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MSDS Material Safety Data Sheet
CAS

111-40-0

File Name: 111-40-0.asp

                              SIGMA-ALDRICH

Material Safety Data Sheet

Date Printed: 28/JUN/2005
Date Updated: 13/MAR/2004
Version 1.4
According to 91/155/EEC

Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.

1 - Product and Company Information

Product Name DIETHYLENETRIAMINE, REAGENTPLUS(TM),
99%
Product Number D93856

Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)

2 - Composition/Information on Ingredients

Product Name CAS # EC no Annex I
Index Number
DIETHYLENETRIAMINE 111-40-0 203-865-4 612-058-00-X

Formula C4H13N3
Molecular Weight 103.17 AMU
Synonyms Aminoethylethandiamine *
3-Azapentane-1,5-diamine *
Bis(2-aminoethyl)amine *
Bis(beta-aminoethyl)amine * Diethylenetriamine
(ACGIH:OSHA) * ChS-P 1 *
2,2'-Diaminodiethylamine * Diethylamine,
2,2'-diamino- * 1,2-Ethanediamine,
N-(2-aminoethyl)- * Ethylamine, 2,2'-iminobis- *
Ethylenediamine, N-(2-aminoethyl)- *
2,2'-Iminobis(ethanamine) * 1,4,7-Triazaheptane

3 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful in contact with skin and if swallowed. Causes burns. May
cause sensitization by skin contact.


4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.

AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.

AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician. Do not induce vomiting.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.

SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.

METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.

STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place. Store under nitrogen.

SPECIAL REQUIREMENTS: Store under inert gas.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.

GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.

EXPOSURE LIMITS
Country Source Type Value
Poland NDS 4 mg/m3


ALDRICH - D93856 www.sigma-aldrich.com Page 2
Poland NDSCh 12 mg/m3
Poland NDSP

EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 4 mg/m3
1 ppm
Remarks: H

EXPOSURE LIMITS - NORWAY
Source Type Value
OEL 4 mg/m3
1 ppm
Remarks: HA

EXPOSURE LIMITS - SWEDEN
Source Type Value
LLV (Level4.5 mg/m3
1 ppm
Remarks: H, S

EXPOSURE LIMITS - SWITZERLAND
Source Type Value
OEL OEL 4 mg/m3
1 ppm
Remarks: H

EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL OEL 4.3 mg/m3
1 ppm

PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
Special Protective Measures: Faceshield (8-inch minimum).

9 - Physical and Chemical Properties

Appearance Physical State: Clear liquid
Color: Colorless

Property Value At Temperature or Pressure

pH N/A
BP/BP Range 200 - 205 掳C
MP/MP Range -35 掳C
Flash Point 102 掳C Method: closed cup
Flammability N/A
Autoignition Temp 358 掳C
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits Lower: 2 %
Upper: 6.7 %
Vapor Pressure N/A
SG/Density 0.95 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density 3.6 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A


ALDRICH - D93856 www.sigma-aldrich.com Page 3
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Conditions of Instability: Absorbs carbon dioxide from air.
Materials to Avoid: Strong oxidizing agents, Strong acids Copper,
Copper alloys.

HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.

HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

RTECS NUMBER: IE1225000

ACUTE TOXICITY

LD50
Oral
Rat
1080 mg/kg
Remarks: Behavioral:Convulsions or effect on seizure threshold.

LD50
Intraperitoneal
Rat
74 MG/KG
Remarks: Behavioral:Convulsions or effect on seizure threshold.
Gastrointestinal:Peritonitis.

LD50
Intraperitoneal
Mouse
71 MG/KG
Remarks: Behavioral:Convulsions or effect on seizure threshold.
Gastrointestinal:Peritonitis.

LD50
Skin
Rabbit
1090 mg/kg

LD50
Skin
Guinea pig
170 UL/KG

IRRITATION DATA

Skin


ALDRICH - D93856 www.sigma-aldrich.com Page 4
Rabbit
500 mg
Remarks: Open irritation test

Skin
Rabbit
500 mg

SENSITIZATION
Sensitization: May cause allergic respiratory and skin reactions

SIGNS AND SYMPTOMS OF EXPOSURE
Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes, and skin.
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting.

ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: Harmful if absorbed through skin.
Eye Contact: Causes burns.
Inhalation: Material is extremely destructive to the tissue of
the mucous membranes and upper respiratory tract. May be harmful
if inhaled.
Ingestion: Harmful if swallowed.

TARGET ORGAN INFORMATION
Liver. Kidneys.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 2079
Class: 8
PG: II
Proper Shipping Name: Diethylenetriamine

IMDG
UN#: 2079
Class: 8
PG: II
Proper Shipping Name: Diethylenetriamine
Marine Pollutant: No
Severe Marine Pollutant: No

IATA


ALDRICH - D93856 www.sigma-aldrich.com Page 5
UN#: 2079
Class: 8
PG: II
Proper Shipping Name: Diethylenetriamine
Inhalation Packing Group I: No

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 612-058-00-X
INDICATION OF DANGER: C
Corrosive.
R-PHRASES: 21/22 34 43
Harmful in contact with skin and if swallowed. Causes burns.
May cause sensitization by skin contact.
S-PHRASES: 26 36/37/39 45
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective
clothing, gloves, and eye/face protection. In case of accident
or if you feel unwell, seek medical advice immediately (show
the label where possible).

COUNTRY SPECIFIC INFORMATION

Germany
WGK: 2

SWITZERLAND
SWISS POISON CLASS: 4

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

DISCLAIMER
For R&D use only. Not for drug, household or other uses.




ALDRICH - D93856 www.sigma-aldrich.com Page 6

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