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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
1 Identification of substance
Product details
Trade name: PCLD10 Electric Dye Concentrate
Article number: PCLD10
Manufacturered For:
Sherwin-Williams Automotive Finishes Corp.
101 Prospect Ave. NW
Cleveland, OH 44115
USA
(216)566-2902
Information department: 24HR EMERGENCY 216-566-2917
2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
108-65-6 2-methoxy-1-methylethyl acetate 7 5-100%
78-93-3 butanone 2.5-10%
9004-36-8 CELLULOSE ACETATE BUTYRATE 2 .5-10%
SOLVENT ORANGE 2.5%
8052-41-3 Stoddard solvent 2.5%
3 Hazards identification
Hazard description:
Irritant
Highly flammable
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Highly flammable.
Irritating to eyes, respiratory system and skin.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
NFPA ratings (scale 0 - 4)
Health = 2
3 Fire = 3
2 0 Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 3
FIRE 3
Reactivity = 0
REACTIVITY 0
USA
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 1)
4 First aid measures
After inhalation: In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water with full jet
Protective equipment: No special measures required.
6 Accidental release measures
Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
7 Handling and storage
Handling:
Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
108-65-6 2-methoxy-1-methylethyl acetate
WEEL 100 ppm
(Contd. on page 3)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 2)
78-93-3 butanone
PEL
REL
TLV
BEI
8052-41-3 Stoddard solvent
PEL
REL
*15-min
TLV
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
General Information
Fluid
Form:
(Contd. on page 4)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 3)
According to product specification
Color:
Characteristic
Odor:
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 79癈 (174癋)
-4癈 (25癋)
Flash point:
315.0癈 (599癋)
Ignition temperature:
Product is not selfigniting.
Auto igniting:
Product is not explosive. However, formation of explosive air/vapor mixtures
Danger of explosion:
are possible.
Explosion limits:
1.5 Vol %
Lower:
10.8 Vol %
Upper:
Vapor pressure at 20癈 (68癋): 3.4 hPa (3 mm Hg)
Density at 20癈 (68癋):
Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
Solvent content:
91.2 %
Organic solvents:
91.2 %
VOC content:
875.6 g/l / 7.31 lb/gl
8.8 %
Solids content:
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
108-65-6 2-methoxy-1-methylethyl acetate
Oral LD50 8532 mg/kg (rat)
Inhalative LC50/4 h 35.7 mg/l (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
USA
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 4)
12 Ecological information
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
DOT regulations:
3
Hazard class:
UN1263
Identification number:
II
Packing group:
Proper shipping name (technical name): PAINT
3
Label
Land transport TDG (Canada) and ADR/RID (Europe):
3 Flammable liquids
Hazard class:
1263
UN-Number:
II
Packaging group:
3
Label:
1263 PAINT, special provision 640D
Description of goods:
Maritime transport IMDG:
3
IMDG Class:
1263
UN Number:
3
Label
II
Packaging group:
F-E,S-E
EMS Number:
No
Marine pollutant:
(Contd. on page 6)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 5)
PAINT
Propper shipping name:
Air transport ICAO-TI and IATA-DGR:
15 Regulations
Sara
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
78-93-3 butanone
SOLVENT ORANGE
TSCA (Toxic Substances Control Act):
108-65-6 2-methoxy-1-methylethyl acetate
78-93-3 butanone
8052-41-3 Stoddard solvent
1333-86-4 Carbon black
Proposition 65
Chemicals known to cause cancer:
1333-86-4 Carbon black
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Cancerogenity categories
EPA (Environmental Protection Agency)
78-93-3 butanone D
IARC (International Agency for Research on Cancer)
1333-86-4 Carbon black 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
1333-86-4 Carbon black A4
(Contd. on page 7)
USA
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD10 Electric Dye Concentrate
(Contd. of page 6)
NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
Irritant
Highly flammable
Hazard-determining components of labelling:
Stoddard solvent
Risk phrases:
Highly flammable.
Irritating to eyes, respiratory system and skin.
Safety phrases:
Keep container in a well-ventilated place.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Avoid exposure - obtain special instructions before use.
This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Contact: Mike Veney 216-332-8528