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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/11/2008 Reviewed on 03/11/2008
1 Identification of substance
?Product details
?Trade name: 39673 Self Etching Primer Black
?Article number: 39673
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Information department:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Emergency information: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
68476-86-8 Petroleum gases, liquefied, sweetened 25-50%
Danger: 2.2/1
Warning: 2.5/C
67-64-1 acetone 10-25%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
141-78-6 ethyl acetate 2.5-10%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
110-19-0 isobutyl acetate 2.5-10%
Danger: 2.6/2
108-88-3 toluene 2.5-10%
Danger: 2.6/2; 3.10/1, 3.7/2
Warning: 3.2/2, 3.3/2A, 3.8/3
78-93-3 butanone 2.5-10%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
9004-70-0 CELLULOSE NITRATE 2.5-10%
Danger: 2.1 ; 3.1.O/3, 3.2/2, 3.3/2A, 3.8/3
14808-60-7 Quartz (SiO2) 2.5-10%
Danger: 3.6/1B, 3.8/2
Warning: 3.3/2A
MALEIC MODIFIED ROSIN RESIN 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.8/3
123-86-4 n-butyl acetate 1-2.5%
Warning: 2.6/3; 3.8/3
(Contd. on page 2)
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Material Safety Data Sheet
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Printing date 03/11/2008 Reviewed on 03/11/2008
Trade name: 39673 Self Etching Primer Black
(Contd. of page 1)
67-63-0 propan-2-ol 1-2.5%
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
1330-20-7 xylene 1-2.5%
Danger: 3.1.D/3, 3.1.I/4, 3.2/2
Warning: 2.6/3
1330-78-5 tris(methylphenyl) phosphate 1-2.5%
Danger: 3.8/1
4.1.C/2
1%
84-74-2 dibutyl phthalate
Danger: 3.7/1B
Warning: 4.1.A/1
3 Hazards identification
?Hazard description:
Toxic
Extremely flammable
?WHMIS-symbols:
A - Compressed gas
B5 - Flammable aerosol
D2A - Very toxic material causing other toxic effects
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Warning! Pressurized container.
May cause cancer by inhalation.
May cause harm to the unborn child.
Extremely flammable.
Irritating to eyes.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
Danger of serious damage to health by prolonged exposure.
Possible risk of harm to the unborn child.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
87.1 % by mass of the contents are flammable
Keep out of the reach of children.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
(Contd. on page 3)
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Material Safety Data Sheet
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Printing date 03/11/2008 Reviewed on 03/11/2008
Trade name: 39673 Self Etching Primer Black
(Contd. of page 2)
?NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 4
FIRE 4
Reactivity = 0
REACTIVITY 0
?GHS label elements
Danger
2.2/1 - Extremely flammable gas.
2.3/1 - Extremely flammable aerosol.
Danger
3.6/1B - May cause cancer.
3.7/1B - May damage fertility or the unborn child.
3.8/1 - Causes damage to organs.
Warning
3.3/2A - Causes serious eye irritation.
?Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
?Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed: Call a POISON CENTER or doctor/physician.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see label).
If eye irritation persists: Get medical advice/attention.
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Eliminate all ignition sources if safe to do so.
?Storage:
Store in a well-ventilated place.
Store locked up.
Protect from sunlight. Do no expose to temperatures exceeding 50癈/ 122癋.
(Contd. on page 4)
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Material Safety Data Sheet
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 3)
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Immediately rinse with water.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
?Information about protection against explosions and fires:
Do not spray on a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
?Storage:
?Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurized containers.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Do not gas tight seal receptacle.
Store in cool, dry conditions in well sealed receptacles.
(Contd. on page 5)
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Material Safety Data Sheet
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Printing date 03/11/2008 Reviewed on 03/11/2008
Trade name: 39673 Self Etching Primer Black
(Contd. of page 4)
Protect from heat and direct sunlight.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
67-64-1 acetone
EL Short-term value: 500 ppm
Long-term value: 250 ppm
141-78-6 ethyl acetate
EL 150 ppm
110-19-0 isobutyl acetate
EL 150 ppm
108-88-3 toluene
EL 20 ppm
78-93-3 butanone
EL Short-term value: 100 ppm
Long-term value: 50 ppm
14808-60-7 Quartz (SiO2)
EL 0.025 mg/m?br>
ACGIH A2; IARC 1
123-86-4 n-butyl acetate
EL 20 ppm
67-63-0 propan-2-ol
EL Short-term value: 400 ppm
Long-term value: 200 ppm
1330-20-7 xylene
EL Short-term value: 150 ppm
Long-term value: 100 ppm
84-74-2 dibutyl phthalate
EL 5 mg/m?br>
R
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 5)
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Aerosol
Form:
According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: < 0癈
< 0癈
?Flash point:
405癈
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
In use, may form flammable/explosive vapour-air mixture.
?Danger of explosion:
?Explosion limits:
1.9 Vol %
Lower:
13.0 Vol %
Upper:
233 hPa
?Vapor pressure at 20癈:
0.77 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
(Contd. on page 7)
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Material Safety Data Sheet
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Printing date 03/11/2008 Reviewed on 03/11/2008
Trade name: 39673 Self Etching Primer Black
(Contd. of page 6)
?Solvent content:
83.6 %
Organic solvents:
83.6 %
VOC content:
495.7 g/l / 4.14 lb/gl
12.9 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
84-74-2 dibutyl phthalate
Oral LD50 8000 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic if inhaled.
12 Ecological information
?General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 8)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/11/2008 Reviewed on 03/11/2008
Trade name: 39673 Self Etching Primer Black
(Contd. of page 7)
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
2.1
?Hazard class:
UN1950
?Identification number:
-
?Packing group:
?Proper shipping name (technical name): AEROSOLS, flammable
2.1
?Label
?TDG (Transport dangerous goods):
2 5F Gases
?TDG class:
1950
?UN-Number:
-
?Packaging group:
2.1
?Label:
1950 AEROSOLS
?Description of goods:
?Maritime transport IMDG:
2.1
?IMDG Class:
1950
?UN Number:
2.1
?Label
-
?Packaging group:
F-D,S-U
?EMS Number:
No
?Marine pollutant:
AEROSOLS
?Propper shipping name:
?Air transport ICAO-TI and IATA-DGR:
2.1
?ICAO/IATA Class:
1950
?UN/ID Number:
2.1
?Label
-
?Packaging group:
(Contd. on page 9)
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Material Safety Data Sheet
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 8)
AEROSOLS, flammable
?Propper shipping name:
?UN "Model Regulation": UN1950; AEROSOLS; 2.1; -
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
None of the ingredient is listed.
?Section 313 (Specific toxic chemical listings):
108-88-3 toluene
78-93-3 butanone
67-63-0 propan-2-ol
1330-20-7 xylene
84-74-2 dibutyl phthalate
14807-96-6 Talc (Mg3H2(SiO3)4)
67-56-1 methanol
ACRYLIC RESIN
COPPER COMPOUND MIXTURE
100-41-4 ethylbenzene
?TSCA (Toxic Substances Control Act):
68476-86-8 Petroleum gases, liquefied, sweetened
67-64-1 acetone
141-78-6 ethyl acetate
110-19-0 isobutyl acetate
108-88-3 toluene
78-93-3 butanone
14808-60-7 Quartz (SiO2)
123-86-4 n-butyl acetate
67-63-0 propan-2-ol
1330-20-7 xylene
1330-78-5 tris(methylphenyl) phosphate
84-74-2 dibutyl phthalate
14807-96-6 Talc (Mg3H2(SiO3)4)
1333-86-4 Carbon black
108-65-6 2-methoxy-1-methylethyl acetate
?Proposition 65
?Chemicals known to cause cancer:
14808-60-7 Quartz (SiO2)
1330-20-7 xylene
1333-86-4 Carbon black
68911-87-5 ALKYL QUATERNARY AMMONIUM MONTMORILLONITE
(Contd. on page 10)
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Material Safety Data Sheet
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 9)
100-41-4 ethylbenzene
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
108-88-3 toluene
64-17-5 ethanol
?Cancerogenity categories
?EPA (Environmental Protection Agency)
67-64-1 acetone D
108-88-3 toluene D
78-93-3 butanone D
1330-20-7 xylene D
84-74-2 dibutyl phthalate D
100-41-4 ethylbenzene D
?IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
14808-60-7 Quartz (SiO2) 1
67-63-0 propan-2-ol 3
1330-20-7 xylene 3
14807-96-6 Talc (Mg3H2(SiO3)4) 3
1333-86-4 Carbon black 2B
68911-87-5 ALKYL QUATERNARY AMMONIUM MONTMORILLONITE TRACE AMOUNTS OF 14808-60-7
111-76-2 2-butoxyethanol 3
100-41-4 ethylbenzene 2B
?NTP (National Toxicology Program)
14808-60-7 Quartz (SiO2) K
?TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
108-88-3 toluene A4
14808-60-7 Quartz (SiO2) A2
1330-20-7 xylene A4
14807-96-6 Talc (Mg3H2(SiO3)4) A4
1333-86-4 Carbon black A4
64-17-5 ethanol A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
14808-60-7 Quartz (SiO2)
1333-86-4 Carbon black
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
(Contd. on page 11)
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Material Safety Data Sheet
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 10)
?Canadian substance listings:
?Canadian Domestic Substances List (DSL)
68476-86-8 Petroleum gases, liquefied, sweetened
67-64-1 acetone
141-78-6 ethyl acetate
110-19-0 isobutyl acetate
108-88-3 toluene
78-93-3 butanone
9004-70-0 CELLULOSE NITRATE
14808-60-7 Quartz (SiO2)
123-86-4 n-butyl acetate
67-63-0 propan-2-ol
1330-20-7 xylene
1330-78-5 tris(methylphenyl) phosphate
84-74-2 dibutyl phthalate
14807-96-6 Talc (Mg3H2(SiO3)4)
1333-86-4 Carbon black
?Canadian Ingredient Disclosure list (limit 0.1%)
64-17-5 ethanol
?Canadian Ingredient Disclosure list (limit 1%)
67-64-1 acetone
141-78-6 ethyl acetate
110-19-0 isobutyl acetate
108-88-3 toluene
78-93-3 butanone
14808-60-7 Quartz (SiO2)
123-86-4 n-butyl acetate
67-63-0 propan-2-ol
1330-78-5 tris(methylphenyl) phosphate
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Toxic
Extremely flammable
?Hazard-determining components of labelling:
Quartz (SiO2)
tris(methylphenyl) phosphate
toluene
dibutyl phthalate
?Risk phrases:
May cause cancer by inhalation.
May cause harm to the unborn child.
Extremely flammable.
(Contd. on page 12)
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Trade name: 39673 Self Etching Primer Black
(Contd. of page 11)
Irritating to eyes.
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
Danger of serious damage to health by prolonged exposure.
Possible risk of harm to the unborn child.
?Safety phrases:
Avoid exposure - obtain special instructions before use.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
Wear suitable protective clothing and gloves.
In case of insufficient ventilation, wear suitable respiratory equipment.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
This material and its container must be disposed of as hazardous waste.
?Special labeling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
87.1 % by mass of the contents are flammable
Keep out of the reach of children.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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