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The Greenstreak Group, Inc.
MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
1. PRODUCT AND COMPANY INDENTIFICATION
Company 24 Hour Emergency Response Information
Product Name: SBR and Neoprene 1-800-364-3577 or (651)737-6501
Adhesive
Manufacturer: The Greenstreak Group
Address: 3400 Treecourt Industrial Blvd
St. Louis MO 63122
Issues date: 05/02/2005
Supercedes Date: 06/08/2003
Product Use:
Specific Use: CONTACT ADHESIVE
2. COMPOSITION/ INFORMATION ON INGREDIENTS
CAS Number Content(% by Wt) Chemical Name
64741-84-0 15-25 NAPHTHA SOLVENT LIGHT
9010-98-4 10-20 POLYCHLOROPRENE
110-54-3 10-20 N-HEXANE
67-64-1 10-20 ACETONE
78-93-3 7-13 METHYL ETHYL KETONE
68611-24-5 7-13 MAGNESIUM RESINATE
Mixture 5-10 MIXED HEXANE ISOMERS
108-88-3 3-7 TOLUENE
Mixture 1-3 MIXED HEPTANES
3. HAZARDS IDENTIFICATION
Emergency Overview
Odor, Color, Grade: grey/green, strong petroleum odor.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from
fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long
distances along the ground or floor to an ignition source and flash back. May cause target organ
effects. Contains a chemicals which can cause birth defects or other reproductive harm.
Potential Health Effects
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MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and
dryness.
May be absorbed following inhalation and cause target organ effects.
Inhalation:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and
vomiting.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous system (CNS) Depression: Signs/symptoms may include headache, dizziness,
drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and
unconsciousness.
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue,
weakness, abdominal tenderness and jaundice.
Central Neuropathy: Signs/symptoms may include irritability, memory impairment,
personality changes, sleep disorder, and decreased ability to concentrate.
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the
extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy.
Kidney Effects: Signs/symptoms may include reduced or absent urine production,
increased serum creatinine, lower back pain, increased protein in urine, and increased
blood urea nitrogen (BUN).
Methyl ethyl ketone has been shown to potentiate the neurotoxic effects of n-hexane. Contains a
chemical or chemicals which can cause birth defects or other reproductive harm.
4. FIRST AID MEASURES
The following first aid recommendations are based on an assumption that appropriate personal and
industrial hygiene practices are followed.
If inhaled:
Remove person to fresh air. If signs/symptoms develop, get medical attention.
If on skin:
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MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get
medical attention. Wash contaminated clothing and clean shoes before reuse.
If in eyes:
Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
If swallowed:
Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an
unconscious person. Get immediate medical attention.
5. FIRE FIGHTING MEASURES
Flammable Properties:
Autoignition temperature: No Data Available
Flash Point: -14 癋 (Test Method: Tagliabue Closed Cup)
Flammable Limits- LEL 1% volume
Flammable Limits- UEL 12.8% volume
Suitable extinguishable media:
Use fire extinguishers with class B extinguishing agents ( e.g., dry chemical, carbon dioxide).
Hazards during fire fighting:
Not applicable. Closed containers exposed to heat from fire may build pressure and explode.
Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to
an ignition source and flash back.
Special Fire Fighting Procedures:
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers
and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a
self- contained breathing apparatus (SCBA).
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and
thermal decomposition information.
6. ACCIDENTAL RELEASE MEASURES
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory
protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for
more information on handling and managing the spill. Evacuate unprotected and untrained personnel
from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources
such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate
the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor
could be an ignition source and could cause flammable gases or vapors in the spill area to burn or
explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer
systems or bodies of water. Avoid contact with incompatible materials listed in the Reactivity Data
Section. Cover spill area with a fire- extinguisher foam. An aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite,
or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears
dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability
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MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
hazard. Collect as much of the spilled material as possible using non- sparking tools. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh
air. Read and following safety precautions on the solvent label and MSDS. Place in a metal container
approved for transportation by appropriate authorities. Seal the container. Dispose of collected material
as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as
reportable according to local, state, and federal regulations.
7. HANDLING AND STORAGE
Handling
Ground containers securely when transferring contents. Wear low static or properly grounded shoes.
Vapors may ignite explosively. May cause flash fire. Prevent build- up of vapors ?open all windows
and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross ?br>
ventilation. Without adequate ventilation, vapors may settle in low- lying areas. Keep away from heat,
sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Extinguish pilot lights and turn
off stoves, ovens and other gas and electric appliances (space and water heaters, furnaces, etc.), electric
motors, and other sources of ignition during adhesive use and until all vapors are gone; i.e., until the
odor of vapors at the floor level has disappeared. Do not use electric light switches. Do not generate
static sparks ( such as by walking on carpet, etc.). Use the same precautions to any other container to
which this product may by transferred. Avoid prolonged breathing of vapors. Avoid eye and skin
contact. Keep container closed when not in use. If work area conditions prevent compliance with any
of the above precautions, do not use the product. Keep out of the reach of children. For industrial or
professional use only: Not intended for consumer sale or use. Follow OTHER PRECAUTIONARY
INFORMATION below.
Storage
General Advice:
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-
ventilated area. Keep container tightly closed. Store away from oxidizing agents.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Advice on system design
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open
containers. Use general dilution ventilation and/or local exhaust ventilation to control airborne
exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is
not adequate, use respiratory protection equipment.
Personal Protective Equipment
Respiratory protection:
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of
contaminants and in accordance with OSHA regulations: Half facepiece air- purifying respiratory with
organic vapor/ acid cartridges and P95 particulate prefilters, Half facepiece air- purifying respirator
with organic vapor/acid gad cartridges and N95 particulate prefilters, Half facepiece air- purifying
respiraoty with organic vapor/acid gas cartridges. Consult the current 3M Respiratory Selection Guide
for additional information or call 1-800-243-46-30 for 3M technical assistance.
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The Greenstreak Group, Inc.
MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
Skin protection:
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an
exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of
appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol.
Eye/Face protection:
Avoid eye contact. Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented
Goggles.
Prevention of Swallowing:
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and
water.
EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ACETONE ACGIH TWA 500ppm Table A4
ACETONE ACGIH STEL 750ppm Table A4
ACETONE OSHA TWA, Vacated 750ppm
ACETONE OSHA TWA 1000ppm Tabel Z- 1
ACETONE OSHA STEL, Vacated 1000ppm
N-HEXANE ACGIH TWA 50ppm Skin Notation*
N-HEXANE OSHA TWA, Vacated 50ppm Table Z-1A
N-HEXANE OSHA TWA 500ppm Table Z-1A
METHYL ETHYL KETONE ACGIH TWA 200ppm
METHYL ETHYL KETONE ACGIH STEL 300ppm
METHYL ETHYL KETONE OSHA TWA 200ppm Table Z-1A
METHYL ETHYL KETONE OSHA STEL 300ppm Table Z-1
TOLUENE ACGIH TWA 50ppm Skin Notation*;TableA4
TOLUENE CMRG STEL 75ppm Skin Notation*
TOLUENE OSHA TWA, Vacated 100ppm
TOLUENE OSHA STEL, Vacated 150ppm
TOLUENE OSHA TWA 200ppm Table Z-2
TOLUENE OSHA CEIL 300ppm Table Z-2
*Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly, by direct contact with
the substances. Vehicles can alter skin absorption.
VAC Vacated PEL: Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in
some states. Check with your local regulatory agency.
Source of Exposure Limit Data:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental
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MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
Exposure Level (WEEL).
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid
Odor: Strong petroleum
Color: grey/green
Autoignition temperature: No Data Available
Flash Point: -14癋 [Test Method: Tagliabue Closed Cup]
Flammable Limits-LEL 1% volume
Flammable Limits-UEL 12.8% volume
Boiling Point 132癋 [Details: CONDITIONS: acetone]
Vapor Density: 3 [Ref Std: AIR=1]
Vapor Pressure: 180 mmHg [Details: CONDITIONS:@68癋]
Specific Gravity: .84 [Ref Std: WATER=1]
PH: No Data Available
Melting Point: No Data Available
10. STABILITY AND REACTIVITY
Stability:
Stable
Materials and Conditions to avoid:
Strong oxidizing agents
Hazardous Polymerization:
Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products:
Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion
Ketones During Combustion
11. TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this
material and/or its components.
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The Greenstreak Group, Inc.
MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined
CHEMICAL FATE INFORMATION
Not determined
13. DISPOSAL CONSIDERATIONS
Waste disposal of substance:
Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate uncured product
in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a
permitted hazardous waste facility. Combustion products will include HCl. Facility must be capable of
handling halogenated materials.
EPA Hazardous Waste Number (RCRA):
D001 (Ignitable), D035 (Methyl ethyl ketone)
Since regulations vary, consult applicable regulations or authorities before disposal.
14. TRANSPORT INFORMATION
ID Number(s):
62-1357-2630-5, 62-1357-2631-3, 62-1357-5530-4, 62-1357-5535-3, 62-1357-6530-3,
62-1357-7530-2, 62-1357-8530-1, 62-1357-8540-0, 62-1357-9531-8, 62-1357-9532-6,
78-8990-0393-9
Please contact the emergency numbers listed on the first page of the MSDS for
Transportation Information for this material.
15. REGULATORY INFORMATION
Federal Regulations
Contact 3M for more information.
SARA hazard categories (EPCRA 311/312):
Fire Hazard-Yes Pressure Hazard-No Reactivity Hazard-No Immediate-Yes
Delayed Hazard-Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR
part 72 (EPCRA):
Ingredient C.A.S. No % by Wt
TOLUENE 108-88-3 3-7
N-HEXANE 110-54-3 10-20
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The Greenstreak Group, Inc.
MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
METHYL ETHYL KETONE 78-93-3 7-13
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
N-HEXANE 110-54-3 Toxic Substances Control Act Applicable
(TSCA) 4 Test Rule Chemicals
ACETONE 67-64-1 Toxic Substances Control Act Applicable
(TSCA) 4 Test Rule Chemicals
State Regulations
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No Classification
TOLUENE 108-88-3 *Developmental Toxin
*Warning: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing
Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard,
29CFR 1910.1200.
16. OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Physical Hazard: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response
personnel to address the hazards that are presented by short- term, acute exposure to a material under
conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical
and toxic properties of the material but also include the toxic properties of combustion or decomposition
products that are known to be generated in significant quantities.
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MATERIAL SAFETY DATA SHEET
SBR & Neoprene Adhesive
June 15, 2006
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 3: Other potential health effects heading was modified.
Copyright was modified
Section 8: Exposure guidelines data source legend was modified.
Section 3: Immediate physical hazard(s) was modified.
Section 5: Fire fighting procedures information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 7: Handling information was modified.
Section 7: storage information was modified.
Section 8: Eye/face protection phrase was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified,
Section 15: TSCA section 12[b] text was modified.
Section 3: Other health effects information was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 15: EPCRA 313 text was modified.
Section 15: California proposition 65 heading was modified.
Section 15: California proposition 65 reproductive harm warning was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 8: Exposure guidelines legend was modified.
Section 8 : Exposure guidelines note was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 3: Other health effects information (reproductive hazards) was modified.
Section 3 : Other potential health effects was modified.
Section 12 Ecotoxicological phrase was modified.
Section 2: Ingredient phrase was added.
DISCLAIMER:
The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued.
3M MAKES NO WARRNATIES, EXPRESSED OR IMPLIED, INCLIDING, BUT NOT LIMITED TO,
ANY IMPLIED WARRANTY OF MERCGANTABILITY OR FITNEDD FOR A PARTICULAR
PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can effect the use and application of a 3M product, some of
which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M
product to determine whether it is fit for a particular purpose and suitable for user's method of use or
application.
3M provides information in electronic form as a service to its costumers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no
representatives as to its completeness or accuracy. In addition, information obtained from a database may
not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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