77 癋
Vapour density (air=1) : 3.1
Electrical conductivity : Typical 8 pS/m at 20 ?/ 68 ?br>
C F(ASTM D-4308)
Dielectric constant : Typical 2.4
Evaporation rate (nBuAc=1) : 6.1 (DIN 53170, di-ethyl ether=1)
2 (ASTM D 3539, nBuAc=1)
Surface tension : Typical 28.5 mN/m at 20 ?/ 68 ?br>
C F(ASTM D-971)
Molecular weight : 92 g/mol
10. STABILITY AND REACTIVITY
Stability : Stable under normal conditions of use. Reacts violently with
strong oxidising agents.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Prevent vapour accumulation.
Materials to Avoid : Strong oxidising agents.
Hazardous : Thermal decomposition is highly dependent on conditions. A
Decomposition Products complex mixture of airborne solids, liquids and gases, including
carbon monoxide, carbon dioxide and other organic compounds
will be evolved when this material undergoes combustion or
thermal or oxidative degradation.
11. TOXICOLOGICAL INFORMATION
Basis for Assessment : Information given is based on product data.
Acute Oral Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat
Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Low toxicity: LC50 >20 mg/l / 4 hours, Rat
Classified as harmful by the European Commission.
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Skin Irritation : Irritating to skin.
Eye Irritation : Moderately irritating to eyes (but insufficient to classify).
Respiratory Irritation : Inhalation of vapours or mists may cause irritation to the
respiratory system.
Sensitisation : Not a skin sensitiser.
Repeated Dose Toxicity : Central nervous system: repeated exposure affects the
nervous system. Effects were seen at high doses only.
Respiratory system: repeated exposure affects the respiratory
system. Effects were seen at high doses only.
Visual system: may cause decreased color perception. These
subtle changes have not been found to lead to functional
colour vision deficits.
Auditory system: prolonged and repeated exposures to high
concentrations have resulted in hearing loss in rats. Solvent
abuse and noise interaction in the work environment may
cause hearing loss.
7/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
Mutagenicity : Not mutagenic.
Carcinogenicity : Not carcinogenic in animal studies.
Reproductive and : Causes foetotoxicity in animals at doses which are maternally
Developmental Toxicity toxic.
Does not impair fertility.
Additional Information : Exposure to very high concentrations of similar materials has
been associated with irregular heart rhythms and cardiac
arrest.
Abuse of vapours has been associated with organ damage and
death.
12. ECOLOGICAL INFORMATION
Acute Toxicity
Fish : Toxic: 1 < LC/EC/IC50 <= 10 mg/l
Aquatic Invertebrates : Harmful: 10 < LC/EC/IC50 <= 100 mg/l
Algae : Low toxicity: LC/EC/IC50 > 100 mg/l
Mobility : Floats on water.
If product enters soil, it will be highly mobile and may
contaminate groundwater.
Persistence/degradability : Readily biodegradable meeting the 10 day window criterion.
Oxidises rapidly by photo-chemical reactions in air.
Bioaccumulation : Does not bioaccumulate significantly.
Other Adverse Effects : In view of the high rate of loss from solution, the product is
unlikely to pose a significant hazard to aquatic life.
13. DISPOSAL CONSIDERATIONS
Material Disposal : Recover or recycle if possible. It is the responsibility of the
waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations.
Container Disposal : Drain container thoroughly. After draining, vent in a safe place
away from sparks and fire. Residues may cause an explosion
hazard. Do not, puncture, cut, or weld uncleaned drums. Send
to drum recoverer or metal reclaimer.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
14. TRANSPORT INFORMATION
ADG
UN number 1294
Proper shipping name TOLUENE
Class 3
Packing group II
Hazchem Code 3[Y]E
IMDG
Identification number UN 1294
Proper shipping name TOLUENE
8/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
Class / Division 3
Packing group II
Marine pollutant: No
IATA (Country variations may apply)
UN No. : 1294
Proper shipping name : Toluene
Class / Division :3
Packing group : II
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
SUSDP Schedule : 6
AICS : Listed.
DSL : Listed.
INV (CN) : Listed.
ENCS (JP) : Listed. (3)-2
TSCA : Listed.
EINECS : Listed. 203-625-9
KECI (KR) : Listed. 97-1-298
KECI (KR) : Listed. KE-33936
PICCS (PH) : Listed.
16. OTHER INFORMATION
R-phrase(s)
R11 Highly flammable.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
MSDS Version Number : 2.2
MSDS Effective Date : 02.08.2006
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation :
Uses and Restrictions : Raw material for use in the chemical industry.
Use as a solvent only in industrial manufacturing processes.
MSDS Distribution : The information in this document should be made available to
all who may handle the product
Disclaimer : This information is based on our current knowledge and is
9/10
Print Date 09.08.2006 MSDS_AU
Toluene
Version 2.2
Effective Date 02.08.2006
Material Safety Data Sheet
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
10/10
Print Date 09.08.2006 MSDS_AU
|