Safety Data Sheet 1907/2006/EC (GB)
EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Buehler GmbH
Date printed: 25.04.2008, Revision: 25.04.2008 Page 1 / 5
1 Identification of the substance / preparation and of the company
Product: EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Registration number: not applicable
Use: See product designation
Identified use: none
Method of operation: See product information.
Company: Buehler GmbH
In der Steele 2
D-40599 D黶seldorf (Germany/Allemagne)
Phone: 0800 707 6273
Fax: 0800 707 6274
Homepage: www.buehler-met.de/en/
E-mail: sales@buehler.co.uk
Emergency phone: 0800 707 6273 (Only valid if dialled within the UK)
Responsible: Simonavicius@chemiebuero.de
2 Hazards identification
Physico-chemical hazards: See chapter 10.
Human health dangers: See R-phrases.
Environmental hazards: See R-phrases.
Other hazards: none
Hazard symbols:
Harmful Dangerous for the
environment
R-phrases: R 40: Limited evidence of a carcinogenic effect.
R 36/38: Irritating to eyes and skin.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
3 Composition / Information on ingredients
Diantimony trioxide 1 - < 5%
Xn, R40 CAS: 1309-64-4, EINECS/ELINCS: 215-175-0, EU-INDEX: 051-005-00-X, ECBnr:
1 - < 5%
Xn, R48/20 CAS: 14808-60-7, EINECS/ELINCS: 238-878-4, EU-INDEX: , ECBnr:
Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight 25 - < 40%
Xi-N, R36/38-43-51/53 CAS: 25068-38-6, EINECS/ELINCS: 500-033-5, EU-INDEX: 603-074-00-8, ECBnr:
Silica, vitreous 50 - < 80%
CAS: 60676-86-0, EINECS/ELINCS: 262-373-8, EU-INDEX: , ECBnr:
2,4,6-Tris(dimethylaminomethyl)phenol 1 - < 5%
Xn, R22-36/38 CAS: 90-72-2, EINECS/ELINCS: 202-013-9, EU-INDEX: 603-069-00-0, ECBnr:
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
General information: Remove contaminated soaked clothing immediately and dispose of safely.
Inhalation: Ensure supply of fresh air.
In the event of symptoms seek for medical treatment.
Skin contact: In case of contact with skin wash off immediately with soap and water.
Consult a doctor if skin irritation persists.
Eye contact: In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
Ingestion: Consult a doctor immediately.
Induce the patient to vomit of his own accord only if fully conscious.
Rinse out mouth and give plenty of water to drink.
Advice to doctor: Treat symptomatically.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00045 GB
Safety Data Sheet 1907/2006/EC (GB)
EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Buehler GmbH
Date printed: 25.04.2008, Revision: 25.04.2008 Page 2 / 5
5 Fire-fighting measures
Suitable extinguishing media: Carbon dioxide.
Foam.
Water spray jet.
Dry powder.
Extinguishing media that must not Full water jet.
be used:
Special exposure hazards arising Unknown risk of formation of toxic pyrolysis products.
from the substance or preparation
itself or combustion products:
Special protective equipment for Use self-contained breathing apparatus.
firefighters:
Additional information: Fire residues and contaminated firefighting water must be disposed of in accordance within the local
regulations.
6 Accidental release measures
Personal precautions: Ensure adequate ventillation.
Keep people away and stay on the upwind side.
Avoid dust formation.
Use breathing apparatus if exposed to dust.
Environmental precautions: Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up: Take up mechanically.
Avoid raising dust.
Dispose of absorbed material in accordance within the regulations.
7 Handling and storage
Advice on safe handling: Dust deposits that cannot be avoided must be taken up regularly.
Provide vacuuming if dust raised.
Avoid the formation and deposition of dust.
Advice on protection against fire Take precautionary measures against static discharges.
and explosion:
Dust can form an explosive mixture with air.
Requirements for storage rooms Keep only in original container.
and vessels:
Advice on storage compatibility: Do not store together with oxidizing agents.
Further information on storage Keep container tightly closed.
conditions:
Keep container in a well-ventilated place.
Store in a dry place.
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Safety Data Sheet 1907/2006/EC (GB)
EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Buehler GmbH
Date printed: 25.04.2008, Revision: 25.04.2008 Page 3 / 5
8 Exposure controls / personal protection
Additional advice on system design:Ensure adequate ventilation on workstation.
Ingredients with occupational exposure limits to be monitored: (GB)
1 - < 5%
0,1mg/m?, General remarks: respirable crystalline
Silica, vitreous 50 - < 80%
0,08mg/m?, General remarks: respirable dust
* LTEL: Long-term exposure limit
Respiratory protection: Breathing apparatus in the event of high concentrations.
Short term: filter apparatus, filter P3.
Hand protection: Butyl rubber, >120 min (EN 374).
Eye protection: Safety glasses.
Skin protection: Light protective clothing of plastic material.
General protective measures: Avoid contact with eyes and skin.
Do not inhale dust.
Hygiene measures: Do not eat, drink, smoke or take drugs at work.
After worktime and before work breaks the affected skin areas must be thoroughly cleaned.
Remove soiled or soaked clothing immediately.
Delimitation and monitoring of the not determinated
environmental exposition:
9 Physical and chemical properties
Form: powder
Color: black
Odor: characteristic
pH-value: not applicable
pH-value [1%]: not applicable
Boiling point [癈]: 199-260
Flash point [癈]: > 149
Flammability [癈]: not applicable
Lower explosion limit: not determinated
Upper explosion limit: not determinated
Oxidizing properties: no
Vapour pressure [kPa]: not determinated
Density [g/ml]: 2,09
Density at [癈]: 20癈
Bulk density [kg/m砞: not determinated
Solubility in water: insoluble
Partition coefficient not determinated
[n-octanol/water]:
Viscosity: not applicable
Relative vapour density determined > 1
in air:
Evaporation speed: <1
Melting point [癈]: not determinated
Autoignition temperature [癈]: not determinated
Decomposition temperature [癈]: not determinated
10 Stability and reactivity
Hazardous reactions: Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.
Reactions with acids, alkalies and oxidizing agents.
Hazardous decomposition products:No hazardous decomposition products known.
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00045 GB
Safety Data Sheet 1907/2006/EC (GB)
EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Buehler GmbH
Date printed: 25.04.2008, Revision: 25.04.2008 Page 4 / 5
11 Toxicological information
Acute oral toxicity: not determinated
Acute dermal toxicity: not determinated
Acute inhalational toxicity: not determinated
Irritant effect on eye: not determinated
Irritant effect on skin: not determinated
Sensitization: not determinated
Subacute toxicity: not determinated
Chronic toxicity: not determinated
Mutagenicity: not determinated
Reproduction toxicity: not determinated
Carcinogenicity: not determinated
Experiences made in practice: none
General remarks: The product was classified on the basis of the calculation procedure of the preparation directive.
12 Ecological information
Fish toxicity: not determinated
Daphnia toxicity: not determinated
Behaviour in environment not determinated
compartments:
Behaviour in sewage plant: not determinated
Bacteria toxicity: not determinated
Biological degradability: not determinated
COD: not determinated
BOD 5: not determinated
AOX-advice: The product contains organically bound halogen in accordance with the formulation.
2006/11/EC: yes
General information: The product was classified on the basis of the calculation procedure of the preparation directive.
13 Disposal considerations
Disposal / Product: Dispose of as hazardous waste.
Disposal / Contaminated packaging: Uncontaminated packaging may be taken for recycling.
Waste no. (recommended): 070214*
14 Transport information
Classification according to ADR: UN 3077 Environmentally hazardous substance, solid, n.o.s. (Bisphenol A Epoxy resin) 9, III
- Classification Code: M7
- ADR Limited Quantities: LQ27: 6kg
- Label:
Classification according to IMDG: UN 3077 Environmentally hazardous substance, solid, n.o.s. (Bisphenol A Epoxy resin) 9 III
- IMDG Limited Quantities: LQ: 5 kg
- EMS: F-A, S-F
- Label:
Classification according to IATA: UN 3077 Environmentally hazardous substance, solid, n.o.s. (Bisphenol A Epoxy resin) 9 III
- Label:
http://www.chemiebuero.de Tel.+49(0)941-566-398(-792)Fax.+49(0)941-566-994 eMail:info@chemiebuero.de wbl00045 GB
Safety Data Sheet 1907/2006/EC (GB)
EpoMet/EpoMet F
Article number: 20-3380-xxx, 20-3381-070
Buehler GmbH
Date printed: 25.04.2008, Revision: 25.04.2008 Page 5 / 5
15 Regulatory information
Exposure scenario: not applicable
Chemical safety report: not applicable
Labelling: The product is classified and labelled in accordance within EC-directives.
Hazard symbols:
Harmful Dangerous for the
environment
Contains: - Diantimony trioxide
- Reaction product: bisphenol-A-(epichlorhydrin) Epoxy resin (number average molecular weight
700
R-phrases: R 40: Limited evidence of a carcinogenic effect.
R 36/38: Irritating to eyes and skin.
R 43: May cause sensitisation by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrases: S 22: Do not breathe dust.
S 24/25: Avoid contact with skin and eyes.
S 28.2: After contact with skin, wash immediately with water and soap.
S 36/37: Wear suitable protective clothing and gloves.
S 61: Avoid release to the environment. Refer to special instructions, safety data sheets.
Special labelling: none
Authorisation, TITEL VII: not applicable
Restrictions, TITEL VIII: not applicable
EEC-REGULATIONS: 1967/548 (2004/73, 29. ATP); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004; 1907/2006.
TRANSPORT-REGULATIONS: ADR (2007); IMDG-Code (33. Amdt.); IATA-DGR (2008).
NATIONAL REGULATIONS (GB) EH40/2005 Workplace exposure limits with amendments October 2007.
16 Other informations
R-phrases (Chapter 03): R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 43: May cause sensitisation by skin contact.
R 22: Harmful if swallowed.
R 36/38: Irritating to eyes and skin.
R 40: Limited evidence of a carcinogenic effect.
R 48/20: Harmful - danger of serious damage to health by prolonged exposure through inhalation.
Modified position: Plus: Chapter: 12 General information:
Plus: Chapter: 15 Hazard symbols:
Plus: Chapter: 15 R-phrases:
Plus: Chapter: 15 S-phrases:
Observe employment restrictions yes
for people:
VOC (1999/13/CE): 0%
Customs Tariff: not determinated
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall
not establish a legally valid contractual relationship.
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