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Common Name: UNDERWATER REPAIR PUTTY (UW) HARDENER
Manufacturer: ITW DEVCON
MSDS Revision Date: 10/10/2006
Grainger Item Number(s): 5E151
Manufacturer Model Number(s):
MSDS Table of Contents
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SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS
SECTION 3: HAZARDS IDENTIFICATION
SECTION 4: FIRST AID MEASURES
SECTION 5: FIRE FIGHTING MEASURES
SECTION 6: ACCIDENTAL RELEASE MEASURES
SECTION 7: HANDLING AND STORAGE
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10: STABILITY AND REACTIVITY
SECTION 11: TOXICOLOGICAL INFORMATION
SECTION 12: ECOLOGICAL INFORMATION
SECTION 13: DISPOSAL CONSIDERATIONS
SECTION 14: TRANSPORT INFORMATION
SECTION 15: REGULATORY INFORMATION
SECTION 16: ADDITIONAL INFORMATION
DEVCON(R*)
11800
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: UNDERWATER REPAIR PUTTY (UW) HARDENER
STOCK NO.: 11800
MANUFACTURER NAME: ITW DEVCON
ADDRESS:
30 ENDICOTT ST.
DANVERS, MA 01923
PRODUCT DESCRIPTION:
THE FOLLOWING HEALTH HAZARD DATA PERTAIN TO THE HARDENER ONLY.
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WHEN FULLY CURED, THE MIXED PRODUCT IS NON-HAZARDOUS.
BUSINESS PHONE: (978) 777-1100
EMERGENCY PHONE: (800) 424-9300
NFPA:
3
1
1
HMIS:
HEALTH 3*
FIRE 1
REACTIVITY 1
PPE X
* CHRONIC HEALTH EFFECTS
SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME CAS# INGREDIENT PERCENT
1,3-PROPANEDIAMINE, N-(3-(TRIDECYCLOXY) 68479-04-9 5-10 BY WEIGHT
PROPYL)-, BRANCHED
2,4,6-TRIS (DIMETHYLAMINOMETHYL)PHENOL 90-72-2 5-10 BY WEIGHT
INERT MATERIAL N/A 10-30 BY WEIGHT
TRADE SECRET. N/A 30-60 BY WEIGHT
FILLERS N/A 10-30 BY WEIGHT
CRYSTALLINE SILICA 14808-60-7 0.1-1 BY WEIGHT
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING!
HARMFUL. POTENTIAL SENSITIZER. IRRITANT.
APPLIES TO HAZARDOUS INGREDIENTS:
ROUTE OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION
POTENTIAL HEALTH EFFECTS:
EYE CONTACT:
CAN CAUSE SEVERE EYE IRRITATION AND BURNS. EYE CONTACT MAY CAUSE PERMANENT
DAMAGE OR BLINDNESS.
SKIN CONTACT:
CAUSES SEVERE SKIN IRRITATION. MAY CAUSE PERMANENT SKIN DAMAGE. ALLERGIC
REACTIONS ARE POSSIBLE.
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MAY CAUSE SKIN SENSITIZATION, AN ALLERGIC REACTION, WHICH BECOMES EVIDENT
ON REEXPOSURE TO THIS MATERIAL.
INHALATION:
VAPOR OR MIST MAY CAUSE SEVERE RESPIRATORY SYSTEM IRRITATION. MAY CAUSE
RESPIRATORY SENSITIZATION WITH ASTHMA-LIKE SYMPTOMS IN SUSCEPTIBLE
INDIVIDUALS.
INGESTION:
CAUSES IRRITATION, A BURNING SENSATION OF THE MOUTH, THROAT AND
GASTROINTESTINAL TRACT AND ABDOMINAL PAIN.
CHRONIC SKIN CONTACT:
PROLONGED SKIN CONTACT MAY LEAD TO BURNING ASSOCIATED WITH SEVERE
REDDENING, SWELLING, AND POSSIBLE TISSUE DESTRUCTION
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. DIGESTIVE SYSTEM.
SIGNS/SYMPTOMS:
OVEREXPOSURE MAY CAUSE EYE WATERING OR DISCOMFORT, REDNESS AND SWELLING.
AGGRAVATION OF PRE-EXISTING CONDITIONS:
INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS, ASTHMA, ALLERGIES OR KNOWN
SENSITIZATION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
SECTION 4: FIRST AID MEASURES
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 TO 20 MINUTES.
ENSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH
FINGERS. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 TO 20 MINUTES,
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF
IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: >200 DEG. F (93.3 DEG. C)
FLASH POINT METHOD: ESTIMATED.
UPPER FLAMMABLE OR EXPLOSIVE LIMIT: NOT DETERMINED,
LOWER FLAMMABLE OR EXPLOSIVE LIMIT: NOT DETERMINED.
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
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FLAMMABILITY CLASS: CLASS IIIB.
EXTINGUISHING MEDIA:
USE CARBON DIOXIDE (CO2) OR DRY CHEMICAL WHEN FIGHTING FIRES INVOLVING THIS
MATERIAL.
UNSUITABLE MEDIA: WATER OR FOAM MAY CAUSE FROTHING.
FIRE FIGHTING INSTRUCTIONS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. USE COLD WATER SPRAY TO COOL FIRE
EXPOSED CONTAINERS TO MINIMIZE RISK OF RUPTURE, DO NOT ENTER CONFINED FIRE
SPACE WITHOUT FULL PROTECTIVE GEAR. IF POSSIBLE, CONTAIN FIRE RUN-OFF
WATER.
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
SECTION 6: ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE:
AVOID PERSONAL CONTACT AND BREATHING VAPORS OR MISTS. VENTILATE AREA. USE
PROPER PERSONAL PROTECTIVE EQUIPMENT AS LISTED IN SECTION 8.
PERSONAL PRECAUTIONS:
EVACUATE AREA AND KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE SPILL AREA.
SPILL CLEANUP MEASURES:
ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE IN A
CHEMICAL WASTE CONTAINER. PROVIDE VENTILATION. CLEAN UP SPILLS IMMEDIATELY
OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. AFTER REMOVAL,
FLUSH SPILL AREA WITH SOAP AND WATER TO REMOVE TRACE RESIDUE.
ENVIRONMENTAL PRECAUTIONS:
AVOID RUNOFF INTO STORM SEWERS, DITCHES, AND WATERWAYS.
LARGE SPILL: PUMP OR SHOVEL TO STORAGE/SALVAGE VESSELS.
SECTION 7: HANDLING AND STORAGE
HANDLING:
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR, AEROSOL OR MIST.
STORAGE:
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT AND
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
DO NOT STORE IN REACTIVE METAL CONTAINERS. KEEP AWAY FROM ACIDS, OXIDIZERS.
HYGIENE PRACTICES: WASH THOROUGHLY AFTER HANDLING.
SPECIAL HANDLING PROCEDURES:
PROVIDE APPROPRIATE VENTILATION/RESPIRATORY PROTECTION AGAINST
DECOMPOSITION PRODUCTS (SEE SECTION 10) DURING WELDING/FLAME CUTTING
OPERATIONS AND TO PROTECT AGAINST DUST DURING SANDING/GRINDING OF CURED
PRODUCT.
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SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
ENGINEERING CONTROLS:
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, GENERAL DILUTION VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
WHERE SUCH SYSTEMS ARE NOT EFFECTIVE WEAR SUITABLE PERSONAL PROTECTIVE
EQUIPMENT, WHICH PERFORMS SATISFACTORILY AND MEETS OSHA OR OTHER RECOGNIZED
STANDARDS. CONSULT WITH LOCAL PROCEDURES FOR SELECTION, TRAINING,
INSPECTION AND MAINTENANCE OF THE PERSONAL PROTECTIVE EQUIPMENT.
SKIN PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES AND OTHER PROTECTIVE APPAREL TO PREVENT
SKIN CONTACT.
HAND PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES. CONSULT GLOVE MANUFACTURER'S DATA FOR
PERMEABILITY DATA.
EYE/FACE PROTECTION:
WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY
29 CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN
STANDARD EN 166.
RESPIRATORY PROTECTION:
A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC
VAPOR/PARTICULATES COMBINATION CARTRIDGE OR CANISTER MAY BE PERMISSIBLE
UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO
EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS
LIMITED. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY
POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR
ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE
ADEQUATE PROTECTION.
OTHER PROTECTIVE:
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN
EYEWASH AND A DELUGE SHOWER SAFETY STATION.
ONLY ESTABLISHED PEL AND TLV VALUES FOR THE INGREDIENTS ARE LISTED BELOW
INGREDIENT GUIDELINES:
INGREDIENT: CRYSTALLINE SILICA
GUIDELINE TYPE: OSHA PEL-TWA
GUIDELINE INFORMATION: (10 MG/M3)/((% SiO2) + 2)
GUIDELINE TYPE: ACGIH TLV-TWA
GUIDELINE INFORMATION: 0.025 MG/M3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
COLOR: VISCOUS WHITE.
ODOR: AMMONIA LIKE.
PHYSICAL STATE: PASTE.
pH: 10.5 @ 5 PERCENT SOLUTION
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VAPOR PRESSURE: <1 MMHg @ 25 DEG. F
VAPOR DENSITY: >1 (AIR = 1)
BOILING POINT: NOT DETERMINED.
MELTING POINT: NOT DETERMINED.
SOLUBILITY IN WATER: NEGLIGIBLE.
SPECIFIC GRAVITY: 1.48
EVAPORATION POINT: NOT DETERMINED.
PERCENT VOLATILE: 0
VOLATILE ORGANIC COMPOUND CONTENT: 0 G/L
MOLECULAR FORMULA: VARIES
MOLECULAR WEIGHT: VARIES
PERCENT SOLIDS BY WEIGHT: 100
SECTION 10: STABILITY AND REACTIVITY
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
CONDITIONS TO AVOID:
EXTREME HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBLE MATERIALS, OXIDIZERS AND
OXIDIZING CONDITIONS.
INCOMPATIBILITIES WITH OTHER MATERIALS:
OXIDIZERS, ACIDS, AND CHLORINATED ORGANIC COMPOUNDS. REACTIVE METALS
(E.G. SODIUM, CALCIUM, ZINC). SODIUM/CALCIUM HYPOCHLORITE.
NITROUS ACID/OXIDE, NITRITES. PEROXIDES, MATERIALS REACTIVE WITH HYDROXYL
COMPOUNDS.
HAZARDOUS POLYMERIZATION: NOT REPORTED.
SECTION 11: TOXICOLOGICAL INFORMATION
2,4,6-TRIS (DIMETHYLAMINOMETHYL)PHENOL:
EYE EFFECT:
EYE - RABBIT STANDARD DRAIZE TEST: 50 (MICRO)G/24H - (SEVERE) (RTECS)
SKIN EFFECTS:
SKIN - RABBIT STANDARD DRAIZE TEST: 500 (MICRO)L/24H - (SEVERE) (RTECS)
SKIN - RAT LD50:
1280 MG/KG - (DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE) (RTECS)
INGESTION EFFECTS:
ORAL - RAT LD50:
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1200 MG/KG - (PERIPHERAL NERVE AND SENSATION - FLACCID PARALYSIS WITHOUT
ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) LUNGS, THORAX, OR
RESPIRATION - DYSPNEA) (RTECS)
CRYSTALLINE SILICA:
INGESTION EFFECTS:
ORAL - RODENT RAT TDLO - LOWEST PUBLISHED TOXIC DOSE:
120 GM/KG - (GASTROINTESTINAL - HYPERMOTILITY, DIARRHEA
GASTROINTESTINAL - OTHER CHANGES) (RTECS)
INHALATION EFFECTS:
INHALATION - RODENT RAT TCLO - LOWEST PUBLISHED TOXIC CONCENTRATION:
1 MG/KG - (LUNGS, THORAX, OR RESPIRATION - OTHER CHANGES
BIOCHEMICAL - METABOLISM (INTERMEDIARY) - EFFECT ON INFLAMMATION OR
MEDIATION OF INFLAMMATION) (RTECS)
CARCINOGENICITY:
IARC:
GROUP 1: CARCINOGENIC TO HUMANS
NTP: REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY: NO ECOTOXICITY DATA WAS FOUND FOR THE PRODUCT.
ENVIRONMENTAL FATE: NO ENVIRONMENTAL INFORMATION FOUND FOR THIS PRODUCT.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
CONSULT WITH THE US EPA GUIDELINES LISTED IN 40 CFR PART 261.3 FOR THE
CLASSIFICATIONS OF HAZARDOUS WASTE PRIOR TO DISPOSAL. FURTHERMORE, CONSULT
WITH YOUR STATE AND LOCAL WASTE REQUIREMENTS OR GUIDELINES, IF APPLICABLE,
TO ENSURE COMPLIANCE. ARRANGE DISPOSAL IN ACCORDANCE TO THE EPA AND/OR
STATE AND LOCAL GUIDELINES.
RCRA HAZARD CLASS: NONE
SECTION 14: TRANSPORT INFORMATION
DOT SHIPPING NAME: NON-REGULATED
DOT UN NUMBER: N/A
DOT HAZARD CLASS: N/A
DOT PACKING GROUP: N/A
DOT SUBPART E LABELING REQUIREMENT: N/A
NAERG NUMBER: N/A
TECHNICAL NAME N/A
SECTION 15: REGULATORY INFORMATION
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APPLIES TO ALL INGREDIENTS:
TSCA 8(B):
INVENTORY STATUS:
ALL OF THE CONSTITUENTS OF THIS PRODUCT ARE EITHER TSCA LISTED OR EXEMPT
FROM LISTING.
2,4,6-TRIS (DIMETHYLAMINOMETHYL)PHENOL:
EC NUMBER: 603-069-00-0
CRYSTALLINE SILICA:
STATE:
LISTED IN THE STATE OF MASSACHUSETTS HAZARDOUS SUBSTANCE LIST.
LISTED IN THE PENNSYLVANIA STATE HAZARDOUS SUBSTANCES LIST.
COMMENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADIAN REGULATIONS WHMIS HAZARD CLASS(ES): D2B; D2A
SECTION 16: ADDITIONAL INFORMATION
HMIS:
HEALTH HAZARD 3*
FIRE HAZARD 1
REACTIVITY 1
PERSONAL PROTECTION X
NFPA:
HEALTH 3
FIRE HAZARD 1
REACTIVITY 1
MSDS REVISION DATE: 10/10/2006
MSDS AUTHOR: ACTIO CORPORATION
DISCLAIMER:
THIS HEALTH AND SAFETY INFORMATION IS CORRECT TO THE BEST OF OUR KNOWLEDGE
AND BELIEF AT THE DATE OF ITS PUBLICATION BUT WE CANNOT ACCEPT LIABILITY
FOR ANY LOSS, INJURY OR DAMAGE WHICH MAY RESULT FROM ITS USE. THE
INFORMATION GIVEN IN THE DATA SHEET IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, STORAGE AND THE USE OF THE SUBSTANCE. IT IS NOT A SPECIFICATION
NOR DOES IT GUARANTEE ANY SPECIFIC PROPERTIES. ALL CHEMICALS SHOULD BE
HANDLED ONLY BY COMPETENT PERSONNEL, WITHIN A CONTROLLED ENVIRONMENT.
COPYRIGHT(C) 1996-2006 ACTIO SOFTWARE CORPORATION. ALL RIGHTS RESERVED.
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