Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
* * * Section 1 - Chemical Product and Company Identification * * *
Material Name: APAC 616
Product Use
Sealer
Manufacturer Information
MAPEI Corporation
1144 East Newport Center Drive
Deerfield Beach, Florida 33442
Customer Service
Phone: 1-800-747-2722
Fax: 706-277-4157
www.apacadhesives.com
apac@apacadhesives.com
IN THE EVENT OF A CHEMICAL EMERGENCY INVOLVING A SPILL, LEAK, FIRE, EXPLOSION, EXPOSURE
OR ACCIDENT, CONTACT THE FOLLOWING NUMBERS:
Emergency 24 hour numbers:
(USA) CHEMTREC 1-800-424-9300
(Canada) CANUTEC 1-631-996-6666
* * * Section 2 - Hazards Identification * * *
Emergency Overview
This product has been evaluated using criteria specified in 29CFR 1910.1200 (Hazard Communication Standard).
Extremely flammable; material will readily ignite at normal temperatures. This product is irritating to the eyes.
Hazard Statements
DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR - VAPOR MAY CAUSE FLASH FIRE. IRRITANT.
VAPOR HARMFUL. HARMFUL OR FATAL IF SWALLOWED. Irritating to eyes. Vapor accumulation can flash or
explode when ignited. Wear suitable gloves, eye/face protection, and respiratory protection. Keep out of the reach
of children.
Potential Health Effects: Eyes
This product is irritating to the eyes. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
Potential Health Effects: Skin
Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis.
Potential Health Effects: Ingestion
Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Potential Health Effects: Inhalation
Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. This product is an
asphyxiant gas which can cause unconsciousness/death if OXYGEN levels are sufficiently reduced.
Medical Conditions Aggravated by Exposure
Hypersensitivity to product, allergies, and skin or respiratory disorders
Potential Environmental Effects
No information available for the product.
HMIS Ratings: Health: 2 Fire: 3 Reactivity: 0 Pers. Prot.: Safety glasses, gloves, synthetic apron, vapor respirator if
airborne concentrations exceed exposure limits
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
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Page 1 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
* * * Section 3 - Composition / Information on Ingredients * * *
CAS # Component Percent
110-54-3 Hexane 30-60
108-88-3 Toluene 10-30
67-64-1 Acetone 7-13
78-93-3 Methyl ethyl ketone 7-13
Proprietary Phenolic resin 3-7
1309-48-4 Magnesium oxide 0.5-1.5
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Get medical attention or advice. Immediately flush eyes with plenty of water for at least 15 minutes.
First Aid: Skin
Get medical attention or advice. Flush with large amounts of water.
First Aid: Ingestion
If the material is swallowed, get immediate medical attention or advice.
First Aid: Inhalation
Get medical attention or advice. Immediately remove the affected person to fresh air. If the affected person is not
breathing, apply artificial respiration.
First Aid: Notes to Physician
Provide general supportive measures and treat symptomatically.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
Extremely dangerous fire and explosion hazard. Vapors may be ignited by flame, sparks or contact with any hot
surface (light bulb or steam pipes) under normal atmospheric conditions. Forms explosive mixtures with air.
Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back.
Empty containers may retain product residue including Flammable or Explosive vapors. Do not cut, drill, grind, or
weld near full, partially full, or empty product containers. Eliminate ignition sources including sources of electrical,
static or frictional sparks.
Hazardous Combustion Products
Irritating and toxic gases or fumes may be released during a fire. Upon decomposition, this product emits carbon
monoxide, carbon dioxide and/or low molecular weight hydrocarbons.
Extinguishing Media
Dry chemical (preferred), foam, water.
Fire Fighting Equipment/Instructions
Wear self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode
when fighting fires.
NFPA Ratings: Health: 3 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Contain the discharged material.
Personal Precautions
Eliminate ignition sources including sources of electrical, static or frictional sparks.
Clean-Up Procedures
Attempt to reclaim the free product, if this is possible. Thoroughly wash the area with water after a spill or leak
clean-up. Wear appropriate protective equipment and clothing during clean-up. Keep out of the reach of children.
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Page 2 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Environmental Precautions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Evacuation Procedures
Isolate area. Keep unnecessary personnel away.
Special Procedures
Wear appropriate protective equipment and clothing during clean-up.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Keep this product from heat, sparks, or open flame. Do not smoke, extinguish all flames and pilot lights, and turn
off stoves, heaters, electric motors, and other sources of ignition during use and until all vapors are gone. Prevent
build-up of vapors - open all windows and doors - use only with cross-ventilation. Use only in well ventilated
areas. Avoid breathing vapors or mists of this product. Avoid getting this material into contact with your skin and
eyes. Close container after use. Keep out of the reach of children.
Storage Procedures
Do not handle or store near an open flame, heat or other sources of ignition. Store in a cool, dry, well-ventilated
area. Keep the container tightly closed.
* * * Section 8 - Exposure Controls / Personal Protection * * *
A: Component Exposure Limits
Hexane (110-54-3)
ACGIH: Skin - potential significant contribution to overall exposure by the cutaneous route
50 ppm TWA
OSHA: 500 ppm TWA; 1800 mg/m3 TWA
NIOSH: 50 ppm TWA; 180 mg/m3 TWA
Alberta: 50 ppm TWA; 176 mg/m3 TWA
Substance may be readily absorbed through intact skin
British Columbia: 20 ppm TWA
Skin notation
Manitoba: 50 ppm TWA
New Brunswick: 50 ppm TWA; 176 mg/m3 TWA
NW Territories: 100 ppm TWA; 352 mg/m3 TWA
125 ppm STEL; 440 mg/m3 STEL
Nova Scotia: 50 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
Nunavut: 100 ppm TWA; 352 mg/m3 TWA
125 ppm STEL; 440 mg/m3 STEL
Ontario: 50 ppm TWAEV; 176 mg/m3 TWAEV
Quebec: 50 ppm TWAEV; 176 mg/m3 TWAEV
Skin designation
Saskatchewan: 62.5 ppm STEL
50 ppm TWA
Yukon: 125 ppm STEL; 450 mg/m3 STEL
100 ppm TWA; 360 mg/m3 TWA
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Page 3 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Toluene (108-88-3)
ACGIH: 20 ppm TWA
OSHA: 200 ppm TWA
300 ppm Ceiling
NIOSH: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
Alberta: 50 ppm TWA; 188 mg/m3 TWA
Substance may be readily absorbed through intact skin
British Columbia: Adverse reproductive effect
20 ppm TWA
Manitoba: 20 ppm TWA
New Brunswick: 50 ppm TWA; 188 mg/m3 TWA
Skin - potential for cutaneous absorption
NW Territories: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
Skin notation
Nova Scotia: 20 ppm TWA
Nunavut: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
Skin notation
Ontario: 20 ppm TWAEV
Quebec: 50 ppm TWAEV; 188 mg/m3 TWAEV
Skin designation
Saskatchewan: 60 ppm STEL
50 ppm TWA
Yukon: Skin notation
150 ppm STEL; 560 mg/m3 STEL
100 ppm TWA; 375 mg/m3 TWA
Acetone (67-64-1)
ACGIH: 750 ppm STEL
500 ppm TWA
OSHA: 1000 ppm TWA; 2400 mg/m3 TWA
NIOSH: 250 ppm TWA; 590 mg/m3 TWA
Alberta: 500 ppm TWA; 1200 mg/m3 TWA
750 ppm STEL; 1800 mg/m3 STEL
British Columbia: 250 ppm TWA
500 ppm STEL
Manitoba: 500 ppm TWA
750 ppm STEL
New Brunswick: 500 ppm TWA; 1188 mg/m3 TWA
750 ppm STEL; 1782 mg/m3 STEL
NW Territories: 1000 ppm TWA; 2370 mg/m3 TWA
1250 ppm STEL; 2970 mg/m3 STEL
Nova Scotia: 500 ppm TWA
750 ppm STEL
Nunavut: 1000 ppm TWA; 2370 mg/m3 TWA
1250 ppm STEL; 2970 mg/m3 STEL
Ontario: 500 ppm TWAEV
750 ppm STEV
Quebec: 500 ppm TWAEV; 1190 mg/m3 TWAEV
1000 ppm STEV; 2380 mg/m3 STEV
Saskatchewan: 750 ppm STEL
500 ppm TWA
Yukon: 1250 ppm STEL; 3000 mg/m3 STEL
1000 ppm TWA; 2400 mg/m3 TWA
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Page 4 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Methyl ethyl ketone (78-93-3)
ACGIH: 300 ppm STEL
200 ppm TWA
OSHA: 200 ppm TWA; 590 mg/m3 TWA
NIOSH: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
Alberta: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
British Columbia: 50 ppm TWA
100 ppm STEL
Manitoba: 200 ppm TWA
300 ppm STEL
New Brunswick: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
NW Territories: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
Nova Scotia: 200 ppm TWA
300 ppm STEL
Nunavut: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
Ontario: 200 ppm TWAEV; 590 mg/m3 TWAEV
300 ppm STEV; 885 mg/m3 STEV
Quebec: 50 ppm TWAEV; 150 mg/m3 TWAEV
100 ppm STEV; 300 mg/m3 STEV
Saskatchewan: 300 ppm STEL
200 ppm TWA
Yukon: 250 ppm STEL; 740 mg/m3 STEL
200 ppm TWA; 590 mg/m3 TWA
Magnesium oxide (1309-48-4)
ACGIH: 10 mg/m3 TWA (inhalable fraction)
OSHA: 15 mg/m3 TWA (fume, total particulate)
Alberta: 10 mg/m3 TWA (fume)
British Columbia: 10 mg/m3 TWA (fume, inhalable); 3 mg/m3 TWA (Mg, respirable dust and fume)
10 mg/m3 STEL Mg respirable dust and fume
Manitoba: 10 mg/m3 TWA (inhalable fraction)
New Brunswick: 10 mg/m3 TWA (fume)
NW Territories: 10 mg/m3 TWA (Mg, fume)
20 mg/m3 STEL (Mg, fume)
Nova Scotia: 10 mg/m3 TWA (inhalable fraction)
Nunavut: 10 mg/m3 TWA (Mg, fume)
20 mg/m3 STEL (Mg, fume)
Ontario: 10 mg/m3 TWAEV (inhalable)
Quebec: 10 mg/m3 TWAEV (Mg, fume)
Saskatchewan: 20 mg/m3 STEL (inhalable fraction)
10 mg/m3 TWA (inhalable fraction)
Yukon: 10 mg/m3 STEL (Mg, fume)
10 mg/m3 TWA (Mg, fume)
Engineering Controls
Use general ventilation.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields.
Personal Protective Equipment: Skin
The use of nitrile-latex gloves is recommended.
Personal Protective Equipment: Respiratory
If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection.
Personal Protective Equipment: General
Launder contaminated clothing before reuse. Use good industrial hygiene practices in handling this material.
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Page 5 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
* * * Section 9 - Physical & Chemical Properties * * *
Appearance: Amber liquid Odor: Slight odor
Physical State: Liquid pH: 132?F - 232?F
Vapor Pressure: N/A Vapor Density: Heavier than air
Boiling Point: N/A Melting Point: N/A
Solubility (H2O): N/A Specific Gravity: N/A
Evaporation Rate: Slower than ether VOC: 631 g/L
Octanol/H2O Coeff.: N/A Flash Point: <20?F
Flash Point Method: CC Upper Flammability Limit (UFL): 1%
Lower Flammability Limit (LFL): N/A Burning Rate: N/A
Auto Ignition: N/A
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Keep away from heat, sparks, or open flame. Eliminate sources of ignition.
Incompatibility
This product may react with strong acids, bases and oxidizing agents.
Hazardous Decomposition
Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Upon decomposition,
this product may emit fumes of carbon monoxide, carbon dioxide, oxides of nitrogen, and other organic
compounds.
Possibility of Hazardous Reactions
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
No information available for the product.
B: Component Analysis - LD50/LC50
Hexane (110-54-3)
Inhalation LC50 Rat 48000 ppm 4 h; Oral LD50 Rat 25 g/kg; Dermal LD50 Rabbit 3000 mg/kg
Toluene (108-88-3)
Inhalation LC50 Rat 12.5 mg/L 4 h; Inhalation LC50 Rat >26700 ppm 1 h; Oral LD50 Rat 636 mg/kg; Dermal
LD50 Rabbit 8390 mg/kg; Dermal LD50 Rat 12124 mg/kg
Acetone (67-64-1)
Oral LD50 Rat 5800 mg/kg
Methyl ethyl ketone (78-93-3)
Inhalation LC50 Mouse 32 g/m3 4 h; Oral LD50 Rat 2737 mg/kg; Dermal LD50 Rabbit 6480 mg/kg
Carcinogenicity
A: General Product Information
No information available for the product.
B: Component Carcinogenicity
Toluene (108-88-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable))
Acetone (67-64-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
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Page 6 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Magnesium oxide (1309-48-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Sensitization
No information available for the product.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for the product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Hexane (110-54-3)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 2.1-2.98 mg/L [flow-through]
24 Hr EC50 Daphnia magna >1000 mg/L
Toluene (108-88-3)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 15.22-19.05 mg/L [flow-through] 1 day old
96 Hr LC50 Pimephales promelas 12.6 mg/L [static]
96 Hr LC50 Oncorhynchus mykiss 5.89-7.81 mg/L [flow-through]
96 Hr LC50 Oncorhynchus mykiss 14.1-17.16 mg/L [static]
96 Hr LC50 Oncorhynchus mykiss 5.8 mg/L [semi-static]
96 Hr LC50 Lepomis macrochirus 11.0-15.0 mg/L [static]
96 Hr LC50 Oryzias latipes 54 mg/L [static] [static]
96 Hr LC50 Poecilia reticulata 28.2 mg/L [semi-static]
96 Hr LC50 Poecilia reticulata 50.87-70.34 mg/L [static]
96 Hr EC50 Pseudokirchneriella >433 mg/L
subcapitata
72 Hr EC50 Pseudokirchneriella 12.5 mg/L [static]
subcapitata
48 Hr EC50 Daphnia magna 5.46 - 9.83 mg/L [static]
48 Hr EC50 Daphnia magna 11.5 mg/L
Acetone (67-64-1)
Test & Species Conditions
96 Hr LC50 Oncorhynchus mykiss 4.74-6.33 ml/L
96 Hr LC50 Pimephales promelas 6210-8120 mg/L [static]
96 Hr LC50 Lepomis macrochirus 8300 mg/L
48 Hr EC50 Daphnia magna 10294 - 17704 mg/L [Static]
48 Hr EC50 Daphnia magna 12600 - 12700 mg/L
Methyl ethyl ketone (78-93-3)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 3130-3320 mg/L [flow-through]
48 Hr EC50 Daphnia magna >520 mg/L
48 Hr EC50 Daphnia magna 5091 mg/L
48 Hr EC50 Daphnia magna 4025 - 6440 mg/L [Static]
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
No information available for the product.
B: Component Waste Numbers
Toluene (108-88-3)
RCRA: waste number U220
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Page 7 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Acetone (67-64-1)
RCRA: waste number U002 (Ignitable waste)
Methyl ethyl ketone (78-93-3)
RCRA: waste number U159 (Ignitable waste, Toxic waste)
200.0 mg/L regulatory level
Disposal Instructions
Waste must be handled in accordance with all federal, state, provincial, and local regulations. Consult authorities
before disposal.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
* * * Section 14 - Transportation Information * * *
US DOT Information
Shipping Name: Adhesives
UN/NA #: UN1133 Hazard Class: 3 Packing Group: II
IATA Information
Shipping Name: Adhesives
UN #: UN1133 Hazard Class: 3 Packing Group: II
IMDG Information
Shipping Name: Adhesives
UN #: UN1133 Hazard Class: 3 Packing Group: II
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
All of the components of this product are listed on, or are exempted from listing on the U.S. EPA TSCA Inventory
of Chemical Substances. All components of this product are included, or are exempt from inclusion, in the
Canadian Domestic Substance List unless otherwise noted.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Hexane (110-54-3)
SARA 313: 1.0 % de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Toluene (108-88-3)
SARA 313: 1.0 % de minimis concentration
CERCLA: 1000 lb final RQ; 454 kg final RQ
Acetone (67-64-1)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Methyl ethyl ketone (78-93-3)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
Hexane 110-54-3 No Yes Yes Yes Yes Yes
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Page 8 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
Material Safety Data Sheet
Material Name: APAC 616 ID: SAH00260
Toluene 108-88-3 Yes Yes Yes Yes Yes Yes
Acetone 67-64-1 Yes Yes Yes Yes Yes Yes
Methyl ethyl ketone 78-93-3 Yes Yes Yes Yes Yes Yes
Magnesium oxide 1309-48-4 Yes Yes Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer. This product contains a chemical known to the
state of California to cause reproductive/developmental effects.
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Hexane 110-54-3 1%
Toluene 108-88-3 1%
Acetone 67-64-1 1%
Methyl ethyl ketone 78-93-3 1%
Magnesium oxide 1309-48-4 1%
Additional Regulatory Information
A: General Product Information
Supplier(s) of proprietary component(s) state that these components are contained on the TSCA inventory.
B: Component Analysis - Inventory
Component CAS # TSCA CAN EEC
Hexane 110-54-3 Yes DSL EINECS
Toluene 108-88-3 Yes DSL EINECS
Acetone 67-64-1 Yes DSL EINECS
Methyl ethyl ketone 78-93-3 Yes DSL EINECS
Magnesium oxide 1309-48-4 Yes DSL EINECS
* * * Section 16 - Other Information * * *
Reference
G1-2851-01
Other Information
Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or any
other warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for
any direct, incidental or consequential damages resulting from its use. The information herein is presented in good faith and believed to be
accurate as of the effective date given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and
local laws.
Key/Legend
NA = Not available or Not Applicable. BLV=Biological Limit Values TLV = Threshold Limit Value. NFPA = National Fire Protection Association.
HMIS = Hazardous Material Information System. CFR = Code of Federal Regulations. EPA = Environmental Protection Agency; TSCA =
Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for
Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA =
Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry.
Contact: Product Safety Specialist
Contact Phone: 1-954-246-8888
End of Sheet SAH00260
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Page 9 of 9 Issue Date: 18 January 2010 Revision: 1.0001 Print Date: 1/18/2010
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