MATERIAL SAFETY DATA SHEET
I. PRODUCT NAME AND MANUFACTURER
PRODUCT NAME: D-56 READY TO BRUSH CEMENT MSDS NO. 200002
MATTHEWS INTERNATIONAL CORPORATION
PACKAGING GRAPHICS & DESIGN
252 Park West Drive
Pittsburgh, PA 15275
(412) 788-2111
II. PRODUCT INGREDIENTS
% CAS NO. PEL STEL CEIL TLV TLV-STEL
Toluene 25.6 108-88-3 200ppm 500ppm 300ppm 50ppm NE
Ethyl Acetate 10-20 141-78-6 400ppm NE NE 400ppm NE
Aliphatic Hydrocarbon 25-36 64742-89-8 400ppm* NE NE NE NE
Normal Heptane 1-5 142-82-5 400ppm 500ppm NE 400ppm 500ppm
* - Exposure limit shown is manufacturer's recommendation for this product component
NE ?Not Established
III. POTENTIAL HEALTH EFFECTS
EYES: May cause irritation.
SKIN: Primary skin irritant.
INHALATION: Central nervous system depression characterized by headaches, dizziness, nausea, and confusion.
INGESTION: Can cause gastrointestinal irritation, nausea, and vomiting. Aspiration of material into lung may cause chemical
pneumonitis, which can be fatal.
REPEATED OVEREXPOSURE: Repeated overexposure to toluene may cause liver damage. Reports have associated prolonged and repeated
occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH:
Toluene has been found to cause kidney, lung and spleen damage in laboratory animals.
IV. FIRST AID
EYES: Immediately flush with large amounts of water, lifting upper and lower lids occasionally, for at least 15 minutes. Seek
medical attention.
SKIN: Immediately flush the affected area with large amounts of water. Remove contaminated clothing as water is applied.
Consult a physician.
INHALATION: Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep warm and quiet. Get medical
attention immediately.
INGESTION: If swallowed, do not induce vomiting. Call poison control center, hospital emergency room or physician immediately.
V. FIREFIGHTING INSTRUCTIONS
NFPA FLAMMABILITY CLASSIFICATION: Flammable Liquid, Class IB
FLASH POINT (Method Use): 17?F (-8?C) SFCC
FLAMMABLE LIMITS: LEL - 1.0% UEL - 11.0%
AUTO-IGNITION TEMPERATURE: No Data
EXTINGUISHING MEDIA: Use NFPA Class B Fire Extinguisher (carbon dioxide, all purpose dry chemical or alcohol foam)
designed to extinguish flammable liquid fires. Polymer foam is preferred for large fires.
SPECIAL PROCEDURES: Fire fighters should wear SCBA. Water may be ineffective, but may be used to cool exposed
containers to prevent pressure build up and possible auto ignition when exposed to extreme heat. If
water is used, fog nozzles are preferable.
UNUSUAL FIRE AND EXPLOSION HAZARDS: During emergency conditions, overexposure to decomposition products may cause a health
hazard. Symptoms may not be immediately apparent. Obtain medical attention.
DANGER - Extremely flammable. Vapors may cause flash fire.
MATTHEWS INTERNATIONAL CORP.
Product Name: D-56 Ready to Brush Cement MSDS #200002
VI. ACCIDENT RESPONSE MEASURES
CHEMTREC TELEPHONE: 800-424-9300 NATIONAL SPILL RESPONSE CENTER: 800-424-8802
SPILL PROCEDURES: Wear respirators, eye, hand and body protection appropriate for the size of the spill and the exposure encountered. Keep
unauthorized personnel away. Eliminate all ignition sources (flames, hot surfaces, and sources of electrical, static or frictional sparks). Dike and
contain spill with inert material (sand, vermiculite, etc.). Transfer liquids to covered metal containers for recovery or disposal, or remove with
inert absorbent. Use only non-sparking tools. Place absorbent diking materials in covered metal containers for disposal. Prevent contamination
of sewers, streams, and groundwater with spilled material or used absorbent.
VII. SAFE HANDLING AND STORAGE
Do not store above 115?F (46?C). Store large quantities in compliance with applicable OSHA regulations (29 CFR 1910.106). Prohibit
smoking in these areas. Do not store or use near sources of ignition (open flame, sparks, heat, etc.) or combustible materials. Containers should
be grounded and bonded to the receiving container when dispensing this liquid product. Do not take internally. Close container after each use.
Empty containers must not be washed and reused for any purpose. Never use pressure to empty. Drum is not a pressure vessel. Do not weld,
braze or cut on empty container.
VIII. ENGINEERING CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Control airborne concentrations below the exposure limits. Use only with adequate ventilation.
RESPRIRATORY: Proper selection of respiratory protection depends on many factors including duration, level of exposure, and
conditions of use. In general, exposure to organic chemicals such as those contained in this product may not
require the use of respiratory protection if used in well-ventilated areas. In restricted ventilation areas, a
NIOSH approved chemical cartridge respirator may be required. Under certain conditions, such as spraying, a
mechanical pre-filter may be required. In confined areas use a NISOSH MSHA approved air supply respirator.
If the TLV's listed in Section II are exceeded, use a properly fitted NIOSH ?MSHA approved respirator with
an appropriate protection factor. Refer to OSHA 29 CFR 1910. 134 "Respiratory Protection" and "Respiratory
Protection ?A Manual and Guideline ?ACGIH."
VENTILATION: Provide local exhaust ventilation in sufficient volume and pattern to maintain exposures below nuisance dust
levels and permissible exposure limits shown in Section II. Refer to Industrial Ventilation ?A Manual by
ACGIH for additional information.
HAND PROTECTION: Solvent impermeable gloves required for repeated and prolonged contact.
EYE PROTECTION: Wear safety glasses for normal use. Wear safety goggles when the potential for splash hazards exist.
OTHER PROTECTIVE EQUIPMENT: Eye wash facility or device, safety shower.
IX. PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGF: 190?240?F, 88?116?C MELTING POINT: NA
VAPOR PRESSURE: 42 mm Hg VAPOR DENSITY (Air =1): >1
pH: NA SPECIFIC GRAVITY (H2O =1): 0.9, 7.9 lb/gal
VOLATILE BY VOLUME: 86% VOCs: 5.74 lb/gal, 689 g/l (less water, calculated)
EVAPORATION RATE: Slower than diethyl ether.
ODOR AND APPEARANCE: Amber liquid, translucent with sweet, aromatic odor.
X. STABILITY AND REACTIVITY
STABILITY: Normally stable.
CONDITIONS TO AVOID: Excessive heat (>115?F, (46?C), sources of ignition.
INCOMPATIBILITY: Strong acids or alkaline materials, oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Burning, welding or cutting may produce smoke, carbon monoxide, and carbon dioxide.
HAZARDOUS POLYMERIZATION: Will not occur.
XI. TOXICOLOGICAL INFORMATION
No information available.
XII. ECOLOGICAL INFORMATION
No information available.
MATTHEWS INTERNATIONAL CORP.
Product Name: D-56 Ready to Brush Cement MSDS #200002
XIII. DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, state, provincial and local regulations. Observe precautions for disposal of flammable materials.
Used portions of D-56 Ready to Brush Cement are considered hazardous waste under Federal Hazardous Waste Regulations (40 CFR 261).
RCRA Waste Code Classification: D001, F005 NOTE: Chemical additions, processing or otherwise altering this material may make the waste
management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Under RCRA, it is the responsibility of the
product user to determine at the time of disposal whether a material containing the product or derived from the product should be classified as a
hazardous waste. (40 CFR 261.20-24)
XIV. TRANSPORTATION INFORMATION
US DOT DESCRIPTION: Adhesives, 3, UN1133, PG II (Contains Toluene)
NA ERG: No. 128 The US Code of Federal Transportations, Regulations, and the policies established by some transporters require
that the shipper properly classify and assign a proper shipping name and label, mark and package the material
properly. Therefore, the user of this information is cautioned to consult with applicable regulations and with
qualified advisors prior to the repackaging and/or reshipment of this or any other product which contains this
product.
XV. REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: All components in this product are considered hazardous ingredients.
HMIS RATINGS: Health: 2 Flammability: 3 Reactivity: 0
CLEAN AIR ACT: This product contains the following hazardous air pollutants under section 112 of the 1990 Clean Air Act: Toluene
CERCLA/SARA 40 CFR 117, 302: No extremely hazardous substances are contained in this product.
REPORTABLE QUANTITIES: Toluene - 1000lb Ethyl Acetate - 5000lb
SECTION 311/312 HAZARD CATEGORIES: Fire, Acute Health, Delayed Health
SECTION 313 TOXIC CHEMICALS: Toluene
STATE REGULATIONS: California: The following statement is made in order to comply with the California Safe Drinking Water and Toxic
Enforcement Act of 1986: This product contains Toluene, a chemical known to the State of California to cause birth defects or other reproductive
harm.
TSCA: All ingredients in this product are listed on the US TSCA inventory. For Ethyl Acetate (CAS 141-78-6) TSCA(12b),(4),(8a
PAIR)(TSCA 8d)(DSL) // For Toluene (108-88-3) TSCA (8a), (CAIR),(PAIR), (8d) DSL
For N-Heptane (142-82-5) TSCA (12b)(TSCA 4a)(TSCA 8a PAIR)(TSCA 8d) DSL
All ingredients are listed on the US TSCA inventory.
CANADA: All ingredients in this product are listed on the Canadian Domestic Substance List.
XVI. OTHER INFORMATION
MSDS #200002 Original issue date: 9/17/86 Revised: 8/12/05 Prepared by: M.A. Remlinger / C. Spataro
The information contained herein is based upon what we believe to be reliable data. However, we make no warranty or guarantee, expressed or
implied, concerning the accuracy of such information and disclaim all liability from reliance thereon. You should evaluate the information
through your own sources prior to use.
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