MATERIAL SAFETY DATA SHEET
I. PRODUCT NAME AND MANUFACTURER
PRODUCT NAME: 566 SEALER MSDS NO. 200003
MATTHEWS INTERNATIONAL CORPORATION
PACKAGING GRAPHICS & DESIGN
252 Park West Drive
Pittsburgh, PA 15275
(412) 788-2111
II. PRODUCT INGREDIENTS
INGREDIENTS % CAS NO. PEL STEL-OSHA TLV STELTLV LD50
Isopropyl Alcohol 30-60 67-63-0 400ppm 500ppm 400ppm 500ppm 5840 1kg oral, rat
Toluene 30-60 108-88-3 100ppm 500ppm 50ppm NE 5000 mg/kg, oral, rat
Methyl Ethyl Ketone <5 78-93-3 200ppm 300ppm 200ppm 300ppm 2737 mg/kg, oral, rat
III. POTENTIAL HEALTH EFFECTS
EMERGENCY OVERVIEW: Amber liquid with pungent odor. Flammable. Can cause central nervous system depression with narcotic effects
in high concentrations. Reports have associated overexposure to solvents with permanent brain and nervous system
damage. Repeated over-exposure to Toluene may cause liver damage. Exposure to Methyl Ethyl Ketone may enhance
neurotoxicity of n-Hexane and Methyl-n-Butyl Ketone. Synergistic effect has resulted in peripheral neuropathy in humans.
EYES: May cause severe eye irritation.
SKIN: Liquid material may be absorbed through skin in harmful amounts. May cause defatting and irritation of the skin.
INHALATION: May cause irritation of nose or throat. High concentrations may cause acute central nervous system depression
characterized
by headaches, dizziness, nausea and confusion.
INGESTION: Can cause gastrointestinal irritation, nausea, and vomiting. Aspiration of material into lung may cause chemical
pneumonitis which can be fatal.
EFFECTS OF REPEATED OVEREXPOSURE: Repeated overexposure to toluene may cause liver damage. Exposure to methyl ethyl ketone
may enhance the nuerotoxicity of n-hexane and methyl-n-butyl ketone. This synergistic effect has resulted in peripheral
neuropathy in humans. Reports have associated prolonged and repeated occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents
may be harmful or fatal.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH: Toluene has been found to cause kidney,
lung and spleen damage in laboratory animals. Laboratory studies involving rats
Indicate some evidence that Methyl Ethyl Ketone may be embryotoxic, phetotoxic, and terratogenic.
IV. FIRST AID
EYES: Flush with large amounts of water, lifting upper and lower lids occasionally, for at least 15 minutes. Seek medical
attention.
SKIN: Immediately wash the affected area with soap and water. Remove contaminated clothing as water is applied. Seek medical
attention if irritation persists.
INHALATION: Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep warm and quiet. Get
medical attention immediately.
INGESTION: If swallowed, do not induce vomiting. Call poison control center, hospital emergency room or physician immediately.
NOTES TO PHYSICIAN: Any treatment that might be required for over exposure should be directed at the control of symptoms and the clinical
conditions.
V. FIREFIGHTING INSTRUCTIONS
FLASH POINT (Method Use): 24?F (-4?C) SFCC NFPA : Flammable Liquid, Class I B Liquid
FLAMMABLE LIMITS: LEL - 1.7% UEL - 13.0%
AUTO-IGNITION TEMPERATURE: No Data
EXTINGUISHING MEDIA: Small Fires: Use NFPA Class B Fire Extinguisher (carbon dioxide, all purpose dry chemical or
alcohol foam) designed to extinguish flammable liquid fires. Large Fires: Polymer foam.
SPECIAL PROCEDURES: Firefighters should wear SCBA. Water may be ineffective, but may be used to cool exposed containers to
prevent pressure build up and possible auto ignition when exposed to extreme heat. If water is used, fog
nozzles are preferable.
UNUSUAL FIRE AND EXPLOSION HAZARDS: During emergency conditions, overexposure to decomposition products may cause a health
hazard. Symptoms may not be immediately apparent. Obtain medical attention. DANGER - Extremely
flammable. Vapors may cause flash fire.
MATTHEWS INTERNATIONAL CORP.
Product Name: 566 Sealer MSDS #200003
VI. ACCIDENT RESPONSE MEASURES
CHEMTREC TELEPHONE: 800-424-9300 NATIONAL SPILL RESPONSE CENTER: 800-424-8802
SPILL PROCEDURES: Wear respirators, eye, hand and body protection appropriate for the size of the spill and the exposure encountered. Keep
unauthorized personnel away. Eliminate all ignition sources (flames, hot surfaces, and sources of electrical, static or frictional sparks). Dike and
contain spill with inert material (sand, vermiculite, etc.). Transfer liquids to covered metal containers for recovery or disposal, or remove with
inert absorbent. Use only non-sparking tools. Place absorbent diking materials in covered metal containers for disposal. Prevent contamination
of sewers, streams, and groundwater with spilled material or used absorbent.
VII. SAFE HANDLING AND STORAGE
Do not store above 115?F (46?C). Store large quantities in compliance with applicable OSHA regulations (29 CFR 1910.106). Prohibit
smoking in these areas. Do not store or use near sources of ignition (open flame, sparks, heat, etc.) or combustible materials. Containers should
be grounded and bonded to the receiving container when dispensing this liquid product. Do not take internally. Close container after each use.
Empty containers must not be washed and reused for any purpose. Never use pressure to empty. Drum is not a pressure vessel. Do not weld,
braze or cut on empty container.
VIII. ENGINEERING CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Control airborne concentrations below the exposure limits. Use only with adequate ventilation.
RESPRIARTORY PROTECTION: Proper selection of respiratory protection depends on many factors including duration, level of exposure, and
conditions of use. In general exposure to organic chemicals such as those contained in this product may not require the use of respiratory
protection if used in well ventilated areas. In restricted ventilation areas, a NIOSH approved chemical cartridge respirator may be required.
Under certain conditions, such as spraying, a mechanical pre-filter may be required. In confined areas use a NISOSH MSHA approved air supply
respirator. If the TLV's listed in Section II are exceeded use a properly fitted NIOSH ?MSHA approved respirator with an appropriate protection
factor. Refer to OSHA 29 CFR 1910. 134 "Respiratory Protection" and "Respiratory Protection ?A Manual and Guideline ?ACGIH."
VENTILATION: Provide local exhaust ventilation in sufficient volume and pattern to maintain exposures below nuisance dust levels and
permissible exposure limits shown in Section II. Refer to Industrial Ventilation ?A Manual by ACGIH for additional information.
HAND PROTECTION: Solvent impermeable gloves required for repeated and prolonged contact.
EYE PROTECTION: Wear safety glasses for normal use. Wear safety goggles when the potential for splash hazards exist.
OTHER PROTECTIVE EQUIPMENT: Not likely to be needed.
IX. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 180?F, 82?C to 233?F, 112?C MELTING POINT: NA
VAPOR PRESSURE: No data VAPOR DENSITY (Air =1): >1
pH: NA SPECIFIC GRAVITY (H2O =1): 0.9, 7.4 lb/gal
VOLATILE BY VOLUME: 83% VOC=S: 5.73 lb/gal minus water and CAA exempt compounds
688 g/l (less water, calculated)
SOLUBLE IN WATER? 41.0% EVAPORATION RATE: Slower than diethyl ether
ODOR AND APPEARANCE: Amber liquid, with pungent odor.
X. STABILITY AND REACTIVITY
STABILITY: Normally stable.
CONDITIONS TO AVOID: Excessive heat (>115?F, (46?C), sources of ignition.
INCOMPATIBILITY: Strong acids or alkaline materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Burning, including when heated by welding or cutting may produce smoke, carbon
monoxide, and carbon dioxide.
HAZARDOUS POLYMERIZATION: Will not occur.
MATTHEWS INTERNATIONAL CORP.
Product Name: 566 Sealer MSDS #200003
XI. TOXICOLOGICAL INFORMATION
No Information Available.
XII. ECOLOGICAL INFORMATION
No Information Available.
XIII. DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, state, provincial and local regulations. Observe precautions for disposal of flammable materials.
Used portions of 566 Sealer are considered hazardous waste under Federal Hazardous Waste Regulations (40 CFR 261).
RCRA Waste Code Classification: D001, F005 NOTE: Chemical additions, processing or otherwise altering this material may make the waste
management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Under RCRA, it is the responsibility of the
product user to determine at the time of disposal whether a material containing the product or derived from the product should be classified as a
hazardous waste. (40 CFR 261.20-24)
XIV. TRANSPORTATION INFORMATION
US DOT DESCRIPTION: Adhesives, 3, UN1133, PG II (Contains Toluene)
NA ERG: No. 128
The US Code of Federal Transportations, Regulaitons, and the policies established by some transporters require thet the shipper properly classify
and assign a Proper Shipping Name and label, mark and package the material properly. Therefore the user of this information is cautioned to
consult with
Applicable regulations and with qualified advisors prior to the repackaging and/or reshipment of this or any other product which contain this
product.
XV. REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: All components contained in this product are considered hazardous ingredients.
CLEAN AIR ACT: This product contains the following hazardous air pollutants under section 112 of the 1990 Clean Air Act:
Methyl Ethyl Ketone, Toluene
CERCLA/SARA, 40 CFR 117, 302: No extremely hazardous substances are contained in this product.
REPORTABLE QUANTITIES: Isopropyl Alcohol -NA Toluene - 1,000 lbs Methyl Ethyl Ketone - 5000 lbs
SECTION 311/312 HAZARD CATEGORIES: Fire, Acute Health, Delayed Health
SECTION 313 TOXIC CHEMICALS: Toluene, Methyl Ethyl Ketone
HMIS RATINGS: Health 2 Flammability 3 Reactivity 0
STATE REGULATIONS: California: The following statement is made in order to comply with the California Safe Drinking Water and Toxic
Enforcement Act of 1986: This product contains Toluene, a chemical known to the State of California to cause birth defects
or other reproductive harm.
TSCA: All ingredients in this product are listed on the US TSCA inventory. For Isporoplyl Alcohol (CAS 67-63-0)
TSCA(12b),(4),(8a PAIR) // For Toluene (108-88-3) TSCA (8a), (CAIR),(PAIR), (8d) DSL
For Methy Ethyl Ketone (78-93-3) TSCA (8a)(PAIR)(8d) DSL
CANADA: All ingredients are listed on the Canadian Domestic Substance List.
XVI. OTHER INFORMATION
MSDS #200003 Original issue date: 10/25/85 Revised: 8/012/05 Prepared by: M.A. Remlinger / C. Spataro
The information contained herein is based upon what we believe to be reliable data. However, we make no warranty or guarantee, expressed or
implied, concerning the accuracy of such information and disclaim all liability from reliance thereon. You should evaluate the information
through your own sources prior to use.
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