MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ELECTRICAL PRODUCTS DIVISION
TRADE NAME:
SCOTCHKOTE BRAND ELECTRICAL COATING
ID NUMBER/U.P.C.:
80-6107-3307-5 00-54007-14853-1 80-6112-0519-8 00-54007-43906-6
CS-0406-0592-8 - - -
ISSUED: November 27, 2001
SUPERSEDES: October 24, 2000
DOCUMENT: 10-2644-2
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1. INGREDIENT C.A.S. NO. PERCENT
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ACETONE................................. 67-64-1 40.0 - 45.0
METHYL ETHYL KETONE..................... 78-93-3 12.0 - 15.0
TOLUENE................................. 108-88-3 12.0 - 15.0
ACRYLONITRILE-BUTADIENE POLYMER......... 9003-18-3 10.0 - 15.0
PHENOL-FORMALDEHYDE RESIN............... 25085-50-1 3.0 - 7.0
GLYCEROL ESTERS OF ROSIN ACIDS.......... 8050-31-5 3.0 - 7.0
SALICYLIC ACID.......................... 69-72-7 1.0 - 2.0
ZINC OXIDE.............................. 1314-13-2 1.0 - 2.0
ANTIOXIDANT............................. 68411-46-1 0.1 - 1.0
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
The components of this product are in compliance with the chemical
notification requirements of TSCA.
All ingredients on TSCA; EINECS; CDSL
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
METHYL ETHYL KETONE
TOLUENE
ZINC OXIDE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 2
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2. PHYSICAL DATA
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BOILING POINT:................. 56.5C
VAPOR PRESSURE:................ 229 mm Hg @25C
VAPOR DENSITY:................. 2.00
EVAPORATION RATE:.............. N/D
SOLUBILITY IN WATER:........... Nil
SPECIFIC GRAVITY:.............. 0.88
PERCENT VOLATILE:.............. 75
pH:............................ N/A
VISCOSITY:..................... 325cps
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Liquid, Brown, solvent odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... 0F Closed Cup
FLAMMABLE LIMITS - LEL:........ 2.15%
FLAMMABLE LIMITS - UEL:........ 13.0%
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Vapors may travel long distances along the ground or floor to an
ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
OSHA FIRE HAZARD CLASS: Class IB Flammable Liquid
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4. REACTIVITY DATA
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STABILITY: Stable
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 3
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4. REACTIVITY DATA (continued)
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INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
None known.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrocarbons,
Amine Compounds.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Extinguish
all ignition sources. Contain spill. Cover with inorganic absorbent
material. Collect spilled material. Clean up residue. Place in an
approved metal container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: ca. 2.1 lb/gal.
VOC Less H2O & Exempt Solvents: ca. 251 gms/liter.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D001
(Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT:
Immediately flush skin with large amounts of water. Remove
contaminated clothing. If irritation persists, call a physician. Wash
contaminated clothing before reuse.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear unvented goggles during operations in which
exposure is likely.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber. Use one or more of the following
personal protection items as necessary to prevent skin contact:
apron, coveralls.
RECOMMENDED VENTILATION:
Use with appropriate local exhaust ventilation. Provide appropriate
local exhaust ventilation at transfer points. Provide appropriate
local exhaust ventilation on open containers. Provide sufficient
ventilation to maintain emissions below recommended exposure limits.
If exhaust ventilation is not adequate, use appropriate respiratory
protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator, full-face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
RECOMMENDED STORAGE:
Store in a cool place. Store away from acids. Store out of direct
sunlight. Keep container in well-ventilated area. Contents may be
under pressure, open carefully. Keep out of the reach of children.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Flammable liquid and vapor. Keep
away from heat, sparks, open flame, and other sources of ignition.
Ground containers securely when transferring contents. Wear low
static or properly grounded shoes. No smoking while handling this
material. Vapors may ignite explosively.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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ACETONE.............................. 500 PPM TWA ACGIH
ACETONE.............................. 750 PPM STEL ACGIH
ACETONE.............................. 750 PPM TWA OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM STEL OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM TWA OSHA
METHYL ETHYL KETONE.................. 200 PPM TWA OSHA
METHYL ETHYL KETONE.................. 300 PPM STEL OSHA
METHYL ETHYL KETONE.................. 200 PPM TWA ACGIH
METHYL ETHYL KETONE.................. 300 PPM STEL ACGIH
TOLUENE.............................. 50 PPM TWA ACGIH Y
TOLUENE.............................. 100 PPM TWA OSHAV
OSHA VACATED PEL
TOLUENE.............................. 150 PPM STEL OSHAV
OSHA VACATED PEL
TOLUENE.............................. 200 PPM TWA OSHA
TOLUENE.............................. 300 PPM CEIL OSHA
TOLUENE.............................. 75 PPM STEL CMRG Y
ACRYLONITRILE-BUTADIENE POLYMER...... NONE NONE NONE NONE
PHENOL-FORMALDEHYDE RESIN............ NONE NONE NONE NONE
GLYCEROL ESTERS OF ROSIN ACIDS....... NONE NONE NONE NONE
SALICYLIC ACID....................... NONE NONE NONE NONE
ZINC OXIDE........................... 10 MG/M3 TWA ACGIH
AS DUST
ZINC OXIDE........................... 10 MG/M3 TWA OSHAV
AS DUST
OSHA VACATED PEL
ZINC OXIDE........................... 5 MG/M3 TWA ACGIH
as fume
ZINC OXIDE........................... 10 MG/M3 STEL ACGIH
as fume
ZINC OXIDE........................... 5 MG/M3 TWA OSHA
as fume
ZINC OXIDE........................... 10 MG/M3 STEL OSHAV
as fume
OSHA VACATED PEL
ZINC OXIDE........................... 15 MG/M3 TWA OSHA
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 6
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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AS TOTAL DUST
ZINC OXIDE........................... 5 MG/M3 TWA OSHA
RESPIRABLE
ANTIOXIDANT.......................... NONE NONE NONE NONE
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Moderate Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, itching, and dryness.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
INHALATION:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Vapors of the uncured product may cause irritation of the respiratory
system.
Prolonged or repeated exposure may cause:
Blood disorders: signs/symptoms can include prolonged weakness
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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and fatigue.
Liver Effects: signs/symptoms can include yellow skin(jaundice)
and tenderness of upper abdomen.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Cardiac Sensitization: sudden heart stoppage due to a reflex
effect on the nerves which control the heart. This effect
usually occurs only after inhalation of concentrated vapors such
as in intentional abusive sniffing of certain solvents and
propellants.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness, incoordination,
slowed reaction time, fatigue, blurred vision, slurred speech,
giddiness, tremors and convulsions.
Aspiration Pneumonitis: signs/symptoms can include coughing,
difficulty breathing, wheezing, coughing up blood and pneumonia,
which can be fatal.
Repeated ingestion may cause:
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice)
and tenderness of upper abdomen.
REPRODUCTIVE/DEVELOPMENTAL TOXINS:
WARNING: Contains a chemical which can cause birth defects. (108-88-
3)
SALICYLIC ACID (69-72-7) has been associated with lower birth weights,
increased perinatal mortality, ante- and postpartum hemorrhage,
prolonged gestation and complicated deliveries.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHKOTE BRAND ELECTRICAL COATING
November 27, 2001 PAGE 8
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE October 24, 2000 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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