Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
1 Identification of substance
Product details
Trade name: PCLD6 Electric Dye Concentrate
Article number: PCLD6
Manufacturered For:
Sherwin-Williams Automotive Finishes Corp.
101 Prospect Ave. NW
Cleveland, OH 44115
USA
(216)566-2902
Information department: 24HR EMERGENCY 216-566-2917
2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
123-86-4 n-butyl acetate 7 5-100%
78-93-3 butanone 2.5-10%
9004-36-8 CELLULOSE ACETATE BUTYRATE 2 .5-10%
1330-20-7 xylene 2.5-10%
9003-22-9 Acetic acid ethylenyl ester, polymer with chloroethene 2.5%
3089-17-6 QUINACRIDONE MAGENTA 2.5%
ACRYLIC RESIN 2.5%
81-77-6 INDATHRONE BLUE 2.5%
3 Hazards identification
Hazard description:
Irritant
Highly flammable
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Has a narcotizing effect.
Highly flammable.
Irritating to eyes, respiratory system and skin.
Vapours may cause drowsiness and dizziness.
Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
NFPA ratings (scale 0 - 4)
Health = 2
3 Fire = 3
2 0 Reactivity = 0
(Contd. on page 2)
USA
Page 2/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 1)
HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 3
FIRE 3
Reactivity = 0
REACTIVITY 0
4 First aid measures
After inhalation: In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Protective equipment: No special measures required.
6 Accidental release measures
Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
Handling:
Information for safe handling:
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
(Contd. on page 3)
USA
Page 3/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 2)
Components with limit values that require monitoring at the workplace:
123-86-4 n-butyl acetate
PEL
REL
TLV
78-93-3 butanone
PEL
REL
TLV
BEI
1330-20-7 xylene
PEL
REL
(o-, m-, & p-isomers)
TLV
BEI
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 4)
USA
Page 4/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 3)
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
General Information
Fluid
Form:
According to product specification
Color:
Characteristic
Odor:
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 124癈 (255癋)
-4癈 (25癋)
Flash point:
370.0癈 (698癋)
Ignition temperature:
Product is not selfigniting.
Auto igniting:
Product is not explosive. However, formation of explosive air/vapor mixtures
Danger of explosion:
are possible.
Explosion limits:
1.2 Vol %
Lower:
7.5 Vol %
Upper:
Vapor pressure at 20癈 (68癋): 10.7 hPa (8 mm Hg)
Density at 20癈 (68癋):
Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
Solvent content:
89.2 %
Organic solvents:
89.2 %
VOC content:
819.8 g/l / 6.84 lb/gl
10.8 %
Solids content:
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
(Contd. on page 5)
USA
Page 5/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 4)
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
12 Ecological information
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
DOT regulations:
3
Hazard class:
UN1263
Identification number:
II
Packing group:
Proper shipping name (technical name): PAINT
3
Label
Land transport TDG (Canada) and ADR/RID (Europe):
3 Flammable liquids
Hazard class:
1263
UN-Number:
II
Packaging group:
3
Label:
1263 PAINT, special provision 640D
Description of goods:
Maritime transport IMDG:
3
IMDG Class:
1263
UN Number:
(Contd. on page 6)
USA
Page 6/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 5)
3
Label
II
Packaging group:
F-E,S-E
EMS Number:
No
Marine pollutant:
PAINT
Propper shipping name:
Air transport ICAO-TI and IATA-DGR:
15 Regulations
Sara
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
78-93-3 butanone
1330-20-7 xylene
ACRYLIC RESIN
108-88-3 toluene
100-41-4 ethylbenzene
TSCA (Toxic Substances Control Act):
123-86-4 n-butyl acetate
78-93-3 butanone
1330-20-7 xylene
108-88-3 toluene
100-41-4 ethylbenzene
Proposition 65
Chemicals known to cause cancer:
1330-20-7 xylene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
Cancerogenity categories
EPA (Environmental Protection Agency)
78-93-3 butanone D
(Contd. on page 7)
USA
Page 7/7
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 03/02/2006 Reviewed on 03/02/2006
Trade name: PCLD6 Electric Dye Concentrate
(Contd. of page 6)
1330-20-7 xylene D
108-88-3 toluene D
100-41-4 ethylbenzene D
IARC (International Agency for Research on Cancer)
1330-20-7 xylene 3
9003-22-9 Acetic acid ethylenyl ester, polymer with chloroethene 3
108-88-3 toluene 3
100-41-4 ethylbenzene 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
1330-20-7 xylene A4
108-88-3 toluene A4
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
Irritant
Highly flammable
Risk phrases:
Highly flammable.
Irritating to eyes, respiratory system and skin.
Vapours may cause drowsiness and dizziness.
Safety phrases:
Keep container in a well-ventilated place.
Keep away from sources of ignition - No smoking.
Avoid contact with eyes.
This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Contact: Mike Veney 216-332-8528