EMERGENCY PHONE: 1-800-424-9300 Chemtrec
INTERNATIONAL TRANSPORTATION ACCIDENTS: 1-703-527-3887 Chemtrec
I. CHEMICAL PRODUCT IDENTIFICATION
Product Name : 791CL Clear Strippable Booth Coating
03/18/08
Date Printed :
03/18/08
Revision Date : Revision Number : 2
Supercedes : 03/13/02 CHEMCO INFO:800-323-0431
II. COMPOSITION/INFORMATION ON INGREDIENTS - (EXPOSURE LIMITS - SEE SECTION VIII)
INGREDIENT NAME CAS # %
Toluene 108-88-3 30.01 - 40.00
Acetone 67-64-1 15.01 - 20.00
Methyl ethyl ketone 78-93-3 10.01 - 15.00
Methyl isobutyl ketone 108-10-1 10.01 - 15.00
Chlorinated paraffins 63449-39-8 1.01 - 5.00
If ingredient percentages do not total 100%, the balance is due to rounding or applies to ingredient(s) deemed nonhazardous under 29 CFR 1910.1200 (Hazard Communication Standard).
III. HAZARDS IDENTIFICATION
HMIS
2
HEALTH
3
FLAMMABILITY
0
REACTIVITY
0 = Least 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Effects
Routes of Entry: Inhalation, Absorption, Skin contact, Eye contact, Ingestion.
Skin allergies, Skin disease including eczema and sensitization, Eye disease, Respiratory disease
Medical Conditions Aggravated:
including asthma and bronchitis, Kidney disease, Liver disease.
Immediate (Acute) Health Effects:
Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.
Inhalation:
Harmful if inhaled. High concentrations in immediate area can displace oxygen and can cause
dizziness, unconsciousness, and even death with longer exposure. Inhalation of high concentrations
may result in central nervous system (CNS) depression, and in the production of methemoglobinemia,
leading to cyanosis.
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage.
Skin Contact:
Irritating and may injure eye tissue if not removed promptly. This product can cause prolonged
Eye Contact:
vision impairment, tears, swelling and redness.
May cause irritation and minor systemic damage. Harmful if absorbed through the skin. A single
Skin Absorption:
exposure is not likely to result in the product being absorbed through the skin in harmful amounts.
Harmful if swallowed. May cause systemic poisoning. Can cause abdominal discomfort, nausea,
Ingestion:
vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis.
Nervous System, Heart, Kidneys, Respiratory System, Skin, Eyes, Liver, PNS.
Target Organ Acute Toxicity:
Long-Term (Chronic) Health Effects:
Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness,
Inhalation:
weakness, fatigue, nausea and headache. Repeated or prolonged inhalation may cause toxic effects.
Prolonged or repeated inhalation may cause kidney and lung damage.
Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not
Skin Contact:
likely to cause permanent damage.
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 1 of 5
Upon prolonged or repeated contact, can cause moderate to severe eye injury. Eye contact may result
Eye Contact:
in tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment
(cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause minor
Skin Absorption
systemic damage.
IARC: No NTP: No OSHA: No
Carcinogenicity:
Respiratory System, Nervous System, Heart, Kidneys, Skin, Eyes, Liver, PNS.
Target Organ Chronic Toxicity:
NOTICE - Reports have associated repeated and prolonged occupational overexposure to solvents with
brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal.
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
Inhalation:
breathing, give artificial respiration. Get medical attention immediately.
Immediately flush eyes with plenty of luke warm water for at least 20 minutes retracting eyelids often.
Eyes:
Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention and monitor the eye daily as advised by your physician.
Wash with soap and water. Remove contaminated clothing, launder immediately, and discard
Skin Contact:
contaminated leather goods. Get medical attention immediately.
Seek medical advice immediately. Provide ingredients information from Section II of this MSDS to
Ingestion:
the medical care provider. Contact your local Poison Control Center (listed in the telephone book), or
dial the local "Emergency" (911) number for additional information. Do not induce vomiting unless
instructed to do so by a physician or other competent medical personnel. Never give anything by
mouth to an unconscious person.
Acute massive exposure to toluene can cause transient hematuria and albuminuria. Cardiac
Notes to M.D.
arrhythmias can occur after massive inhalation.
V. FIRE FIGHTING MEASURES
Extremely Flammable
Flammability Summary:
-20 ?C; -4 ?F
Flash Point:
448 ?C; 838 ?F
Autoignition Temperature:
Autoignition Temperature:
1.1 7.0
Lower Flammable/Explosive Limit, % in air: Upper Flammable/Explosive Limit, % in air:
Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash
Fire Hazards:
point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and
flash back This product, when dried or cured, may support combustion when subjected to sources of
ignition or heat in sufficient amount.
Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog
Extinguishing Media:
may also be effective for extinguishing if swept across the base of the fire. Water can also be used to
absorb heat and keep exposed material from being damaged by fire.
Do not enter fire area without proper protection including self-contained toxic breathing apparatus and
Fire Fighting Instructions:
full protective equipment. Fight fire from a safe distance and a protected location due to the potential of
hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter
than water and burn while floating on the surface. Use water spray/fog for cooling. Do not point solid
water stream directly into burning oil to avoid spreading.
Carbon dioxide, Carbon monoxide, Phosgene.
Hazardous Combustion Products:
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 2 of 5
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be severely irritating or toxic. Follow personal protective
Health Consideration for Spill Response:
equipment recommendations found in Section VIII of this MSDS. Personal protective equipment needs
must be evaluated based on information provided on this sheet and the special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,
and the expertise of employees in the area responding to the spill. Never exceed any occupational
exposure limits. Evaporation of volatile substances can lead to the displacement of air creating an
environment that can cause asphyxiation.
Spill Mitigation Procedures:
Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so.
General Methods:
Wear complete and proper personal protective equipment following the recommendation of Section
VIII at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a
sealed container pending a waste disposal evaluation. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area.
Ventilate the area by opening door and/or turning on fans and blowers.
Air Release:
Avoid runoff into storm sewers and ditches that lead to waterways. If runoff occurs, notify proper
Water Release:
authorities as required, that a spill has occurred.
Do not flush to sewer.
Land Spills:
VII. HANDLING AND STORAGE
Harmful or irritating; avoid overexposure to the material. Use only in a well ventilated area. Use spark-
Handling:
proof tools and explosion-proof equipment.
Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep
Storage:
container(s) closed when not in use. Keep away from sources of ignition.
VIII. ENGINEERING CONTROLS, PERSONAL PROTECTIVE EQUIPMENT, AND EXPOSURE LIMITS
Local exhaust ventilation, process enclosures, or other engineering controls are important when
Engineering Controls:
handling or using this product to avoid overexposure.Facilities storing or using this material should be
equipped with an eyewash and safety shower. Vapor concentrations should be monitored and
controlled in accordance with 29 CFR 1910.1000.
Protective Equipment:
If general or local exhaust ventilation is not available or sufficient to reduce exposure to below
Respiratory Tract:
acceptable levels, then respiratory protection is required to avoid overexposure when handling this
product.
Wear safety glasses with side shields when handling this product. When the possibility exists for eye
Eyes:
contact with splashing or spraying liquid, or airborne material, wear additional eye protection such as
chemical splash goggles and/or face shield . Do not wear contact lenses. Have an eye wash station
available.
Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals.
Skin:
Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water
before eating, drinking, and when leaving work.
Wear chemically resistant gloves and apron. (Consult your safety equipment supplier).
Protective Clothing:
CHEMICAL NAME CAS ACGIH TLV OSHA PEL IDLH
#
Toluene 108-88-3 50 ppm TWA 200 ppm TWAC 300 ppm Not determined.
Acetone 67-64-1 500 ppm TWA750 ppm STEL 1000 ppm TWA; 2400 mg/m3 TWA 2500 ppm IDLH (lower explosive level)
Methyl ethyl ketone 78-93-3 200 ppm TWA300 ppm STEL 200 ppm TWA; 590 mg/m3 TWA 3000 ppm IDLH
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 3 of 5
Methyl isobutyl ketone 108-10-1 50 ppm TWA75 ppm STEL 100 ppm TWA; 410 mg/m3 TWA 500 ppm IDLH
Chlorinated paraffins 63449-39-8 No TLV No PEL established Not determined.
IX. PHYSICAL DATA
Clear Liquid.
Appearance:
Clear
Color:
Moderate Hydrocarbon Ketone
Odor:
N/A
pH:
Not Determined.
Octanol/Water Coeff:
Partial.
Solubility in Water:
Heavier than air. Vapors that evolve from this product will tend to settle and accumulate near the floor.
Vapor Density:
Faster than n-Butyl acetate.
Evaporation Rate:
0.891 / 7.44 Lbs./Gl.
Specific Gravity/Density:
5.8 Lbs/Gl less water & 696 g/l less water & 4.6 Lbs/Gl as
V.O.C.
exempt solvent; exempt solvent; packed
The VOC content is determined by using a percent solids basis, less water and exempt solvents, for adhesives, coatings and inks and the calculations of EPA
Reference Method 24 or equivalent ASTM method approved by the executive office.
The Federal EPA has delisted Acetone as a VOC. Even though this product contains Acetone (see Section II), the VOC listed above does not include Acetone
in the VOC calculation. Individual states may have other regulations. Please check with your state.
56 ?C; 133 ?F
Initial Boiling Point:
N/A
Initial Freezing Point:
X. STABILITY AND REACTIVITY
Stable under normal conditions.
Stability Information:
Sparks, open flame, other ignition sources, and elevated temperatures.Contamination., High
Conditions to Avoid:
temperatures
Strong acids.
Chemical Incompatibility:
Carbon dioxide, Carbon monoxide, , Chlorine containing gases, Phosgene.
Hazardous Decomposition Products:
XI. TOXICOLOGICAL INFORMATION
Chemical Name LD50/LC50
Toluene Inhalation LC50 Mouse : 5320 ppm/8H; Oral LD50 Rat : 5000 mg/kg; Dermal LD50 Rabbit : 14 g/kg
Acetone Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44 gm/m3/4H; Oral LD50 Rat : 5800 mg/kg;
Oral LD50 Mouse : 3 gm/kg
2-Butanone Inhalation LC50 Rat : 23500 mg/m3/8H; Inhalation LC50 Mouse : 32 gm/m3/4H; Oral LD50 Rat : 2737 mg/kg;
Oral LD50 Mouse : 4050 mg/kg; Dermal LD50 Rabbit : 6480 mg/kg
2-Pentanone, 4-methyl- Inhalation LC50 Mouse : 23300 mg/m3; Oral LD50 Rat : 2080 mg/kg; Oral LD50 Mouse : 2671 mg/kg;
Dermal LD50 Rabbit : >20 mL/kg
Paraffin waxes and hydrocarbon waxes, Oral LD50 Rat : >21500 uL/kg; Dermal LD50 Rabbit : >10 mL/kg
chlorinated
XII. ECOLOGICAL INFORMATION
Care should be taken to minimize releases of any industrial chemicals to the environment.
Overview:
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Spent Product:
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 4 of 5
Information in this MSDS is provided only as a guide. Consult with competent authority to determine
Disposal Methods:
proper waste disposal procedures. Clean up and dispose of waste and clean-up materials in accordance
with all federal, state, and local environmental regulations.
D001 D035, .
Potential EPA Waste Codes:
Some Components Possibly Subjected to USEPA Land Disposal Restrictions:
When disposing of unused products or any waste, the preferred options are to send to a licensed reclaimer or to permitted incinerators. There may be some other ingredients subject to LDR categories.
Toluene 108-88-3
Acetone 67-64-1
Methyl ethyl ketone 78-93-3
Methylisobutyl ketone 108-10-1
XIV. TRANSPORTATION INFORMATION
Agency Basic Description and Label
Paint Related Material, 3, UN1263, PG II; Label Required: Flammable Liquid.
DOT
Hazardous Substance
Toluene final RQ = 1000 pounds (454 kg); also listed as Benzene, methyl-
Acetone final RQ = 5000 pounds (2270 kg); also listed as 2-Propanone
Ethyl methyl ketone final RQ = 5000 pounds (2270 kg); also listed as 2-Butanone; also listed as Ethyl methyl ketone
Methylisobutyl ketone final RQ = 5000 pounds (2270 kg); also listed as 4-Methyl-2-pentanone
XV. REGULATORY INFORMATION
Regulation
SARA 313 Reportable : Toluene, Methyl ethyl ketone, Methylisobutyl ketone
TSCA Inventory : All components of this product are listed in, or exempt from, the TSCA 8(b) Inventory.
M.S.D.S. Reportable HAP(s) : Toluene, Methyl ethyl ketone (2-Butanone), Methyl isobutyl ketone (Hexone).
California Proposition 65 : The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986 -
Proposition 65: "WARNING: This product contains chemical(s) known to the State of California to cause birth defects."
XVI. ADDITIONAL INFORMATION
Major References: VENDOR'S MSDS's, PAINT & COATINGS HANDBOOK, EPA's LIST OF LISTS, AND OTHER PUBLISHED MATERIALS.
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, THEY ARE
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU PERFORM AN ASSESSMENT TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION, OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND INFORMATION FURNISHED
HERE ARE GIVEN GRATIS. NO OBLIGATIONS NOR LIABILITIES FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED
AT YOUR RISK.
CHEMCO MFG. CO., INC. 515 HUEHL ROAD, NORTHBROOK, IL 60062 PH:800-323-0431 WWW.CHEMCOMFG.COM
Page 5 of 5
|