TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
SYNONYMS
PROPER SHIPPING NAME
FLAMMABLE LIQUID, N.O.S.
(contains isohexanes and toluene)
PRODUCT USE
Used according to manufacturer' s directions. The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical
ventilation. Used as a thinner for contact adhesive.
SUPPLIER
Company:The Laminex Group
Address:
90- 94 Tram Road
Doncaster
VIC, 3108
AUS
Telephone:+61 3 9848 4811
Fax: +61 3 9848 8158
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
S6
RISK
Risk Codes Risk Phrases
R11 Highly flammable.
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 2 of 7
Section 2 - HAZARDS IDENTIFICATION
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R48/20 Harmful: danger of serious damage to health by prolonged
exposure through inhalation.
R52/53 Harmful to aquatic organisms may cause long- term adverse
effects in the aquatic environment.
R63(3) Possible risk of harm to the unborn child.
R65 HARMFUL- May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
SAFETY
Safety Codes Safety Phrases
S16 Keep away from sources of ignition. No smoking.
S23 Do not breathe gas/fumes/vapour/spray.
S51 Use only in well ventilated areas.
S09 Keep container in a well ventilated place.
S53 Avoid exposure - obtain special instructions before use.
S29 Do not empty into drains.
S401 To clean the floor and all objects contaminated by this
material use water and detergent.
S07 Keep container tightly closed.
S13 Keep away from food drink and animal feeding stuffs.
S27 Take off immediately all contaminated clothing.
S26 In case of contact with eyes rinse with plenty of water and
contact Doctor or Poisons Information Centre.
S46 If swallowed IMMEDIATELY contact Doctor or Poisons
Information Centre. (show this container or label).
S60 This material and its container must be disposed of as
hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
n- hexane 110-54-3 <5
isohexanes 73513-42-5 30-60
methyl ethyl ketone 78-93-3 <10
toluene 108-88-3 30-60
Section 4 - FIRST AID MEASURES
SWALLOWED
?If swallowed do NOT induce vomiting.
?If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Avoid giving milk or oils.
Avoid giving alcohol.
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible
aspiration of vomitus.
EYE
If this product comes in contact with the eyes:
?Wash out immediately with fresh running water.
?Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
SKIN
If skin contact occurs:
?Immediately remove all contaminated clothing, including footwear.
?Flush skin and hair with running water (and soap if available).
INHALED
?If fumes or combustion products are inhaled remove from contaminated area.
?Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or
pharmacologically.
Following acute or short term repeated exposures to toluene:
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 3 of 7
Section 4 - FIRST AID MEASURES
?Toluene is absorbed across the alveolar barrier, the blood/air mixture being 11.2/15.6 (at 37 degrees C.) The concentration of
toluene, in expired breath, is of the order of 18 ppm following sustained exposure to 100 ppm. The tissue/blood proportion is 1/3
except in adipose where the proportion is 8/10.
?Metabolism by microsomal mono-oxygenation, results in the production of hippuric acid. This may be detected in the urine in
amounts between 0.5 and 2.5 g/24 hr which represents, on average 0.8 gm/gm of creatinine. The biological half-life of hippuric
acid is in the order of 1-2 hours.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
?Foam.
?Dry chemical powder.
FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?May be violently or explosively reactive.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
?Liquid and vapour are highly flammable.
?Severe fire hazard when exposed to heat, flame and/or oxidisers.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
Contains low boiling substance: Closed containers may rupture due to pressure
buildup under fire conditions.
May emit clouds of acrid smoke.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc.
HAZCHEM: 3[Y]E
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
?Remove all ignition sources.
?Clean up all spills immediately.
MAJOR SPILLS
?Clear area of personnel and move upwind.
?Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
?Containers, even those that have been emptied, may contain explosive vapours.
?Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
Contains low boiling substance:
Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately.
?Check for bulging containers.
?Vent periodically.
DO NOT allow clothing wet with material to stay in contact with skin.
?Electrostatic discharge may be generated during pumping - this may result in fire.
?Ensure electrical continuity by bonding and grounding (earthing) all equipment.
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
SUITABLE CONTAINER
?Packing as supplied by manufacturer.
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 4 of 7
Section 7 - HANDLING AND STORAGE
?Plastic containers may only be used if approved for flammable liquid.
?For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used
as an inner package, the can must have a screwed enclosure.
?For materials with a viscosity of at least 2680 cSt. (23 deg. C).
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
?Store in original containers in approved flame-proof area.
?No smoking, naked lights, heat or ignition sources.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWAppm TWAmg/m? STELppm STELmg/m?br>
__________________ __________________ _______ _______ _______ _______
AustraliaExposureStandar n- hexane(Hexane(n- 20 72
ds Hexane))
AustraliaExposureStandar isohexanes(Hexane, 500 1, 760 1, 000 3, 500
ds otherisomers)
AustraliaExposureStandar methylethylketone(Methyl 150 445 300 890
ds ethylketone(MEK))
AustraliaExposureStandar toluene(Toluene) 50 191 150 574
ds
PERSONAL PROTECTION
RESPIRATOR
Type AX Filter of sufficient capacity
EYE
?Safety glasses with side shields.
?Chemical goggles.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Suitability and durability of glove type is dependent on usage. Factors such as:
?frequency and duration of contact,
?chemical resistance of glove material,
OTHER
?Overalls.
?PVC Apron.
ENGINEERING CONTROLS
CARE: Use of a quantity of this material in confined space or poorly ventilated area, where rapid build up of concentrated
atmosphere may occur, could require increased ventilation and/or protective gear.
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required.
Ventilation equipment should be explosion-resistant.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear colourlesshighly flammable liquid with a strong solvent odour; not miscible with water.
PHYSICAL PROPERTIES
Does not mix with water.
Floats on water.
Molecular Weight: Not Available Boiling Range (癈): 55 approx
Melting Range (癈): Not Available Specific Gravity (water=1): 0.78
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): 100 Evaporation Rate: Not Available
Relative Vapour Density (air=1): >1 Flash Point (癈): - 26
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 5 of 7
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Lower Explosive Limit (%): 1.1 Upper Explosive Limit (%): 7.5
Autoignition Temp (癈): Not Available Decomposition Temp (癈): Not Available
State: LIQUID Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
?Presence of incompatible materials.
?Product is considered stable.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Harmful if swallowed. Possible risk of harm to the unborn child.
HARMFUL- May cause lung damage if Harmful: danger of serious damage to health
swallowed.
Irritating to eyes and skin. by prolonged exposure through inhalation.
Vapours may cause dizziness or suffocation.
Vapours may cause drowsiness and dizziness.
TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
N-HEXANE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 28710 mg/kg Eye(rabbit): 10 mg - Mild
Inhalation (human) TCLo: 190 ppm/8W
Inhalation (rat) LD50: 48000 ppm/4h
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
ISOHEXANES:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
No significant acute toxicological data identified in literature search.
METHYL ETHYL KETONE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2737 mg/kg Eye (human): 350 ppm - Irritant
Inhalation (human) TCLo: 100 ppm/5 m Eye (rabbit): 80 mg - Irritant
Inhalation (rat) LD50: 23500 mg/m?8 hr Skin (rabbit): 402 mg/24 hr - Mild
Dermal (rabbit) LD50: 6480 mg/kg Skin (rabbit):13.78mg/24 hr Open
Inhalation (man) TCLo: 10 mg/m?6 hr - Mild
Inhalation (rat) LC50: 50100 mg/m?8 hr
Dermal (rabbit) LD50: 20000 mg/kg
TOLUENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):20 mg/24h- Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit):500 mg - Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit):0.87 mg - Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2mg/24h - SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit):100 mg/30sec - Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
methyl ethyl ILOEl
ketone
toluene IARC:3 ILOEl
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 6 of 7
Section 11 - TOXICOLOGICAL INFORMATION
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: methyl ethyl ketone
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: toluene Category: The substance is classified by IARC as
Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in
animal testing.
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: toluene
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Harmful to aquatic organisms,may cause long-term adverse effects in the aquatic environment.
This material and its container must be disposedof as hazardouswaste.
Section 13 - DISPOSAL CONSIDERATIONS
?Containers may still present a chemical hazard/ danger when empty.
?Return to supplier for reuse/ recycling if possible.
?Recycle wherever possible.
?Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE LIQUID
HAZCHEM: 3[Y]E
UNDG:
Dangerous Goods 3 Subrisk: None
Class:
UN Number: 1993 Packing Group: II
Shipping Name:FLAMMABLE LIQUID, N.O.S.
(contains isohexanes and toluene)
Air Transport IATA:
ICAO/IATA Class: 3 ICAO/IATA Subrisk: None
UN/ID Number: 1993 Packing Group: II
Special provisions: A3
Shipping Name: FLAMMABLE LIQUID N.O.S.
Maritime Transport IMDG:
IMDG Class: 3 IMDG Subrisk: None
UN Number: 1993 Packing Group: II
EMS Number: F- E, S- E Special provisions: 274 330 944
Marine Pollutant: Not Determined
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S6
REGULATIONS
Trade Essentials - Contact AdhesiveThinner - MS702 (CAS: None):
No regulations applicable
n-hexane (CAS: 110-54-3) is found on the following regulatorylists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventoryof Chemical Substances (AICS)
Australia National Pollutant Inventory
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
InternationalCouncil of Chemical Associations(ICCA) - High Production Volume List
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TRADE ESSENTIALS - CONTACT ADHESIVE THINNER - MS702
Chemwatch Material Safety Data Sheet
Issue Date: 26-Nov-2007 CHEMWATCH 04-0272
XC9317EC Version No:1
CD 2007/3 Page 7 of 7
Section 15 - REGULATORY INFORMATION
OECD RepresentativeList of High Production Volume (HPV) Chemicals
isohexanes (CAS: 73513-42-5) is found on the following regulatorylists;
Australia Exposure Standards
isohexanes (CAS: 93924-36-8) is found on the following regulatorylists;
Australia Exposure Standards
methyl ethyl ketone (CAS: 78-93-3) is found on the following regulatorylists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Illicit Drug Reagents/EssentialChemicals - Category III
Australia Inventoryof Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - AppendixE (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - AppendixF (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
OECD RepresentativeList of High Production Volume (HPV) Chemicals
United Nations ConventionAgainst Illicit Traffic in Narcotic Drugs and PsychotropicSubstances - Table II
United Nations List of Precursors and Chemicals Frequentlyused in the Illicit Manufacture of Narcotic Drugs and PsychotropicSubstances Under InternationalControl - Table
toluene (CAS: 108-88-3) is found on the following regulatorylists;
Australia - AustralianCapital Territory - EnvironmentProtection Regulation: Ambient environmentalstandards (Domestic water supply - organic compounds)
Australia - AustralianCapital Territory - EnvironmentProtection Regulation: Pollutants entering waterways taken to cause environmentalharm (Aquatic habitat)
Australia - AustralianCapital Territory EnvironmentProtection Regulation Ecosystemmaintenance- Organic chemicals - Non-pesticideanthropogenicorganics
Australia - AustralianCapital Territory EnvironmentProtection Regulation Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Illicit Drug Reagents/EssentialChemicals - Category III
Australia Inventoryof Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - AppendixE (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - AppendixF (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
InternationalAgencyfor Research on Cancer (IARC) Carcinogens
OECD RepresentativeList of High Production Volume (HPV) Chemicals
United Nations ConventionAgainst Illicit Traffic in Narcotic Drugs and PsychotropicSubstances - Table II
United Nations List of Precursors and Chemicals Frequentlyused in the Illicit Manufacture of Narcotic Drugs and PsychotropicSubstances Under InternationalControl - Table
WHO Guidelines for Drinking-waterQuality - Guideline values for chemicals that are of health significance in drinking-water
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
isohexanes 73513- 42- 5, 93924- 36- 8
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the
reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale
of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,
no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 26-Nov-2007
Print Date: 26-Nov-2007
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