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MSDS Material Safety Data Sheet
CAS

54-80-9 78-93-3

File Name: 54-80-9_78-93.asp

Product name:                                       Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)



MATERIAL SAFETY DATA SHEET
1. Product and Company Identification

Product: Methyl ethyl ketone


MSDS number: 61
Material number: MSDS-061

Manufacturer name and address:

Celanese Ltd. Celanese Mexicana, S.A. de C.V.
1601 W. LBJ Freeway Tecoyotitla # 412
P.O. Box 819005 ExHacienda de Guadalupe Chimalistac
Dallas, TX 75381-9005 Alvaro Obreg髇 CP 01050
United States M閤ico,D.F.
Phone: 972 443 4000 Phone: (55) 54-80-9100


Celanese Canada, Inc.
P.O. Box 99 Station Main
Edmonton, Alberta,
Canada T5J 2H7

Transportation emergency phone numbers:
In USA, call 800 424 9300
Outside USA, call 703 527 3887, collect calls accepted
In Mexico, call 8700 0021400 / (55) 55 59 1588.

Product Use: Solvent for paints and coatings, adhesives, magnetic tape production, lube oil de-
waxing, printing; miscellaneous uses.

2. Composition / Information on Ingredients

Component CAS Number Percent %
OSHA hazard
category:
METHYL ETHYL KETONE 78-93-3 99.5 Hazardous




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

1 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

3. Hazards Identification


Emergency Overview:

DANGER!
? Extremely flammable liquid and vapor. Vapor may cause flash fire.
? Causes eye irritation.
? May cause respiratory tract irritation.
? May cause skin irritation.
? Vapor is heavier than air and can travel considerable distance to a source of ignition and flashback.


Product Description

Appearance: Clear, colorless, oily liquid.
Odor: Strong characteristic "ketone" odor.

Potential health effects
Routes of exposure: Skin, eyes, inhalation, ingestion.

Immediate effects:

Skin: May cause skin irritation. Symptoms of exposure may include: Drying, cracking or
inflammation of skin.

Eyes: Exposure to vapors and liquid Causes eye irritation. Symptoms of exposure may
include: Eye irritation, burning sensation, pain, watering, and/or change of vision.

Inhalation: May cause respiratory tract irritation. Symptoms of exposure may include: Central
nervous system depression with nausea, dizziness, headache, stupor,
uncoordinated or strange behavior or unconsciousness. Nasal discharge,
hoarseness, coughing, chest pain and breathing difficulty.

Ingestion: Essentially non-toxic. Symptoms of exposure may include: Nausea, vomiting, loss
of appetite, gastrointestinal irritation and/or diarrhea. Central nervous system
depression with nausea, headache and mental sluggishness.

Reproductive: No evidence of reproductive effects.

Carcinogenic: No evidence of carcinogenicity.

Mutagenic: Does not show mutagenic potential in Ames test. Does not show mutatgenic
potential in most in vitro tests.

Teratogenic: No evidence of birth defects.
------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

2 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)


Target organ effects: ? Overexposure (prolonged or repeated exposure) may cause:
Central nervous system depression
Injury to the eyes
Irritation of the respiratory tract
Skin damage.


Medical conditions which may Significant exposure to this chemical may adversely affect people with acute or
be aggravated by exposure: chronic disease of the:
Respiratory Tract
Skin
Eyes
Central nervous system


For further information, see: Section 4 - First Aid Measures
Section 5 - Fire Fighting Measures
Section 6 - Accidental Release Measures
Section 8 - Exposure Controls/Personal Protection
Section 9 - Physical and Chemical Properties
Section 10 - Stability and Reactivity

4. First Aid Measures

Skin: Immediately flush skin with plenty of water. Remove contaminated clothing and
shoes. Call a physician if irritation develops and persists. Wash clothing before
reuse. Thoroughly clean shoes before reuse.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses, if worn. Get medical attention immediately.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Ingestion: If large quantities of this material are swallowed, call a physician immediately. Do
NOT induce vomiting unless directed to do so by a physician. Never give anything
by mouth to an unconscious person. Call a physician.

5. Fire Fighting Measures

NFPA: Health: 1 Flammability: 3 Reactivity: 0

Flammable properties

------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

3 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Flash point (test method): -9 C (16 F) (Closed Cup)

Flammable limits in air, % by volume:
Upper: 10 %
Lower: 1.8 %

Autoignition temperature: 404 C (759 F)

Products of combustion: Carbon Monoxide.


Extinguishing Media: Use alcohol type aqueous film forming foam for large fires. Use CO2 or dry
chemical for small fires.

Fire Fighting Instructions: Water may be ineffective but should be used to cool fire-exposed structures and
vessels. Use water spray for large fires. Water spray can be used to reduce the
intensity of flames and to dilute spills to a non-flammable mixture. Keep personnel
removed from and upwind of fire. If potential for exposure to vapors or products of
combustion exists, wear full fire fighting turnout gear and NIOSH approved self-
contained breathing apparatus. Oxidizing chemicals may accelerate the burning
rate in a fire situation. Vapor is heavier than air and can travel considerable
distance to a source of ignition and flashback.

Fire Fighting Vapors and combustion gases can be controlled using a water fog stream.
Environmental Concerns: Thoroughly decontaminate bunker gear and other fire-fighting equipment before
re-use.

6. Accidental Release Measures




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

4 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Spill or Leak Instructions Eliminate ignition sources. See Section 8 for appropriate personal protective
equipment. Contain spill with dikes of soil or nonflammable absorbent to minimize
contaminated area. Water fog stream may reduce vapors. If fire potential exists,
blanket spill with alcohol type aqueous film-forming foam or use water fog stream
to disperse vapors. Avoid run-off into storm sewers and ditches leading to
waterways. If required, notify state and local authorities. Place leaking containers
in well-ventilated area. Clean up small spills by using a nonflammable absorbent or
flushing sparingly with water. Contain larger spills with nonflammable diking or
absorbent. Clean up by vacuuming or sweeping.

Within the United States, call the National Response Center (800-424-8802) and
appropriate state and local authorities if the quantity released over 24 hours is
equal to or greater than the reportable quantity listed below: par 5,000 lbs. of the
material as is, based on a Reportable Quantity of 5,000 lbs. for methyl ethyl
ketone.

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind;
keep out of low areas. Isolate for 800 meters or 0.5 miles in all directions if tank,
rail car, or tank truck in involved in fire. Evacuate downwind areas as conditions
warrant to prevent exposure and to allow vapors or fumes to dissipate. Spills may
expose downwind areas to toxic or flammable concentrations over considerable
distances in some cases.

7. Handling and Storage

Handling: Use with adequate ventilation. Keep containers closed when not in use. Always
open containers slowly to allow any excess pressure to vent. Avoid breathing
vapor. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and
water after handling. Decontaminate soiled clothing thoroughly before re-use.
Destroy contaminated leather clothing.

This product may generate a static charge. Ground/bond equipment when
transferring material to prevent static accumulation. Electrical equipment and
circuits in all storage and handling must conform to requirements of National
Electric Code (Article 500 and 501) for hazardous location.

Storage: Keep all containers tightly closed when not in use. Store out of direct sunlight and
on an impermeable floor.
Do not store with incompatible materials. See Section 10. Stability and Reactivity.

8. Exposure Controls / Personal Protection



------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

5 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Engineering Controls: General or dilution ventilation is frequently insufficient as the sole means of
controlling employee exposure. Local ventilation is usually preferred. Explosion-
proof equipment (for example fans, switches, and grounded ducts) should be used
in mechanical ventilation systems.

A safety shower and eyebath should be readily available.
Protective Equipment
Skin protection: Wear impervious clothing and gloves to prevent contact. Butyl rubber is
recommended. Other protective material may be used, depending on the
situation, if adequate degradation and permeation data is available. If other
chemicals are used in conjunction with this chemical, material selection should be
based on protection for all chemicals present.

Eye/face protection: Wear chemical goggles when there is a reasonable chance of eye contact.

Respiratory protection: Based on workplace contaminant level and working limits of the respirator, use a
respirator approved by NIOSH. The following is the minimum recommended
equipment for an occupational exposure level. To estimate an occupational
exposure level see Section 3, Section 8 and Section 11.

For concentrations > 1 and < 10 times the occupational exposure level: Use air-
purifying respirator with full facepiece and organic vapor cartridge(s) or air-purifying
full facepiece respirator with an organic vapor canister or a full facepiece powered
air-purifying respirator fitted with organic vapor cartridge(s). The air purifying
element must have an end of service life indicator, or a documented change out
schedule must be established. Otherwise, use supplied air.

For concentrations more than 10 times the occupational exposure level and less
than the lower of either 100 times the occupational exposure level or the IDLH:
Use Type C full facepiece supplied-air respirator operated in positive-pressure or
continuous-flow mode.

For concentrations > 100 times the occupational exposure level or greater than the
IDLH level or unknown concentrations (such as in emergencies): Use self-
contained breathing apparatus with full facepiece in positive-pressure mode or
Type C positive-pressure full facepiece supplied-air respirator with an auxiliary
positive-pressure self-contained breathing apparatus escape system.

For escape: Use self-contained breathing apparatus with full facepiece or any
respirator specifically approved for escape.

Exposure guidelines




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

6 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

ACGIH ACGIH ACGIH OSHA OSHA OSHA
Component Percent Celanese
TWA STEL CEILING TWA STEL CEILING
% WEL *
200 ppm 300 ppm - 200 ppm - -
METHYL ETHYL KETONE 99.5
78-93-3

Component Mexico TWA Mexico STEL
METHYL ETHYL KETONE 200 ppm 300 ppm
78-93-3

1990 NIOSH IDLH 1994 NIOSH IDLH
Component
(Recognized by OSHA)
3000 PPM 3000 ppm
METHYL ETHYL KETONE
78-93-3

Comments: Celanese has adopted the ACGIH TLVs
* Workplace Exposure Limit

9. Physical and Chemical Properties

Appearance: Clear, colorless, oily liquid.

Odor: Strong characteristic "ketone" odor.

Vapor Pressure: 91 mm Hg @ 25 deg C

Vapor Density (Air=1 @ 20 C): 2.41

Boiling Point (760 mmHgA): 79.6 C (175.3 F)

Freezing Point: -86.7 C (-124.1 F)

Solubility in Water @ 20 C: 26.8 %

Specific Gravity: 0.805 at 20 deg C

Molecular Weight: 72.11

Evaporation Rate (n-Butyl acetate = 1): 3.3

10. Stability and Reactivity

Stability: Stable.

Conditions to Avoid: Avoid heat , flames, sparks, and other sources of ignition.
------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

7 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)


Incompatibility: Keep away from caustic soda, lime and other strong alkalis, hydrochloric, sulfuric
and other strong inorganic acids, amines and oxidizing agents such as peroxides,
nitric acid, perchloric acid, chromic acid, chromium trioxide, copper or copper
alloys or pyridines.

Hazardous Combustion or Thermal decomposition products may include oxides of carbon.
Decomposition Products:

Hazardous Polymerization: Hazardous polymerization will not occur.

11. Toxicological Information

Component Toxicological Information

Component METHYL ETHYL KETONE
Acute Exposure: Excessive exposure to MEK leads to depression of the central
nervous system, shown by loss of coordination, reflexes and consciousness.

Oral: Slightly toxic; oral LD50 (rat) = 2.7-5.6 g/kg .

Inhalation: Slightly toxic; inhalation LC50 (rat) is estimated to be > 5000 ppm for a
6 hr. vapor exposure based on the lack of mortality in a repeated exposure study
at this level. Other earlier studies exist, but do not meet current scientific
guidelines. Causes irritation of the nasal passages and throat.

Skin: Slightly toxic; Dermal LD50 (rabbit) = 5.0 - 13 g/kg. Can cause mild to
moderate skin irritation (reddening and swelling). Repeated or prolonged contact
can cause drying of the skin and dermatitis. Not a skin sensitizer based on human
patch test.

Eye: Liquid and vapor can cause severe eye irritation.




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

8 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Mutagenicity: MEK has been shown to be without genotoxic activity in a variety of
in vitro and in vivo tests. Among the tests which produced negative results are
assays for point mutation (e.g., Ames test and mouse lymphoma), chromosomal
aberration (rat liver cells in vitro and mouse bone marrow in vivo), DNA damage
(unscheduled DNA synthesis in rat hepatocytes,), and morphologic transformation
(BALB 3T3 morphologic transformation assay). There was some evidence that
MEK induced aneuploidy in yeast, but this does not appear to be biologically
important since negative results were obtained in a mouse micronucleus test.

Carcinogenicity: No toxicologic studies. Not listed by IARC, NTP or OSHA.

Reproductive/Developmental Effects: No human studies have been reported.
An initial inhalation study with rats indicated fetotoxicity (e.g., delayed fetal
development) and possible teratogenicity at 3000 ppm. However, a
comprehensive follow-up study in rats showed only slight fetotoxicity accompanied
by maternal toxicity at 3000 ppm, but no teratogenic effects. No significant
differences were seen between rats exposed to 1000 ppm or 400 ppm MEK and
the control. Likewise an inhalation study with mice showed only fetotoxicity at
3000 ppm and no effects at 1000 ppm or 400 ppm MEK.

The fetotoxicity in mice also was accompanied by maternal toxicity in mice at 3000
ppm. Since effects reported for the fetus (rats & mice) occurred only at dose
levels where maternal toxicity was evident and are, therefore, considered
secondary outcomes from the maternal toxicity, methyl ethyl ketone is concluded
not to be a developmental toxicant.

Other Effects: MEK is not neurotoxic. It has been shown to potentiate the
neurotoxic effects of hexane, 2,5-hexanedione and methyl-n-butyl ketone. MEK
has also potentiated the liver toxicity of halogenated solvents (e.g., chloroform and
carbon tetrachloride) in animal studies.


Repeated Exposure: Male and female rats exposed to 0, l250, 2500 or 5000 ppm
MEK in air for 6 hrs./day, 5 days/week for 90 days failed to demonstrate
pathological changes attributable to MEK in the organs and tissues studied. Other
studies conducted in rats and on other species at lower exposure levels had
similar results. A dose-related increase in absolute and relative liver weights was
statistically significant at the 5000 ppm exposure level. These effects are
considered adaptive in nature.

12. Ecological Information




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

9 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Component Ecological Information

Component METHYL ETHYL KETONE
Ecotoxicity: Methyl ethyl ketone has low acute toxicity to fish (LC50 range -
4,600 - 5,640 ppm) and aquatic invertebrates (EC50 range = 1,950 - 8,890 ppm).
At above 100 ppm it may inhibit the growth of blue-green algae but such
concentrations are unlikely to be reached except for short periods following
accidental discharge. A concentration of 900 ppm of MEK in water caused a 50%
inhibition of the germination of lettuce (lactuca sativa) seeds.


Environmental Fate:

Degradation:
Biodegradation: Extensive data demonstrate that MEK is readily biodegradable.
Determinations in freshwater and seawater demonstrated that the BOD was a high
percentage of the theoretical oxygen demand. Studies on activated sludge
showed that MEK is easily degraded and is not toxic to sludge microorganisms in
concentrations up to 800 ug/liter. Photodegradation - Although MEK is less
reactive in smog than many other organic chemicals, it does undergo significant
photodecomposition probably because of a combination of direct photolysis and
OH radical reactions. In the presence of 5 ppm NO, and with 35-40% relative
humidity and 10 ppm MEK, a photodecomposition half-life of 9.8 hours was found.
The half-life of MEK calculated in urban conditions is likely to be about 5.5 hours.

Bioaccumulation: No direct information is available on the ability of MEK to
accumulate in biological material. Its high water solubility, rapid degradation by
aquatic bacteria, and low octanol-water partition coefficient of 0.26 suggest that it
is unlikely to concentrate in aquatic species. Metabolic studies in man
demonstrate that concentrations likely to be present in the environment will not
lead to accumulation in human tissues.




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

10 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

13. Disposal Considerations

Dispose of spilled material in accordance with state and local regulations for hazardous waste. Recommended
methods are incineration or biological treatment at a federally or state-permitted disposal facility. Note that this
information applies to the material as manufactured; processing, use, or contamination may make this
information inappropriate, inaccurate, or incomplete.

Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or
local regulations or restrictions are complex and may differ from federal regulations. This information is intended
as an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of
the waste. See Section 9 - Physical and Chemical Properties.


EPA Hazardous Waste Code(s): U159



14. Transport Information

US Department of Transportation:
Shipping name: ETHYL METHYL KETONE
Hazard class: 3 (Flammable Liquid)
UN/NA Number: UN1193
Packing Group: II
DOT Reportable Quantity (RQ): 5000 lbs/2270 kg (Methyl ethyl ketone)
Emergency Response Guide: 127


ICAO/IATA:
Proper Shipping Name: ETHYL METHYL KETONE
Hazard Classification: 3 (Flammable Liquid)
IATA UN Number: UN1193
Packing group: II
Label: (Flammable Liquid)


IMDG:
Proper Shipping Name: ETHYL METHYL KETONE
Hazard Class: 3 (Flammable Liquid)
International Marine UN Number: UN1193
Packing Group: II
Flash point (test method): -9 C (16 F) (Closed Cup)
------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

11 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)



Methyl Ethyl Ketone
Transport Canada

Proper Shipping Name:

Trade Information
Schedule B Code (export): 2914.12.0000

15. Regulatory Information

U.S. STATE REGULATIONS
Chemicals associated with the product which are subject to the state right-to-know regulations are listed along with the
applicable state(s):

METHYL ETHYL KETONE 78-93-3 99.5
Pennsylvania Listed
New York Listed
New Jersey Listed
Illinois Listed
Massachusetts Listed
Rhode Island Listed


U.S. FEDERAL REGULATIONS

TSCA Inventory: We certify that all components are either on the TSCA inventory or qualify for an
exemption.



Environmental Regulations:

METHYL ETHYL KETONE 78-93-3 99.5
EPCRA (SARA Title III) Listed
Section 313
CERCLA Hazardous Substance Listed
SARA EHS Listed


SARA 311:
Acute health: Yes
Chronic health: Yes
Fire: Yes

------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

12 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

Sudden release of No
pressure:
Reactive: No



INTERNATIONAL REGULATIONS

International Chemical Inventory
Listed on the chemical inventories of the following countries or qualifies for an exemption:

AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN



CANADIAN REGULATIONS

WHMIS Classification:
Class B, Division 2. Class D, Division 2, Subdivision B.

This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
.


16. Other Information

Prepared by: Product Stewardship Department
Celanese Ltd.
This information is intended solely for the use of individuals trained in the NFPA and/or
Hazard ratings
HMIS systems.

NFPA: Health: 1 Flammability: 3 Reactivity: 0

HMIS: Health: 2* Flammability: 3 Reactivity: 0



Revisions: The following sections have been revised since the last issue of this MSDS.

1. Product and Company Identification (for Asia Pacific MSDSs only)




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

13 of 14
Product name: Methyl ethyl ketone
MSDS number: 61
Material number: MSDS-061
Published date: 03/23/2001(V3)

For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not suggest or
guarantee that any hazards listed herein are the only ones which exist. Celanese Ltd. makes no warranty of any kind,
express or implied, concerning the safe use of this material in your process or in combination with other substances.
Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials.
This material may be released from gas, liquid, or solid materials made directly or indirectly from it. User has the sole
responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet
all applicable safety and health standards. Material safety data sheets are provided on the Internet by Celanese, Ltd. as a
service to its customers. Possession of an Internet MSDS does not indicate that the possessor of the MSDS was a
purchaser or user of the subject product.




------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Transportation emergency: 800 424 9300 CHEMTREC, 24 hrs/day
703 527 3887 Outside USA, collect calls accepted, 24 hrs/day 800-0021400 / (55) 55-
59-1588 In Mexico, SETIQ, 24 hrs/day
Product emergency: 800 835 5235 Celanese, 24 hrs/day

14 of 14

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