Material Safety Data Sheet
IMPORTANT NOTICE: This Material Safety Data Sheet (MSDS) is issued by LA-CO Industries, Inc. (LA-
CO) in accordance with the U.S. OSHA Hazard Communication Standard, Canadian WHMIS Controlled
Products Regulations, British CHIP regulation 6, Australian NMRCWHS and ANSI Z400.1-1993
guidelines. The information contained herein must not be altered, deleted or added to, with the exception
of adding supplier/importer information in the space provided. LA-CO has no objection to its MSDS being
copied if: a) the copy is made for safety-related purposes; and b) no alterations or amendments are made
to the text or format of the MSDS, with the exception of adding supplier/importer information in the space
provided. LA-CO does not guaranty the accuracy of any MSDS for our products which: a) is not prepared
by LA-CO; b) is not authorized by LA-CO; c) is not in the format originally supplied by LA-CO; or d) has
otherwise been amended or altered by a third party, with the exception of adding supplier/importer
information in the space provided. Official LA-CO MSDS's reside on its web site at www.laco.com.
Section 1 Product and Company Identification
EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
Manufacturer: Supplier/Importer:
LA-CO INDUSTRIES, Inc./Markal
Co.
1201 Pratt Blvd.
Elk Grove Village, IL, USA 60007-5746
Information Telephone: 847-956-7600
Emergency Telephone: Call CHEMTREC
USA 800-424-9300
International (Call Collect) 1-703-527-3887
Chemical Formula: Mixture
CAS No.: Not Applicable. Derivation: Not Applicable.
Synonyms: Not Applicable.
General Use: Multi-purpose epoxy putty.
Section 2 Composition/Information on Ingredients
Ingredient CAS No. %
Glycidyl ethers of bisphenol A resins 25068-38-6 10 - 30
Tri(dimethylaminomethyl)phenol 90-72-2 0.5 ?1.5
Zinc sulfide 1 1314-98-3 0.5 ?1.5
(For Section 2 footnotes: See Section 15)
Section 3 Hazards Identification
EMERGENCY OVERVIEW: WARNING: May cause irritation to sensitive skin. Wash hands with
soap and water after use. Eye irritant. In case of eye contact, flush with water. Contact
physician. May be harmful if swallowed. When sanding cured putty or substrate, use
protective eye wear and dust mask. KEEP OUT OF REACH OF CHILDREN. FOR
INDUSTRIAL USE ONLY.
ADVERTENCIA: Puede provocar irrataci髇 en piel sensible. Lave sus manos con aqua y
jab髇 despu閟 de usar el producto. Irrataci髇 de los ojos. En caso de que exista contacto
con los ojos, lave los ojos con abundante agua. Comuniquese con su m閐ico. Puede ser
perjudicial si es tragado. Mant閚gase fuera del alcance de los ni駉s. Cuando pula la
Page 1 of 6
EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
masilla ya seca o el substrato, utilice lentes de seguridad y una mascara para el polvo.
ADVERTISSEMENT: Peut irriter une peau sensible. Lavez-vous les mains avec une eau
savonneuse apr閟 usage. Irritant por les l'oeil, rincez avec de l'eau et communiquez avec
votre m閐ecin. Peut 阾re dommageable si aval? Tenir hors de la port閑 des enfants.
Lorsque vous poncez le produit fini, utilisez des lunettes de s閏urit?et masque filtrant.
POTENTIAL HEALTH EFFECTS
Primary Exposure Routes: Eyes, Skin, Ingestion
Acute Effects
Eyes: Possible irritant.
Skin: Possible irritant.
Ingestion: Irritation of intestinal tract.
Inhalation: None.
Chronic Effects
Eyes: Possible sensitizer.
Skin: Possible sensitizer.
Ingestion: None Known.
Inhalation: None Known.
Carcinogenicity: Not Applicable.
Target Organ Effects: Not Applicable.
Medical Conditions Aggravated by Long-Term Exposure: Not Determined.
Other Information: Not Applicable.
Section 4 First Aid
Eye Contact: Immediately flush eyes with water for at least 15 minutes while holding eyelids open. Have
victim roll eyes for more thorough flushing.
Skin Contact: Flush skin with water or wash with soap and water. Consult physician if irritation
develops.
Ingestion: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING
PERSON. Give victim water to dilute.
Inhalation: Not applicable
Other Information: None known
Section 5 Fire Fighting Measures
Flash Point (method): Non-liquid product. Not applicable per OSHA Regulations, Standards - 29 CFR
1910.106 (a) (14)
Autoignition Temperature: Not determined
LEL: Not Determined. UEL: Not Determined.
Flammability Classification: Not determined
Extinguishing Media: Water spray, foam, carbon dioxide, dry chemical.
Hazardous Combustion Products: Aldehydes, acids; oxides of carbon, nitrogen, and sulfur.
Unusual Fire or Explosion Hazards: None known
Fire-Fighting Instructions/Equipment: Keep personnel removed and upwind of any fire. Wear full fire-
fighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
Section 6 Accidental Release Measures
Use recommended personal protective equipment (see Section 8).
Small Spill: Sweep or scrape up.
Large Spill: Sweep or scrape up.
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EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
Section 7 Handling and Storage
Handling Precautions: Use recommended personal protective equipment (see Section 8). Wash
thoroughly after handling.
Storage Requirements: Store away from incompatible chemicals (see Sec. 10). Store in a cool, dry
area below 90癋 (32癈).
Section 8 Exposure Controls/Personal Protection
Eye/Face Protection: Safety glasses. Where contact with the eyes is likely, use chemical goggles. Use
a face shield as needed.
Skin/Hand Protection: Use impervious gloves.
Respiratory Protection: Suitable for related activities where this product is used.
Other Equipment: Eyewash and safety shower.
Engineering Controls: Suitable for related activities where this product is used.
Administrative Controls: Users of this product must be properly trained and qualified in its use.
Other Information: No food or beverage should be consumed in the work area. Wash thoroughly before
eating, drinking, or smoking.
Section 9 Physical and Chemical Properties
Appearance/Physical State: White and black co-extruded putty.
Odor: Sulfur, mercaptan.
Odor Threshold (ppm): Not Determined.
Specific Gravity (H2O = 1): 1.95
Solubility - Water: Insoluble
- Fat: Soluble
Coefficient of Water/Oil Solubility: <1
Partition Coefficient (n-octanol/water): >1
pH: Not applicable
Melting Point: Not applicable
Boiling Point: Not applicable
Vapor Pressure (mm Hg at 200C): Not applicable
Vapor Density (Air = 1): Not applicable
Evaporation Rate (n-BuAc=1): Not applicable
V.O.C. (U.S. Clean Air Act Section 111): 0%(w/w)l
Flash Point (method): (see Section 5)
Autoignition Temperature: (see Section 5)
Flammability Classification: (see Section 5)
Unusual Fire or Explosion Hazards: (see Section 5)
Oxidizing Properties: Not Applicable.
Other Information: None.
Note: The physical data represented above are typical values and should not be construed as a
specification.
Section 10 Stability and Reactivity
Chemical Stability: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: None known
Chemicals to Avoid: Strong oxidizers.
Hazardous Decomposition Products (non-thermal): Not determined
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EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
Section 11 Toxicological Information
Sensitization to Product: May cause allergic skin reaction.
Reproductive Toxicity: Not Applicable.
Teratogenicity: Not Applicable.
Mutagenicity: Not Applicable.
Glycidyl ethers of bisphenol A resins
IRRITATION DATA
EYE-RBT 100 MG MLD AMIHAB 17,129,1958
SKN-GPG 2750 MG/55D-I AITEAT 23,155,1975
TOXICITY DATA
ORL-RAT LD50:11400 MG/KG AMIHAB 17,129,1958
IPR-RAT LD50:2400 MG/KG AMIHAB 17,129,1958
ORL-MUS LD50:15600 MG/KG AMIHAB 17,129,1958
IPR-MUS LD50:4 GM/KG AMIHAB 17,129,1958
Tri(dimethylaminomethyl)phenol
IRRITATION DATA
SKN-RBT 2 MG/24H SEV 85JCAE -,699,1986
SKN-RBT 500 UL/24H SEV NTIS** OTS0544742
EYE-RBT 50 UG/24H SEV 85JCAE -,699,1986
TOXICITY DATA
ORL-RAT LD50:1200 MG/KG RPTOAN 37,130,1974
SKN-RAT LD50:1280 MG/KG ROHM**
TARGET ORGAN DATA
PERIPHERAL NERVE AND SENSATION (FLACCID PARALYSIS WITHOUT ANESTHESIA)
LUNGS, THORAX OR RESPIRATION (DYSPNAE)
Zinc sulfide
TOXICITY DATA
ORL-RAT LD50:>2 GM/KG RCCRC* NOTOX1072/1332,1989
IHL-RAT LC50:>5040 MG/M3/4H RCCRC* NOTOX1072,1989
SKN-RAT LD50:>2 GM/KG RCCRC* NOTOX1072/1333,1989
Further hazard information, if applicable, may be found in Section 3.
Section 12 Ecological Information
Mobility: Not Determined. Ecotoxicity: Not Determined.
Degradability: Not Determined. Other Adverse Effects: Not Determined.
Accumulation: Not Determined.
Section 13 Disposal Considerations
Dispose of in accordance with all applicable regulations.
The conditions of handling, storage, and use of this product are beyond our control and may be beyond
our knowledge. For this and other reasons, LA-CO Industries, Inc. does not assume responsibility and
expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the
handling, storage, use or disposal of this product.
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EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
Section 14 Transport Information
D.O.T. (U.S.)
Proper Shipping Name: Not Regulated.
Hazard Class or Division: Not Regulated.
Hazard Label: Not Regulated.
I.D. Number: Not Regulated.
TDG (Canada): Not Regulated.
IATA: Not Regulated.
ICAO: Not Regulated.
IMO: Not Regulated.
Australian Code for the Transport of Dangerous Goods
Dangerous Goods Class and Subsidiary Risk: Not Determined.
Section 15 Regulatory Information
Footnotes for Section 2:
1 Subject to the reporting requirements of SARA Title III, Section 313.
2 Appears on the California Safe Drinking Water and Toxic Enforcement Act (Prop. 65) Substances List.
3 Appears on the Massachusetts Substances List.
4 Appears on the New Jersey Right-To-Know Hazardous Substances List.
5 Appears on the Pennsylvania Hazardous Substances List.
6 Appears on the Canadian WHMIS Ingredient Disclosure List.
U.S.A.
OSHA Hazard Status: This product is considered to be hazardous as defined by the U.S. OSHA HCS
(29 CFR 1910.1200).
EPA SARA sec. 311/312 Hazard Categories: Immediate (Acute) Health Hazard, Delayed (Chronic)
Health Hazard
Toxic Substances Control Act (TSCA): All ingredients contained in this product are listed on the U.S.
EPA TSCA Chemical Substance Inventory.
HMIS?Rating: Health 1, Flammability 1, Reactivity 0
NFPA?(704) Rating: Health 2, Flammability 1, Reactivity 0
CANADA
WHMIS Status: This product is considered to be hazardous as defined by Canadian WHMIS Controlled
Products Regulations.
WHMIS Rating: D1-B, D2-B
WHMIS Risk Phrases: None required on containers of 100 ml or less per CPR, Section 19[1][a]-[d].
WHMIS Precautionary Statements: None required on containers of 100 ml or less per CPR, Section
19[1][a]-[d].
Domestic Substances List (DSL): All ingredients contained in this product are listed on the Canadian
EPA (CEPA) Domestic Substances List (DSL).
E.U.
European Inventory of Existing Chemical Substances (EINECS): All ingredients contained in this
product are listed on the European Inventory of Existing Chemical Substances (EINECS).
Categories of Danger (Labeling Information): Harmful (Xn)
Risk (R) Phrases: Not required per regulation 9 (8) of CHIP.
Safety (S) Phrases: Not required per regulation 9 (8) of CHIP.
AUSTRALIA
Worksafe Australia Status: Not determined
HAZCHEM Code: Not determined
Poisons Schedule Number: Not determined
Page 5 of 6
EPOXY STIK
Product Name:
Revision #: 2.4 Date Prepared: April 3, 1997 Date Revised: February 5, 2010
Further regulatory information regarding individual ingredients, if applicable, may be found in Section 2.
This product has been classified in accordance with the hazard criteria of the U.S. OSHA Hazard
Communication Standard, the Canadian WHMIS Controlled Products Regulations, the British CHIP2
regulation 6, and the Australian NMRCWHS. This MSDS contains the information required by the above
regulations and conforms to ANSI Z400.1-1993.
Section 16 Other Information
HMIS is a registered trademark of the National Paint and Coatings Association.
NFPA is a registered trademark of the National Fire Protection Association.
MSDS Prepared By: Director of Chemical Safety
The information contained herein is based on data available to us and is accurate and
reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes
no representations as to its completeness or accuracy. Information is supplied on
condition that persons receiving such information will make their own determination as
to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be
responsible for damages of any nature whatsoever resulting from the use of or reliance
upon the information contained herein.
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