MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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870-001
Product number
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Product name Vandalism Mark & Stain Remover
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16-Feb-2010
Effective date
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Mfg.
Claire Manufacturing Co.
Company information
500 Vista Ave.
Addison, IL 60101 United States
United States
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General Assistance 630-543-7600
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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04
Version #
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06-Jun-2008
Supersedes date
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2. Hazards Identification
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FLAMMABLE
Emergency overview
CONTENTS UNDER PRESSURE. Aerosol. Will be easily ignited by heat, spark or
flames. Harmful in contact with eyes. Cancer hazard. Irritating to skin. Irritating to
respiratory system. Prolonged exposure may cause chronic effects.
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Potential health effects
Ingestion. Inhalation. Skin contact.
Routes of exposure
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Contact may irritate or burn eyes. Eye contact may result in corneal injury.
Eyes
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Irritating to skin. Prolonged or repeated contact can result in defatting and drying of the
Skin
skin which may result in skin irritation and dermatitis (rash).
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
Irritating to respiratory system. Prolonged inhalation may be harmful.
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Exposure by ingestion of an aerosol is unlikely. Harmful if swallowed. May cause delayed
Ingestion
lung damage.
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Kidney. Central nervous system. Liver. Lungs. Respiratory system.
Target organs
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Conjunctiva. Liver injury may occur. Kidney injury may occur. May cause central nervous
Chronic effects
system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue,
mental confusion, and blurred vision) and/or damage. May cause delayed lung damage.
Prolonged skin contact may defat the skin and produce dermatitis.
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Discomfort in the chest. Corneal damage. Narcosis. Liver enlargement. Jaundice.
Signs and symptoms
Conjunctivitis. Defatting of the skin. Irritation.
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3. Composition / Information on Ingredients
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Components CAS # Percent
Methylene Chloride 75-09-2 40 - 50
n-Butane 106-97-8 20 - 30
Toluene 108-88-3 10 - 15
Perchloroethylene 127-18-4 8 - 10
Propane 74-98-6 8 - 10
Propylene Oxide 75-56-9 0.1 - 0.5
Non-hazardous and other components below reportable levels 1 - 2.5
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Get medical attention immediately.
Product name: Vandalism Mark & Stain Remover MSDS US
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Product #: 870-001
Vandalism Mark &date: 16-FEB-2010
Revision Stain Remover Print date: 16-FEB-2010
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Remove and isolate contaminated clothing and shoes. Wash off with warm water and
Skin contact
soap. Get medical attention if irritation develops or persists. For minor skin contact, avoid
spreading material on unaffected skin.
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Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth
Inhalation
method if victim inhaled the substance. Induce artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Call a physician if symptoms develop or persist.
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Rinse mouth. Never give anything by mouth to a victim who is unconscious or is having
Ingestion
convulsions. Do not induce vomiting without medical advice. If vomiting occurs naturally,
have victim lean forward to reduce risk of aspiration. Do not use mouth-to-mouth method
if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device.
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5. Fire Fighting Measures
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Vapor or gas may spread to distant ignition sources and flash back.
Flammable properties
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Extinguishing media
Foam. Dry chemical. Carbon dioxide (CO2).
Suitable extinguishing media
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Protection of firefighters
Fire may produce irritating, corrosive and/or toxic gases.
Specific hazards arising from
the chemical
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In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
Protective equipment and
including helmet, self-contained positive pressure or pressure demand breathing
precautions for firefighters
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable.
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Should not be released into the environment.
Methods for cleaning up
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Do not use if spray button is missing or
defective. Use only with adequate ventilation. Do not get this material in contact with
eyes. Do not get this material in contact with skin. Wear personal protective equipment.
Avoid prolonged exposure.
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Level 1 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Avoid exposure to long periods of
sunlight. Keep in an area equipped with sprinklers. Keep out of the reach of children.
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Methylene Chloride 75-09-2 50 ppm Not established Not established
n-Butane 106-97-8 1000 ppm Not established Not established
Toluene 108-88-3 20 ppm Not established Not established
Perchloroethylene 127-18-4 25 ppm 100 ppm Not established
Propane 74-98-6 1000 ppm Not established Not established
Propylene Oxide 75-56-9 2 ppm Not established Not established
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Product name: Vandalism Mark & Stain Remover MSDS US
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Product #: 870-001
Vandalism Mark &date: 16-FEB-2010
Revision Stain Remover Print date: 16-FEB-2010
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OSHA
Components CAS # TWA STEL Ceiling
Methylene Chloride 75-09-2 25 ppm 125 ppm Not established
Toluene 108-88-3 200 ppm Not established 300 ppm
Perchloroethylene 127-18-4 100 ppm Not established 200 ppm
Propane 74-98-6 1000 ppm Not established Not established
Propylene Oxide 75-56-9 100 ppm Not established Not established
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Wear appropriate chemical resistant clothing. Protective gloves.
Skin protection
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Wear positive pressure self-contained breathing apparatus (SCBA).
Respiratory protection
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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102.2 癋 (38.9 癈) estimated
Boiling point
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Pale yellow
Color
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18.61 kJ/g estimated
Flammability (HOC)
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Yes
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Solvent.
Odor
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Not applicable
pH
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Liquid.
Physical state
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40 - 55 psig @ 70F
Pressure
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Negligible
Solubility
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0.8934 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Risk of ignition. Stable at normal conditions.
Chemical stability
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Heat, flames and sparks.
Conditions to avoid
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Strong oxidizing agents.
Incompatible materials
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Hazardous decomposition products Hydrogen chloride. Irritants. Toxic gas. May include oxides of oxides of carbon.
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11. Toxicological Information
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Acute LC50: 82 mg/l/4h estimated, Rat, Inhalation
Acute effects
Acute LD50: 55930 mg/kg estimated, Rat, Dermal
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
Methylene Chloride 75-09-2 Oral LD50 Rat >2000 mg/kg; Inhalation LC50 Rat 76000 mg/m3 4 h
n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h
Perchloroethylene 127-18-4 Inhalation LC50 Rat 4000 ppm 4 h; Oral LD50 Rat 2629 mg/kg; Dermal LD50 Mouse
2800 mg/kg
Propane 74-98-6 Inhalation LC50 Rat 658 mg/L 4 h
Propylene Oxide 75-56-9 Oral LD50 Rat 520 mg/kg
Toluene 108-88-3 Inhalation LC50 Rat 12.5 mg/L 4 h; Inhalation LC50 Rat >26700 ppm 1 h; Oral LD50
Rat 636 mg/kg; Dermal LD50 Rabbit 8390 mg/kg; Dermal LD50 Rat 12124 mg/kg
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Hazardous by OSHA criteria.
Carcinogenicity
IARC - Group 2A (Probably Carcinogenic to Humans)
Perchloroethylene 127-18-4 Monograph 63 [1995]; Supplement 7 [1987]
IARC - Group 2B (Possibly Carcinogenic to Humans)
Methylene Chloride 75-09-2 Monograph 71 [1999]; Supplement 7 [1987]
Propylene Oxide 75-56-9 Monograph 60 [1994]; Supplement 7 [1987]
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
Product name: Vandalism Mark & Stain Remover MSDS US
3/5
Product #: 870-001
Vandalism Mark &date: 16-FEB-2010
Revision Stain Remover Print date: 16-FEB-2010
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12. Ecological Information
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LC50 32.2 mg/L estimated, Fish, 96.00 Hours,
Ecotoxicity
EC50 30.14 mg/L estimated, Daphnia, 48.00 Hours,
IC50 633 mg/L estimated, Algae, 72.00 Hours,
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
D039: Waste Tetrachloroethylene
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Contents under pressure. Dispose of this material and its container at hazardous or
Disposal instructions
special waste collection point. Do not allow this material to drain into sewers/water
supplies. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose
in accordance with all applicable regulations.
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
6.1
Subsidiary hazard class
1950
UN number
Tetrachloroethylene
Marine pollutant
Additional information:
NOT a LTQ QTY
Packaging exceptions
2.1, 6.1
Labels required
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IATA
Basic shipping requirements:
Aerosols, flammable, containing substances in Division
Proper shipping name
6.1, Packing Group III
2.1
Hazard class
6.1
Subsidiary hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1, 6.1
Labels required
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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Methylene Chloride 75-09-2 0.1 % de minimis concentration
Perchloroethylene 127-18-4 0.1 % de minimis concentration
Propylene Oxide 75-56-9 0.1 % de minimis concentration
Toluene 108-88-3 1.0 % de minimis concentration
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
Product name: Vandalism Mark & Stain Remover MSDS US
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Product #: 870-001
Vandalism Mark &date: 16-FEB-2010
Revision Stain Remover Print date: 16-FEB-2010
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CERCLA (Superfund) reportable quantity
Methylene Chloride: 1000.0000
Toluene: 1000.0000
Perchloroethylene: 100.0000
Propylene Oxide: 100.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of New and Existing Chemicals (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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WARNING: This product contains a chemical known to the State of California to cause
State regulations
cancer and birth defects or other reproductive harm.
U.S. - Pennsylvania - RTK (Right to Know) List
Methylene Chloride 75-09-2 Environmental hazard; Special hazardous substance
n-Butane 106-97-8 Present
Perchloroethylene 127-18-4 Environmental hazard; Special hazardous substance
Propane 74-98-6 Present
Propylene Oxide 75-56-9 Environmental hazard; Special hazardous substance
Toluene 108-88-3 Environmental hazard
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16. Other Information
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Health: 2*
HMIS?ratings
Flammability: 2
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text. The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication, The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification, The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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Product and Company Identification: Product and Company Identification
MSDS sections updated
Physical & Chemical Properties: Physical & Chemical Properties
Physical & Chemical Properties: Appearance
Transport Information: Product Shipping Name/Packing Group
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Regulatory Compliance
Prepared by
Product name: Vandalism Mark & Stain Remover MSDS US
5/5
Product #: 870-001
Vandalism Mark &date: 16-FEB-2010
Revision Stain Remover Print date: 16-FEB-2010
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